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921.
Decheng Wan Junlian Huang 《Journal of polymer science. Part A, Polymer chemistry》1999,37(15):2755-2761
The copolymerization of N-phenylmaleimide (NPMI) with ethyl phenylacrylate (EPA) in a mixture of dioxane (DIO) and pyridine (Py) was investigated. The apparent monomer reactivity ratio r1 (NPMI) = 0.07 ± 0.01 and r2 (EPA) = 0.09 ± 0.02 in DIO was turned to r1 (NPMI) = 3.67 ± 0.07 and r2 (EPA) = 0 ± 0.03 in Py. The copolymerization of NPMI and EPA with the fixed feed ratio (mol/mol 1 : 1) in different volume ratio of DIO/Py showed that the copolymer composition might be varied in a wide range from the 93.5% of NPMI contents in copolymer to 48.7%. When the volume fraction of Py in the mixture of DIO and Py was <10%, the copolymer with nice alternating structure was obtained and the copolymerization could be inhibited completely by hydroquinone; if the fraction of Py was >10%, the following two kinds of copolymers were formed: a copolymer in which the content of NPMI increased with the Py and the copolymerization also could be inhibited by hydroquinone and a copolymer with low molecular weight almost completely composed of homopolymer of NPMI and is not affected by radical inhibitor as hydroquinone. The transformation of the copolymerization mechanism from the radical to anionic, which was dependent on the volume ratio of DIO and Py, was suggested. © 1999 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 37: 2755–2761, 1999 相似文献
922.
V. Bertini M. Pocci N. Picci A. Demunno F. Lucchesini F. Iemma 《Journal of polymer science. Part A, Polymer chemistry》1999,37(16):3109-3118
The new monomers 3-(3-methacryloxypropoxy)benzylamine and 4-(3-methacryloxypropoxy)benzylamine in the form of hydrochlorides have been synthesized and radically copolymerized under various conditions with comonomers of different hydrophilicity, including N-acryloylmorpholine, N-acryloylpyrrolidine, N,N-dimethylacrylamide, and N-vinylbenzoylmorpholine, to obtain linear soluble, granular crosslinked, and silica-based macromolecular systems designed for investigating the action mechanism of benzylamine oxidase. Some characteristics of the prepared materials, including scanning electron microscopy photographs, are reported. © 1999 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 37: 3109–3118, 1999 相似文献
923.
Selmiye Alkan Levent Toppare Yesim Hepuzer Yusuf Yagci 《Journal of polymer science. Part A, Polymer chemistry》1999,37(22):4218-4225
Poly(methyl methacrylate) with a thiophene end group having narrow polydispersity was prepared by the Atom Transfer Radical Polymerization (ATRP) technique. Subsequently, electrically conducting block copolymers of thiophene-capped poly(methyl methacrylate) with pyrrole were synthesized by using p-toluene sulfonic acid and sodium dodecyl sulfate as the supporting electrolytes via constant potential electrolysis. Characterization of the block copolymers were performed by CV, FTIR, SEM, TGA, and DSC analyses. Electrical conductivities were evaluated by the four-probe technique. © 1999 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 37: 4218–4225, 1999 相似文献
924.
Aubrey D. Jenkins 《Journal of polymer science. Part A, Polymer chemistry》1999,37(2):113-126
50 years ago, Alfrey and Price advanced the Q‐e scheme for the interpretation of radical and monomer reactivity and the prediction of monomer reactivity ratios in radical copolymerization. Despite the early criticism of the scheme by Mayo and Walling, and its obvious fundamental shortcomings, it continues to be essentially the only such scheme in use today. However, the more soundly based Patterns of Reactivity Scheme, originally proposed in 1959, has recently been revised in such a way that it provides, in a simple way, far more accurate predictions of monomer reactivity ratios than does the Q‐e scheme. Moreover, it is equally applicable to the forecasting of chain‐transfer constants and to the understanding of the reactivity of initiator radicals. The history of investigations of radical, monomer, and transfer agent reactivity is reviewed here, including a summary of the Revised Patterns Scheme and its applications. © 1999 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 37: 113–126, 1999 相似文献
925.
Satoru Amou Shin Nishimura Akio Takahashi Tokio Hagiwara Hiroshi Hamana Tadashi Narita 《Journal of polymer science. Part A, Polymer chemistry》1999,37(3):341-347
N‐(4‐Tetrahydropyranyl‐oxy‐phenyl)maleimide (THPMI) was prepared and polymerized by radical or anionic initiators. THPMI could be polymerized by 2,2′‐azobis(isobutyronitrile) (AIBN) and potassium tert‐butoxide. Radical polymers (poly(THPMI)r) were obtained in 15–50% yields for AIBN in THF at 65°C after 2–5 h. The yield of anionic polymers (poly(THPMI)a) obtained from potassium tert‐butoxide in THF at 0°C after 20 h was 91%. The molecular weights of poly(THPMI)r and poly(THPMI)a were Mn = 2750–3300 (Mw/Mn = 1.2–3.3) and Mn = 11300 (Mw/Mn = 6.0), respectively. The difference in molecular weights of the polymers was due to the differences in the termination mechanism of polymerization and the solubility of these polymers in THF. The thermal decomposition temperatures were 205 and 365°C. The first decomposition step was based on elimination of the tetrahydropyranyl group from the poly(THPMI). Positive image patterns were obtained by chemical amplification of positive photoresist composed of poly(THPMI) and 4‐morpholinophenyl diazonium trifluoromethanesulfonate used as an acid generator. © 1999 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 37: 341–347, 1999 相似文献
926.
In this work, we address two critical aspects of calculation of the free energy differences in molecular systems from molecular simulations. The first aspect involves checking whether the calculated free energy difference depends significantly on the extent of perturbation used for accomplishment of a given transformation. The second aspect of interest is to verify if the sampling errors in calculating the free energy differences between the wild-type molecule and a mutated one in its free state and in a complex are similar, or not, for a finite-length dynamic simulation. The reliability of the free energy estimates obtained from molecular simulations using thermodynamic cycles depends in part on this fact. For investigating these aspects, we use a self-transformation scheme in which a transformation of a part of a molecular system into itself is considered. We perform MD simulations of DNA fragments in which a part of a specific base is subjected to such a self-transformation. Results indicate that the estimated free energy differences do not depend significantly on the extent of perturbation used to achieve the transformation. Interestingly, the variation in the cumulative free energy difference, ΔA, with the coupling parameter, λ, depends significantly on the extent of perturbation. We examine the physical basis of the observed nature of the variation of the accumulated free energy difference, ΔA, against the λ value in the case of a self-transformation. In a thermodynamic cycle, the sampling errors due to the finite-length simulation for the molecular system are found to be similar to each other for the two perturbations (free and in a complex) justifying the use of such approach in calculating ΔΔA in molecular complexes. ©1999 John Wiley & Sons, Inc. J Comput Chem 20: 877–885, 1999 相似文献
927.
Heiko Schfer Wilfred F. Van Gunsteren Alan E. Mark 《Journal of computational chemistry》1999,20(15):1604-1617
The ability to determine the free energy of solvation for a number of small organic molecules with varying sizes and properties from the coordinate trajectory of a single simulation of a given reference state was investigated. The relative free energies were estimated from a single step perturbation using the perturbation formula. The reference state consisted of a cavity surrounded by solvent. To enhance sampling a soft-core interaction was used for the cavity. The effect of the size of the cavity, the effective core height, and the length of simulation on the ability to reproduce results obtained from thermodynamic integration calculations was considered. The results using a single step perturbation from an appropriately chosen initial state were comparable to results from thermodynamic integration calculations for a wide range of compounds. Using a large number of compounds the computational efficiency was potentially increased by 2–3 orders of magnitude over traditional free energy approaches. Factors determining the efficiency of the approach are discussed. ©1999 John Wiley & Sons, Inc. J Comput Chem 20: 1604–1617, 1999 相似文献
928.
Serge Crouzy Jerme Baudry Jeremy C. Smith Benoît Roux 《Journal of computational chemistry》1999,20(15):1644-1658
Accurate calculation of potential energy and free-energy profiles along reaction coordinates of biological processes such as enzymatic reactions or conformational changes is fundamental to the obtention of theoretical insight into protein function. We describe here the practical implementation of the Automatic Map Refinement Procedure (AMRP) and two-dimensional Weighted Histogram Analysis Method (WHAM) for efficient computation of adiabatic potential energy and free-energy maps, respectively. Methods for efficiently sampling configuration space with high-energy barriers and for removing hysteresis in the case of periodic reaction coordinates are presented. The application of these techniques to the isomerization of the C13C14 and C15N16 bonds in the retinal of bacteriorhodopsin is described. In dark-adapted bacteriorhodopsin (bR), the retinal moiety exists in two conformers, all-trans and (13,15)cis, with the latter making ≃67% of the population. This experimental free energy difference is reproduced here to within kBT. ©1999 John Wiley & Sons, Inc. J Comput Chem 20: 1644–1658, 1999 相似文献
929.
S. El‐Taher 《International journal of quantum chemistry》1999,71(3):273-283
The electrophilic additions of hydroperoxyl (HO ), alkylperoxyl (RO ), and halogenated alkylperoxyl radicals to ethylene were studied using the AM1 and PM3 semiempirical MO methods at the SCF/UHF level. Reactantlike transition states were predicted for the title additions. The AM1 activation enthalpies (ΔH ) were found to be increased in the order HO <CH3O <C2H5O <i‐C3H7O . The reactivity of an alkylperoxyl radical toward ethylene was found to be increased as the degree of halogen substitution on the alkyl group increased. A good correlation was established between ΔH and the Taft polar substituent constants, σ*. The Evans–Polanyi correlation between ΔH and ΔH was justified and the validity of the Hammond postulate was indicated. The calculated results were compared with the available experimental findings. ©1999 John Wiley & Sons, Inc. Int J Quant Chem 71: 273–283, 1999 相似文献
930.
M.?SunEmail author Y.?Wu J.?Li N.?H.?Wang J.?Wu K.?F.?Shang J.?L.?Zhang 《Plasma Chemistry and Plasma Processing》2005,25(1):31-40
OH radical in the corona discharge with pipe–nozzle–plate electrode has been diagnosed by optical emission spectroscopy. Spatial variations of OH radical emission in discharge gap have been measured. Relative intensity of OH radical emission spectroscopy increases with increasing water vapor flux injected into the reactor or intensity of electric field supported. In positive pulsed corona discharge, relative intensity is higher than that in positive DC corona discharge and lower than that in negative DC corona discharge. Strongest intensity of OH radical spectrum appears within the range of 5 mm near the discharge nozzle- electrode. In addition, it is proved that the efficiency of desulphurization from flue gas by pulsed corona discharge plasma processes can be improved when OH radical is produced in the reactor. 相似文献