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81.
82.
Formation of Compounds in the Quasi-binary Systems AcX4? MX2 (Ac = Th, U; M = Ca, Sr, Ba, Eu, Ge, Sn, Pb; X = Br, I) T,x-phase diagrams of the systems ThI4? SnI2, ThI4? PbI2, ThI4? CaI2, and ThI4? SrI2 were established using thermoanalysis and x-ray methods. The only ternary compounds have a 1:1 composition. Further AcMX6 compounds (Ac: Th, U; M: Ca, Sr, Ba, Eu, Ge, Sn, Pb; X: Br, I) were synthesized and their structures investigated. Four structure types are found depending on the temperature and the Ac/M combinations. The structures of γ-ThSnI6 and β-ThSnI6 were determined with single crystal methods as representatives of a whole series of isotypic compounds. 相似文献
83.
Max Herberhold Cornelius G. Kreiter Siegfried Stüber Günter O. Wiedersatz 《Journal of organometallic chemistry》1975,96(1):89-94
The methoxy signals in the 1H NMR spectrum of cyclopentadienylmanganese dicarbonyl tetramethoxyethylene, C5H5Mn(CO)2[C2(OCH3)4], show a definite temperature-dependence. In CS2 solution the variations of the signals are observed within a single temperature range, while in toluene-d8 two regions of change are found to exist. These data are explained on the basis of two mutually independent ligand movements: a hindered rotation of the olefin ligand around the metalligand bond (ΔG3194 = 9.8 ± 0.6 kcal/mol), and a hindered movement of the four methoxy groups (ΔG3263 = 13.8 ± 0.3 kcal/mol, both in toluene-d8. Chiral conformations of the ligand are assumed to be formed when the movement of the methoxy substituents ceases. 相似文献
84.
A new characterization of equilibrium states for classical lattice systems is given in terms of correlation inequalities. Their physical meaning is found to express thermodynamic stability. We demonstrate the applicability of the inequalities in specific models.Bevoegdverklaard navorser N.F.W.O.Aangesteld navorser N.F.W.O. 相似文献
85.
K. G. Guderley 《Journal of statistical physics》1973,8(3):231-237
A formula is presented which can be regarded as the analytic basis for irreducible diagram expansions. It expresses the off-diagonal elements of the inverse of a matrix of operators by the off-diagonal elements and by diagonal elements of various inverses of the original operator. The formula can be obtained by purely analytic means without reference to statistical considerations. No infinite processes are involved if one deals with a finite matrix of operators. 相似文献
86.
H. Fehske A.P. Kampf M. Sekania G. Wellein 《The European Physical Journal B - Condensed Matter and Complex Systems》2003,31(1):11-16
In order to clarify the physics of the crossover from a Peierls band insulator to a correlated Mott-Hubbard insulator, we
analyze ground-state and spectral properties of the one-dimensional half-filled Holstein-Hubbard model using quasi-exact numerical
techniques. In the adiabatic limit the transition is connected to the band to Mott insulator transition of the ionic Hubbard
model. Depending on the strengths of the electron-phonon coupling and the Hubbard interaction the transition is either first
order or evolves continuously across a narrow intermediate phase with finite spin, charge, and optical excitation gaps.
Received 7 July 2002 / Received in final form 21 October 2002 Published online 27 January 2003
RID="a"
ID="a"e-mail: holger.fehske@physik.uni-greifswald.de 相似文献
87.
Igor Pak 《Transactions of the American Mathematical Society》2000,352(12):5525-5561
Let be a finite set of tiles, and a set of regions tileable by . We introduce a tile counting group as a group of all linear relations for the number of times each tile can occur in a tiling of a region . We compute the tile counting group for a large set of ribbon tiles, also known as rim hooks, in a context of representation theory of the symmetric group.
The tile counting group is presented by its set of generators, which consists of certain new tile invariants. In a special case these invariants generalize the Conway-Lagarias invariant for tromino tilings and a height invariant which is related to computation of characters of the symmetric group.
The heart of the proof is the known bijection between rim hook tableaux and certain standard skew Young tableaux. We also discuss signed tilings by the ribbon tiles and apply our results to the tileability problem.
88.
采用化学浸提技术对广东省黄埔港土壤中的铬进行了分析,研究了浸提条件及其对测定结果的影响,并运用GF-AAS法定量分析Cr(Ⅵ).检出限为0.03 μg/L,相对标准偏差(RSD,n=12)为1.52%,加标回收率在95.6%-103.6%. 相似文献
89.
Nathaniel Cain Alexander Haywood George Roberts Douglas Kiserow Ruben Carbonell 《Journal of Polymer Science.Polymer Physics》2011,49(15):1093-1100
The influence of dissolved propane (up to 31.2 wt %) on the phase equilibria of 5 wt % polystyrene (PS) dissolved in 66/34 wt % trans/cis‐decahydronaphthalene (DHN) was measured over the temperature range of 323–423 K. A suitable temperature, pressure, and propane composition operating space was defined to measure intrinsic viscosities of a single fluid phase. Intrinsic viscosities of PS in cosolvent mixtures of propane and trans/cis‐DHN were measured between 323 and 423 K and between 70 and 208 bar. The addition of propane to the isomeric mixture of DHN resulted in a decreased solvent quality for PS, causing a contraction of the PS coil. The most dramatic decrease in solvent quality with the addition of propane occurred at 323 K and 70 bar with approximately a 36% reduction in the viscometric radius with the addition of 45 mol % propane to DHN. At 423 K, the solvent quality was less sensitive to the addition of propane and only a 13% reduction in the viscometric radius was observed at 70 bar and 45 mol % propane in DHN. © 2011 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys, 2011 相似文献
90.
Nichole Cates Miller Roman Gysel Chad E. Miller Eric Verploegen Zach Beiley Martin Heeney Iain McCulloch Zhenan Bao Michael F. Toney Michael D. McGehee 《Journal of Polymer Science.Polymer Physics》2011,49(7):499-503
Polymer:fullerene blends have been widely studied as an inexpensive alternative to traditional silicon solar cells. Some polymer:fullerene blends, such as blends of poly(2,5‐bis(3‐tetradecylthiophen‐2‐yl)thieno[3,2‐b]thiophene (pBTTT) with phenyl‐c71‐butyric acid methyl ester (PC71BM), form bimolecular crystals due to fullerene intercalation between the polymer side chains. Here we present the determination of the eutectic pBTTT:PC71BM phase diagram using differential scanning calorimetry (DSC) and two‐dimensional grazing incidence X‐ray scattering (2D GIXS) with in‐situ thermal annealing. The phase diagram explains why the most efficient pBTTT:PC71BM solar cells have 75–80 wt % PC71BM since these blends lie in the center of the only room‐temperature phase region containing both electron‐conducting (PC71BM) and hole‐conducting (bimolecular crystal) phases. We show that intercalation can be suppressed in 50:50 pBTTT:PC71BM blends by using rapid thermal annealing to heat the blends above the eutectic temperature, which forces PC71BM out of the bimolecular crystal, followed by quick cooling to kinetically trap the pure PC71BM phase. © 2011 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys, 2011 相似文献