电荷转移型导电配位化合物

本文简述了电荷转移型导电配位化合物产生，发展，研究现状及以未来趋势。     

Single magnetic adsorbates on s-wave superconductors

In superconductors, magnetic impurities induce a pair-breaking potential for Cooper pairs, which locally affects the Bogoliubov quasiparticles and gives rise to Yu-Shiba-Rusinov (YSR or Shiba, in short) bound states in the density of states (DoS). These states carry information on the magnetic coupling strength of the impurity with the superconductor, which determines the many-body ground state properties of the system. Recently, the interest in Shiba physics was boosted by the prediction of topological superconductivity and Majorana modes in magnetically coupled chains and arrays of Shiba impurities.Here, we review the physical insights obtained by scanning tunneling microscopy into single magnetic adsorbates on the s-wave superconductor lead (Pb). We explore the tunneling processes into Shiba states, show how magnetic anisotropy affects many-body excitations, and determine the crossing of the many-body ground state through a quantum phase transition. Finally, we discuss the coupling of impurities into dimers and chains and their relation to Majorana physics.     

Y-Ba-Cu-O体系超导材料的表面分析和热稳定性研究

XPS 研究表明,在空气中久置后的 Y₂O₃,BaO 和 CuO 以及 YBa₂Cu₃O_～7,超导体的表面都生成有碳酸盐.超导体中的元素价态为:钇+3价,钡+2价,铜主要+2价.原料 CuO 在真空中在400℃加热后大部分被还原成 Cu₂O;制备不久的超导体在同样条件下其 Cu²⁺离子较难还原,然而在空气中久置后的超导体中的 Cu²⁺又较易还原.这些现象既反映了原料氧化物经烧结后由于生成了 YBa₂Cu₃O^_～7相而增加了稳定性,又说明这种超导材料仍具有亚稳性质.     

Tl2Ba2Ca2Cu3O10的化学键性质和同质异能位移研究

Tl2Ba2Ca2Cu3O10 was reported to be a superconductor with a highest transition temperature of 125 K among the homologous series of Tl2Ba2Can-1CunO2n+4. The direct information on the Cu ion site at the atomic level is important for elucidating the superconductivity mechanism. The local bond properties of Tl2Ba2Ca2Cu3O10 were studied using the average band-gap model. The calculated results show that the covalency of Cu(1)-O bond is 0.561, and the average covalency of Cu(2)-O is 0.296. M(o)ssbauer isomer shifts of 57Fe in Tl2Ba2Ca2Cu3O10 were calculated using the chemical surrounding factor, defined by covalency and electronic polarizability. It is verified that for lower doping, Fe substitute the Cu at the Cu (1) site in forms of Fe3+ and Fe4+; for higher doping, Fe3+ and Fe4+ ion occupies Cu(1) and Cu(2) site respectively.The studies show that the determination of the correspondence between spectrum components and actual copper sites occupied by M(o)ssbauer nucleus was made easier with the aid of the calculation results of the chemical bond parameters.     

A theorem for the existence of Majorana fermion modes in spin-orbit-coupled semiconductors

We prove an index theorem for the existence of Majorana zero modes in a semiconducting thin film with a sizable spin-orbit coupling when it is adjacent to an s-wave superconductor. The theorem, which is analogous to the Jackiw-Rebbi index theorem for the zero modes in mass domain walls in one-dimensional Dirac theory, applies to vortices with odd flux-quantum in a semiconducting film in which s-wave superconductivity and a Zeeman splitting are induced by proximity effect. The momentum space construction of the zero-mode solution presented here is complementary to the approximate real space solution of the Bogoliubov-de Gennes equations at a vortex core (Sau et al., arXiv:0907.2239 [17]), proving the existence of non-degenerate zero-energy Majorana excitations and the resultant non-Abelian topological order in the semiconductor heterostructure. With increasing magnitude of the proximity-induced pairing potential, the non-Abelian superconducting state makes a topological quantum phase transition to an ordinary s-wave superconducting state which no topological order.     

Superconducting properties in Rh17S15 under magnetic field and pressure

We have studied superconducting properties by measuring the electrical resistivity and magnetization for a single crystal of Rh₁₇S₁₅ with a superconducting transition temperature T_c=5.4 K. The upper critical field H_c2(0) and the lower critical field H_c1(0) were obtained as 20.5 and 0.0033 T, respectively. Correspondingly, the coherence length and the penetration depth were estimated to be 40 and 4900 Å, respectively, indicating that Rh₁₇S₁₅ is a typical type-II superconductor with strong correlations of conduction electrons with a 4d-electron character of Rh atoms. The present electron correlations are formed to be enhanced with increasing pressure.     

Tunable striped-patterns by lattice anisotropy and magnetic impurities in d-wave superconductors

The pattern transition induced by lattice anisotropy (LA) and magnetic impurities is computationally observed in near-optimally doped d-wave superconductors (DSCs). For the single impurity case, a transition from the checkerboard to stripe pattern can be induced by a very weak LA. For the two-impurity case, an orientation transition from the longitudinal stripe into transverse pattern is observed when the LA ratio reaches some critical value. At the critical point, the structures around impurities can restore checkerboard patterns. These results indicate that the formation of stripes in DSCs might induced by various effects, and could be tunable experimentally.     

Dynamics in mesoscopic superconducting rings: Multiple phase-slips and vortex–antivortex pairs

We investigate the situation where a mesoscopic 1D ring or 2D cylinder is subject to a magnetic field by simulating the time dependant Ginzburg–Landau equations with periodic boundary conditions. We investigate the different possible evolutions for the 1D phase slip phenomenon. The case of the multiple phase slips is analyzed in details and we study the competition between simultaneous and consecutive multiple phase slips analytically and numerically. In 2D we study the creation of vortex–antivortex pairs. Following the theory of the Kibble–Zurek mechanism, we quenched the sample by applying a strong current and observe vortex–antivortex pairs dynamics.     

超导重力仪用液氦恒温器研制

介绍了一套超导重力仪用液氦恒温器,包括技术指标要求、总体结构、关键技术、试验步骤及结果.恒温器液氦消耗量为0.8L/h,真空腔体内部温度稳定度为±5mK,低温下真空腔体真空度优于5×10-4pa,各参数均优于技术指标要求,完全满足超导重力仪工作环境要求.表明该设计方案是合理的,试验流程是正确的.