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991.
采用固相萃取-气相色谱-质谱法测定纺织品中全氟辛烷磺酸盐的含量。纺织品样品在索氏提取器中用甲醇提取后,经固相萃取净化,并用盐酸溶液酸化,再与四丁基氢氧化铵反应。在气相色谱分离中用HP-5MS毛细管柱为固定相,在质谱分析中采用全扫描和选择离子监测模式。全氟辛烷磺酸盐的质量浓度在1.0~30.0mg·kg-1范围内与其峰面积呈线性关系,方法的检出限(3S/N)为0.13mg·kg-1。加标回收率在88.8%~91.1%之间,测定值的相对标准偏差在均小于5.0%。 相似文献
992.
993.
A tri‐quaternary ammonium salt cationic surfactant was synthesized. Its structure was confirmed by using Fourier‐transform infrared spectroscopy, 1H nuclear magnetic resonance spectroscopy, and X‐ray photoelectron spectroscopy analyses. Three model surfaces, including Au‐CH3, Au‐OH and Au‐COOH, were fabricated. Adsorptions of surfactant on the three model surfaces and subsequent plasma proteins adsorption were investigated by quartz crystal microbalance with dissipation (QCM‐D). The mass of surfactant on the Au‐COOH surface was the largest, followed by that on the Au‐CH3 surface, and that on the Au‐OH surface. These results suggested that the main driving force of surfactant immobilization was electrostatic interaction followed by hydrophobic interaction. Based on the results obtained, we concluded that the protein mass adsorbed on Au‐CH3‐ S , Au‐OH‐ S , and Au‐COOH‐ S surfaces depended on the protein size and orientation. The mass and thickness of S on the Au‐COOH surface is the largest and the protein adsorption capacity of Au‐COOH‐ S surface is inferior to that of Au‐CH3‐ S . The Au‐COOH‐ S surface could inhibit lysozyme adsorption, maintain the adsorption balance of bovine serum albumin, and induce fibrinogen‐binding protein adsorption. 相似文献
994.
An efficient approach for difluoromethylation of dicyanoalkylidenes by electrophilic S-(difluoromethyl)sulfonium salt under organic base was described. A wide range of structurally and functionally diverse dicyanoalkylidenes was readily transferred into corresponding desirable difluoromethylated compounds bearing difluoromethylated all-carbon-substituted centers in good to excellent yields under standard reaction conditions. 相似文献
995.
996.
Addition of 2 equiv. of PPh3 to MnBr2 in tetrahydrofuran (THF) solution under N2 atmosphere results in the formation of Naldini salt (PPh3)2MnBr2 ( 1 ). Reaction of Complex 1 and O2, NO, and CO (with reducing agent) leads to Complex (OPPh3)2MnBr2 ( 2 ), (PPh3)2Mn(NO)Br2 ( 3 ), and (PPh3)2Mn(CO)3Br ( 4 ), respectively. Both Complexes 2 and 4 crystallize in the triclinic space group P-1 with a = 9.94 Å, b = 10.11 Å, c = 10.53 Å; α = 65.42°, β = 63.16°, and γ = 89.22° of 2 and a = 10.23 Å, b = 12.26 Å, c = 14.44 Å and α = 97.03°, β = 104.34°, and γ = 106.33° of 4 . The isoelectronic replacement of 3CO with 2NO yields the {Mn(NO)2}8 species (PPh3)2Mn(NO)2Br ( 5 ). The single crystal of 5 is in the monoclinic space group C2/c with a = 23.17 Å, b = 9.62 Å, c = 15.92 Å, and β = 114.91°. In the THF solution, Complex 5 serves as an NO source in the presence of NO trapping, Co(TPP), Co(TPP) = 5,10,15,20-tetraphenyl-21H,23H-porphine cobalt(II). 相似文献
997.
Glass systems of composition xAg2SO4–20Ag2O–(80?x) [0.50 B2O3–0.50 TeO2], where x = 5, 10, 15, 20, 25 and 30 mol% have been prepared by melt-quenching technique. Frequency- and temperature-dependent conductivity measurements have been carried out in the frequency range 10 Hz to 10 MHz and at a temperature range of 303–353 K, respectively. DC conductivities exhibit Arrhenius behavior over the entire temperature range with a single activation barrier. Addition of Ag2SO4 expands the glass network and, consequently, conductivity increases. This suggests that the structure and network expansion are the key parameters for enhancing conductivity. Impedance spectra of these glasses show a single semicircle, indicating one type of conduction. AC conductivity behavior of the glasses was analyzed using both single power law and Kolhrauh–William–Watts (KWW) stretched exponential relaxation function. The power law exponent (s) is temperature-dependent, while the stretched exponent (β) is insensitive to temperature. Scaling behavior has also been carried out using reduced plots of conductivity with frequency, which suggests the ion transport mechanism remains unaffected by temperature and composition. 相似文献
998.
Abstract Representative water samples were collected from different oases in the western desert of Egypt to examine characteristics of Egyptian groundwater. Chemical data recognized two basic groundwater types; alkali bicarbonate and alkali chloride, where sodium has the highest concentration. For each region the median SD, δ18 0 and ionic strength of water calculated from their chemical analyses are recorded and plotted. Generally, the results of isotopic content measurements of the groundwaters from the different oases in the western desert indicate the fossile origin of these waters. The values of δD and δ18 0 of the western desert oases' waters are characteristic of old paleowaters from the Nubian sand aquifer. Modern sparse rainfall data suggest that any precipitation will exhibit moderate to large positive isotopic content enrichments and cannot be a source for these waters. They have been in no connection with the Nile water, moreover the change in isotopic composition is due to evaporation which is now ineffective at deeper levels. 相似文献
999.
The paper deals with analytical and procedural aspects of δ18O and δ2H determination in saline oil-associated waters. The main objective of the study was to show experimentally the qualitative and quantitative applicability of the simple vacuum distillation of saline oil-associated waters while routine procedures of water isotopic analyses are applied. Additionally, two standard off-line techniques of δ2H determination in water – the zinc and the chromium method – have been compared. Each time a typical isotope salt effect has been tracked on the Dead Sea water. The results clearly show that application of the simple vacuum distillation improve the accuracy and reproducibility of δ2H determinations, especially in chromium off-line technique which appeared to be more sensitive to water salinity. The simple vacuum distillation does not improve the quality of δ18O determinations in the range of water salinities studied. Its application to high concentrated brines (for example, Dead Sea water) decreases the time of equilibration but still propagate the isotopic error connected with low water activity (in the case of 18O/16O ratio) and the incomplete water extraction from the remaining salts (in the case of 2H/1H ratio); in consequence, its time-consuming application seems to be baseless. 相似文献
1000.
H. Kaschenz W. Noack K. Runge W. Körner 《Isotopes in environmental and health studies》2013,49(7):213-217
Zur Ermittlung der gespeicherten Energie bei der Einwirkung ionisierender Strahlung auf Steinsalz und den Bedingungen ihrer Freisetzung wurden lichtspektroskopische Absorptionsmessungen und differentialthermoanalytische Unter-suchungen an in einer 60Co-Bestrahlungsanlage bestrahlten Steinsalzproben durchgeführt. Im untersuchten Bereich der Energiedosis von 1 ? 106 Gy bis 5 ? 107 Gy beträgt die gespeicherte Energie 0,12 bis 1,5 kJ/kg. Der Hauptteil der gespeicherten Energie wird bei Erwärmung zwischen 200 °C und 350 °C freigesetzt. Es wird eingeschätzt, daß durch die gespeicherte Energie im Steinsalz keine Gefährdung bei der Endlagerung radioaktiver Abfälle eintritt. 相似文献