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141.
Chong Jia Yong Su Qingtao Zhou Minjun Xin Yousheng Lv Weihai Kong 《Applied Surface Science》2008,254(8):2331-2335
Large scale flower-like ZnO nanosheets have been synthesized on Zinc foil by a simple hydrothermal method. Their morphology and microstructures were characterized and analyzed by X-ray spectroscopy (XRD), field emission scanning electron microscopy (FE-SEM) and high-resolution transmission electron microscopy (HRTEM). The as-synthesized flower-like nanosheets are hexagonal phase single crystal with 200-300 nm in width, 50 nm in thickness. The growth process follows the liquid phase epitaxial growth mechanism. In this approach, the ZnO buffer is used as substrate for the growth of flower-like ZnO nanosheets. The growth direction of the nanosheets is the preferential [0 0 0 1] growth direction of ZnO. The photoluminescence spectrum of the sample exhibits only a sharp and strong UV emission centered at 386 nm, which indicates that the flower-like ZnO nanosheets on Zn foil are of good optical property. 相似文献
142.
143.
Marek Pietraszkiewicz Rafai Gasiorowski Zbigniew Brzózka 《Journal of inclusion phenomena and macrocyclic chemistry》1990,9(3):259-265
Two nitrogen-substituted 4,13-diaza-I8-crown-6 compounds, bearing 2-methylquinolyl and 2-methylquinolyl-1-oxide groups, have been prepared. Ionophore-cation selectivities with a range of inorganic divalent cations have been investigated by means of membrane techniques, demonstrating their high selectivity for the Hg(II) cation. 相似文献
144.
Viktor Csokai Diem Lan Ha Mai Olívia Varga Klára Tóth Miklós Kubinyi Alajos Grün 《Tetrahedron》2008,64(6):1058-1063
Novel fluorogenic 1,3-alt thiacalix[4](N-phenylazacrown-5)ether ionophore has been synthesized by conjugation of the N-phenyl group with borondipyrromethene (BODIPY) fluorophore moiety. The ionophore exhibits pronounced off-on type fluorescent responses to some transition metal ions, in particular to Cu2+. In a PVC membrane electrode, distinct Ag+ selectivity was observed in potentiometric transduction. 相似文献
145.
The relationship between the selectivity of six drug ion-selective electrodes with anionic species of hetero-poly acid as exchange site and the structural and thermodynamical parameters of the metal ion has been investigated experimentally and theoretically. The electrode selectivity is controlled mainly by the extractibility or hydrophobicity of the metal ion, but not by the ion-association-complex formation process. Linear relationship exists between the pK_(ij) value and the structural parameter z~2/(r + 0.85) and the thermodynamic parameter of hydration (△G_h) of the metal ion. Better correlation is obtained for the pK_(ij)vs. (z~2/r)~(-k) relationship. 相似文献
146.
H. James Harwood Kristin McNamara James J. Johnson Faith J. Wyzgoski 《Journal of polymer science. Part A, Polymer chemistry》2008,46(7):2347-2356
Nuclear magnetic resonance (NMR) analysis of the 13C‐labeled chain ends of polystyrene, polyMMA, and styrene‐MMA copolymers prepared by polymerizations initiated using 13C‐labeled‐phenacyl radicals were investigated. The phenacyl radicals were generated by anaerobic oxidation of acetophenone‐methyl‐13C using a Cu(II) octanoate‐pyridine complex in the presence of triethylamine and triphenylphosphine. NMR analysis of the 13C‐labeled chain ends of these polymers afforded insight into the initiation mechanism. In copolymerization experiments using 13C‐labeled acetophenone initiator, the NMR spectra provided evidence that the phenacyl radical reacts 2.7 times faster with styrene than with MMA. The resonances of the labeled phenacyl carbons also showed that the sequence and stereosequence distributions of monomer units at the chain ends are nearly the same as those that prevail along the polymer chains. Styrene–styrene, styrene–MMA, and MMA–styrene enchainments at the chain ends are equally likely to have meso (erythro) or racemic(threo) configurations but the ratio of meso to racemic MMA‐MMA enchainments is ~ 3/7. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 2347–2356, 2008 相似文献
147.
Summary A thermodynamic equation is derived for the non-specific selectivity of alkyl bonded phases as a function of the mobile phase composition using a displacement mechanism to model the sorption of solvents into the bonded phase. The equation is used to calculate the thermodynamic parameters which characterize the incremental behavior of a hydrophobic group in ethyl alkanoate and methyl perfluoroalkanoate ester solutes chromatographed with water-methanol and water-acetonitrile mobile phases on both octyl and octadecyl bonded phases. 相似文献
148.
Morphologies of a spherical bimodal polyelectrolyte brush induced by polydispersity and solvent selectivity
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Qing-Hai Hao 《中国物理 B》2021,30(6):68201-068201
It is commonly realized that polydispersity may significantly affect the surface modification properties of polymer brush systems. In light of this, we systematically study morphologies of bidisperse polyelectrolyte brush grafted onto a spherical nanocolloid in the presence of trivalent counterions using molecular dynamics simulations. Via varying polydispersity, grafting density, and solvent selectivity, the effects of electrostatic correlation and excluded volume are focused, and rich phase behaviors of binary mixed polyelectrolyte brush are predicted, including a variety of pinned-patch morphologies at low grafting density and micelle-like structures at high grafting density. To pinpoint the mechanism of surface structure formation, the shape factor of two species of polyelectrolyte chains and the pair correlation function between monomers from different polyelectrolyte ligands are analyzed carefully. Also, electrostatic correlations, manifested as the bridging through trivalent counterions, are examined by identifying four states of trivalent counterions. Our simulation results may be useful for designing smart stimuli-responsive materials based on mixed polyelectrolyte coated surfaces. 相似文献
149.
150.
A chlorinated side product was formed under Overman rearrangement conditions from a trichloroacetimidate along with the expected allylic amide. The chlorinated product derived from a hex-2-enopyranoside was obtained in a totally stereoselective manner, and it can be a useful synthetic intermediate for chlorinated sugars. In order to improve the isolated yields of either the expected Overman rearrangement product or the chlorinated compound, we carried out a thorough study on the experimental conditions. The application of the latter for the synthesis of potential calpain inhibitors is also reported. 相似文献