用二维时域有限差分法分析条形多层波导

为精确分析条形多层波导和多量子阱波导，本文提出了一种以二维时 限差分法为基础的全波数值方法，给出了场分布的色散特性的数值结果，并与矢量有限元法已有的结果作了比较；文中还研究了以二维时域有限差分法为基础的标量近似技术，提出了它的有效性和精度的局限性。     

Propagation Rule of Pulsed Light Beams through First-order Optical Systems

1.IntroductionInthepastfe\\'ycarsltllcil1tcnsity-momentsmethodandtheM2factorhavebeenre-vea1edtobeveryuscfulrotlcscribethepropagationlawandthebeamqualityofastaticlightbeam[l~Jj.Rccent1y,1ncji:1sctal.generalizedtheintensitymomentsmethodfortheSCLQ(speetral1y`"el1-centcrcdandlocallyquasi-monochromatic)pulsedlightboms[5j.Itisapparentthatthosercsu]tsubtainedinreferenceL5]areon1yvalidfortheso-calledquasi-monochromaticlightbeamsandarenotvalidforgeneralpolychromaticpulsedlightbeams,esPeciallyaredono…     

利用双参变形自旋相干态计算量子代数SU(2)q,s的Clebsch-Gordan系数

利用量子代数SU(2)_q,s的双参数变形自旋相干态,通过引入量子代数SU(2)_q,s的不可约表示张量积空间的Bargmann表示,导出了这一表示中不可约表示基底、双参数变形自旋相干态以及算符的表达式.最后导出了量子代数SU(2)_q,s在双参数变形自旋相干态下的Clebsch－Gordan系数.     

深紫外无机非线性光学晶体硼铍酸锶及其分子工程学探索方法

阐述了紫外无机非线性光学晶体分子工程学探索方法的基本特点，具体分析深紫外无机非线性光学晶体硼铍酸锶（ＳＢＢＯ）以氟硼铍酸钾（ＫＢＢＦ）为主要参考晶体的分子设计方法，随后根据晶体结构研究、单晶培养、和非线性光学性能测定等实验结果讨论ＳＢＢＯ作为新型深紫外无机晶体的主要优点，即它既具有更短的紫外吸收边（接近１５５ｎｍ）和较大的非线性光学系数（ｄ２２（ＳＢＢＯ）＝０６×ｄ２２（ＢＢＯ）＝１３８ｐｍ／Ｖ），同时晶体无明显层状习性，并肯有良好的化学稳定性和机械性能     

NLO Corrections of HTC Π0 and Π+Π- Pair Production at ILC in TC2 Model

As well known, if the Higgs boson were not observed at LHC, the technicolor model would be the most favorable candidate responsible for the symmetry breaking. To overcome some defects in the previous model, some extended versions have been proposed. In the TC2 model typical signature is existence of heavy H_TC and technipion Π. A direct proof of validity of the model is to produce them at accelerator. Thus we study the production rates of e⁺ e^- → H_TCΠ⁰ and e⁺ e^- → Π⁺ Π^- at ILC in the topcolor-assisted technicolor (TC2) model. In fact, there is a flood of models belonging to new physics, which can result in products withcharacteristics similar to H_TC+Π of the TC2 model. Therefore to distinguish this model from others one may need to investigate some details by calculating the cross section to NLO. We indeed find that the NLO corrections are significant, namely the ratio δ ≡ (σ_NLO- σ_LO)/σ_LO in e⁺ e^- → H_TC Π⁰ exceeds 100% within a plausible parameter space.     

激光光控超导YBa2Cu3Ox薄膜开关的研制

在对光控热电效应开关进行理论分析的基础上,木文提出用YBa₂Cu₃O_x薄膜制作光控开关,并测试了在液氮温度下薄膜开关在不同激光波长下的特征参数,测试的最好结果是响应度R_v(632.8nm,10kHz,1Hz)为217V/W,归一化探测率D_*(632.8nm,10kHz,1Hz)为2.3×10¹¹cm.Hz^1/2/W,响应时间τ为0.21ms.     

D2EHPA萃取稀土的有机相红外光谱及添加DMHPA的影响

本文研究了部分皂化的二（２－乙基己基）磷酸（Ｄ２ＥＨＰＡ）－正庚烷体系萃取稀土离子Ｙ＾３＋，Ｐｒ＾３＋，Ｎｄ＾３＋，Ｅｕ＾３＋后有机的傅里叶变换红外光谱（ＦＴ－ＩＲ）。发现不同稀土离子与萃取剂的配位能力有差异，并且皂化度对萃取有机相中的Ｐ＝Ｏ谱带的频率和吸收强度皆有影响，在Ｄ２ＥＨＰＡ中加入二（１－甲基庚基）磷酸（ＤＭＨＰＡ）导致Ｐ＝Ｏ谱带形状和吸收强度发生变化。     

Novel approach to preparation of LiMn2O4 core/LiNixMn2−xO4 shell composite

Combining two methods, coating and doping, to modify spinel LiMn₂O₄, is a novel approach we used to synthesize active material. First we coated the LiMn₂O₄ particles with the nickel oxide particles by means of homogenous precipitation, and then the nickel oxide-coated LiMn₂O₄ was calcined at 750 °C to form a LiNi_xMn_2−xO₄ shell on the surface of spinel LiMn₂O₄ particles. Scanning electron microscopy (SEM), Transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), cyclic voltammetry (CV) and charge-discharge test were performed to characterize the spinel LiMn₂O₄ before and after modification. The experimental results indicated that a spinel LiMn₂O₄ core is surrounded by a LiNi_xMn_2−xO₄ shell. The resulting composite showed excellent electrochemical cycling performance with an average fading rate of 0.014% per cycle. This improved cycle stability is greatly attributed to the suppression of Jahn-Teller distortion on the surface of spinel LiMn₂O₄ particles during cycling.     

Influences of laser remelting on microstructure of nanostructured Al2O3-13 wt.% TiO2 coatings fabricated by plasma spraying

The effects of laser remelting on microstructure of nanostructured Al₂O₃-13 wt.% TiO₂ ceramic coatings prepared by plasma spraying with agglomerated powders were studied. The microstructure of the feedstock, as-sprayed and laser-remelted coatings were investigated by using scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS) and X-ray diffractometry (XRD). The results indicate that the plasma-sprayed ceramic coating consists of both fully melted regions and partially melted regions. The totally ceramic coating, especially the fully melted regions, has a typical plasma-sprayed lamellar-like structure as the conventional coating, and has some pores. According to the difference of microstructures, the partially melted regions can be divided into liquid-phase sintered regions (a three-dimensional net or skeleton-like structure: Al₂O₃-rich submicron particles embedded in the TiO₂-rich matrix) and solid-phase sintered regions (remained nanoparticles). The lamellar defect of the as-sprayed coating is erased, and the compactness of the coating is improved significantly after laser remelting. The laser-remelted region composed of fine equiaxed grains, which are different from the conventional column-like crystals along the direction of the heat current. Due to the rapid solidification of laser remelting process, there are still some nanoparticles in the remelted region because of an insufficient time for grains growth.     

Study on the photocatalytic activity of K2La2Ti3O10 doped with zinc(Zn)

The layered perovskite type oxides, K₂La₂Ti₃O₁₀ and zinc(Zn)-doped K₂La₂Ti₃O₁₀ were prepared by sol-gel method and were characterized by power X-ray diffraction, UV-vis diffuse reflectance and X-ray photoelectron spectroscopy. The photocatalytic activity for water splitting of the catalyst powders was investigated with I⁻ as electron donor under ultraviolet and visible light irradiation respectively. The electronic structure of the powders has been analyzed by the first principles calculation, which reveals the photo responses in the visible region and the improvement of the photocatalytic activity of K₂La₂Ti₃O₁₀. Conclusions were made that zinc(Zn)-doped K₂La₂Ti₃O₁₀ exhibited higher reactivity for hydrogen production. When I⁻ was used as electron donor, the optimum doping concentration of zinc(Zn) was found to be 0.015:1 (n_Zn:n_Ti). The average hydrogen production rates were 126.6 μmol/(gcat h) under ultraviolet irradiation and 55.5 μmol/(gcat h) under visible light irradiation which were raised by 131% and 251% compared with undoped K₂La₂Ti₃O₁₀ photocatalyst, respectively.