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81.
In order to develop mixed protonic and electronic conductors, we proposed a novel concept for material design that enables to control partial conductivities by fabricating solid solutions of protonic and electronic conductors. In this work, Sr-doped LaBO3 and Sr-doped CeBO3 were chosen as model compounds conducting protons and electron holes, respectively. Solid solutions of the above borates, Sr-doped La1 − xCexBO3, were prepared, and their electrical conductivities were investigated in 8.5 × 102-4.2 × 103 Pa of p(H2O) and 1.0 × 10-1.0 × 105 Pa of p(H2) at 1073 K. From the experimental results of the gas partial pressure dependences of the conductivities, major charge carrier species were identified as a function of x. It was found that proton was the major charge carrier when x < 0.2 while the contribution of the electron hole conduction became remarkable as x increased above 0.2. The contribution of the electron hole conduction can be interpreted by the percolation model. 相似文献
82.
Nanoscopic impedance measurements were carried out on silver ion conducting glasses by coupling an impedance spectrometer with an atomic force microscope. When ac voltages were applied to a conducting AFM tip being in contact with the glass surface, silver nanoparticles were formed during the cathodic half cycle, which were not completely reoxidized in the anodic half cycle. We describe two protocols allowing for a controlled particle growth. The electrochemical oxidation/reduction processes led to low tip/sample interfacial impedances, and the formed silver particles acted as nanoelectrodes sensing the spreading resistance of the glass below the particles. We made a quantitative check of the spreading resistance formula under the assumption that spreading of the electric field is governed by the lateral diameter of the particles and found good agreement between the mean value of the local conductivities obtained at different tip positions and the macroscopic conductivity. 相似文献
83.
The variation of the oxygen content, xO, of synthetic fayalite (Fe2SiO4) single crystals was investigated thermogravimetrically at 1130 °C as a function of the oxygen activity, aO2 (= PO2/PO2° ≈ fO2/fO2° with PO2° ≈ fO2° = 1 bar ≈ 1 atm). It was found that xO varies less in fayalite single crystals than in polycrystalline Fe2SiO4 studied earlier. The majority defects are most likely cation vacancies, (VMe2+)″, ferric ions on M-sites, (Fe3+Me2+), and ferric ions on Si-sites, (Fe3+Si4+)′. Furthermore, the diffusion of iron in synthetic olivine single crystals ((FexMg1 − x)2SiO4) was studied at 1130 °C as a function of orientation, oxygen activity, and cationic composition. The observed oxygen activity dependencies suggest that cations move via different types of cation vacancies, most likely isolated vacancies, (VFe2+)″, and possibly neutral associates, {2(Fe3+Me2+) ⋅ (VMe2+)′ ? ′}x, the latter being minority defects. In addition, the electrical conductivity, σ, of fayalite single crystals was investigated as a function of orientation and oxygen activity within the stability field of fayalite at 1130 °C. The observed oxygen activity dependencies are compatible with (VMe2+)′ ? ′, (Fe3+Me2+), and (Fe3+Si4+)′ being the majority point defects at high aO2 and with h⋅ and e′ as the majority defects at low aO2. The electrical conduction in fayalite is governed by contributions of electrons and holes. This extended point defect model for fayalite is also compatible with data for the variation of the oxygen content and for the iron tracer diffusion. 相似文献
84.
Bangdao ChenHongzhong Liu Hongtao WangFan Fan Li WangYucheng Ding Bingheng Lu 《Applied Surface Science》2011,257(21):9125-9128
Significant emission current enhancement has been achieved for surface conduction electron emitter, due to the special three-dimensional nanocrack structure fabricated by the thermal shock process. The three-dimensional configuration strongly changed the electric field distribution and controlled the emission electron trajectory. Thermal shock treatment was also used to increase the edge roughness of the nanocrack and thereby dramatically improved the field emission characteristics. Stable and uniform electron emission was observed with turn-on voltage of 150 V. The surface conduction current of 400 μA for 6 cells was obtained with the detector voltage of 1 kV and the gap voltage of 170 V. 相似文献
85.
Yuan MoWei-Qing Huang Gui-Fang Huang Wangyu Hu Ling-Ling Wang Anlian Pan 《Physics letters. A》2011,375(19):2000-2006
We investigate the ballistic phonon transport through a Fibonacci array of acoustic nanocavities in a narrow constriction of a semiconductor nanowire at low temperatures. It is found that the transmission spectrum of such a system consists of quasiband gaps and narrow resonances caused by the coupling of phonon waves. Both phonon transmission and thermal conductance exhibit the similarity due to the Fibonacci sequence structure. The similarity is sensitive to the number n and parameters of nanocavities. The results are compared with those in a periodic acoustic nanocavities. 相似文献
86.
Masuo Suzuki 《Physica A》2011,390(11):1904-1916
87.
Hongnian Li Yabo Xu Shining Bao Haiyang Li Peimo He Haijie Qian Fengqin Liu Yibulaxi Kuirexi 《中国科学A辑(英文版)》2000,43(11):1189-1194
K3C60, single crystal film was prepared on the cleaved (111) surface of C60, single crystal. Synchrotron radiation angle-resolved photoemission spectra were measured at normal emission with sample
temperature at × 150K. Up to four subpeaks of LUMO-derived band were observed. These sub-peaks exhibit distinct energy dispersions
which resemble in general the theoretical ones calculated for K3C60 at low temperature with the so-called one-dimensional disordered structure. But there is large deviation of experimental
sub-band intervals from the theoretical values. This result is meaningful for the studies of the physical properties of alkali-doped
C60 solids, e.g. the mechanism for superconductivity. 相似文献
88.
89.
Jumpei Saito Manabu Tanaka Kenji Miyatake Masahiro Watanabe 《Journal of polymer science. Part A, Polymer chemistry》2010,48(13):2846-2854
A new series of sulfonated polyimide (SPI) copolymers containing NH, OH, or COOH groups were synthesized by the polycondensation of 1,4,5,8‐naphthalnetetracarboxylic dianhydride, 3,3′‐bis(sulfopropoxy)‐4,4′‐diaminobiphenyl, and 3‐(4‐aminophenyl)‐5‐(3‐aminophenyl)‐1H‐1,2,4‐triazole (SPI‐8‐m), 3,5‐bis(4‐aminophenyl)‐1H‐1,2,4‐triazole (SPI‐8‐p), 3,6‐diaminocarbazole (SPI‐9), 3,5‐diamino‐1H‐1,2,4‐triazole (SPI‐10), bis(3‐aminopropyl)‐amine (SPI‐11), 2,6‐diaminopurine (SPI‐12), 2,4‐diamino‐6‐hydroxyprymidine (SPI‐13), or 3,5‐bis(4‐aminophenoxy)benzoic acid (SPI‐14). The obtained SPIs were soluble in polar organic solvents and gave tough and flexible membranes by solution casting. The SPI membranes having NH and COOH groups showed high thermal (decomposition temperature ≈200 °C) and mechanical (maximum stress >22 MPa) stability. Introducing NH groups, especially triazole and carbazole groups, was effective in improving proton conductive properties of SPI membranes at low humidity. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 2846–2854, 2010 相似文献
90.
Thermography is a promising method for detecting subsurface defects, but accurate measurement of defect depth is still a big challenge because thermographic signals are typically corrupted by imaging noise and affected by 3D heat conduction. Existing methods based on numerical models are susceptible to signal noise and methods based on analytical models require rigorous assumptions that usually cannot be satisfied in practical applications. This paper presents a new method to improve the measurement accuracy of subsurface defect depth through determining the thermal wave reflection coefficient directly from observed data that is usually assumed to be pre-known. This target is achieved through introducing a new heat transfer model that includes multiple physical parameters to better describe the observed thermal behaviour in pulsed thermographic inspection. Numerical simulations are used to evaluate the performance of the proposed method against four selected state-of-the-art methods. Results show that the accuracy of depth measurement has been improved up to 10% when noise level is high and thermal wave reflection coefficients is low. The feasibility of the proposed method in real data is also validated through a case study on characterising flat-bottom holes in carbon fibre reinforced polymer (CFRP) laminates which has a wide application in various sectors of industry. 相似文献