乙二醇／水与丙三醇／水体系的焓浓图与浓图

本文基于乙二醇／水与丙三醇／水两组二元体系在不同温度下的实验数据,对超额焓数据应用局部作用模型拟合,并分析拟合效果与拟合参数变化情况,发现Wilson模型拟合效果较好。通过Wilson方程的活度系数表达形式,推算了两组体系的气液平衡,并进而计算了两组体系的焓浓图与(火用)浓图。     

Phase Diagram of the Two-dimensional t–t′ Falicov-Kimball Model

The ground-state phase diagram of the two-dimensional Falicov-Kimball model with nearest-neighbour and next-nearest-neighbour hoppings has been studied in the perturbative regime where hoppings are small compared with the on-site Coulomb interaction. The phase diagram at fourth-order exhibits a richer structure than the one of the ordinary Falicov-Kimball model. PACS numbers: 71.10.Fd, 71.21.+a, 75.10.Hk, 75.30.Kz     

Specific features of T-C-P diagrams for binary systems of B-elements

Abstract

The possibility of reaching high pressures gave rise to intense studies of the phase state of substances, their structures, and properties depending on a new thermodynamic parameter-pressure. Characterizing the extensive development of these studies, one should distinguish three stages: (i) the study of polymorphism for elements under high pressure, and the construction of T-P diagrams; (ii) the study of polymorphism for compounds; and (iii) the construction of three-dimensional T- C-P diagrams for binary and multicomponent systems. At present, the first stage is almost completed in the pressure range from ～100 kbar (see Ref. 1) to 1 Mbar. A series of empirical laws have been established that determine the general direction of structural changes for chemical elements with a pressure rise. Thus, for the elements of the B-subgroup of the Periodic Table, the “coordination rule” has been established according to which an increase in pressure produces structural changes in B elements characterized by a higher packing density and coordination number. According to another rule, the so-called homology rule, B-elements under pressure acquire structures typical for their heavier homologues at normal pressure. These rules manifest themselves most clearly for the elements of the IVB subgroup. In a C-Si-Ge-Sn row structure types change with an increase of the coordination number as follows: graphite (3)-diamond (4)-white tin (6). The same sequence is also observed for the elements of the M3 subgroup with a pressure rise: graphite transforms into diamond, and the diamond-like structure of germanium and silicon transforms into the white-tin structure.     

Phase transitions and equations of state at multimegabar pressures

Abstract

Review of phase transitions and equations of state at multimegabar pressures (100–300 GPa) is presented. Energy dispersive x-ray diffraction techniques in conjunction with synchrotron radiation sources are used. Besides several transition metals, Pt to 282 GPa, Re to 251 GPa, W to 209 GPa, and Fe to 255 GPa, the special focus is on Group IVA elements and isoelectronic III-V compounds. At high pressure, the isoelectronic materials are isostructural and exhibit similar equation of state.     

Taming of divergences in a unitary model of massive fermions, vectors and scalars

We consider a massive vector field, interacting through three-field interactions with a massive scalar and spinor field, in a unitary model. There are divergences that cannot be removed by introduction of counter terms into the Lagrangian. It is shown that it is possible to tame many of them and to remove the remaining divergences by appropriate choices of the coupling constants.     

Period doubling toward chaos in a driven magnetic macrospin

The Landau-Lifshitz-Gilbert equation is analyzed in the case of a configuration involving easy plane isotropy under the influence of a sinusoidally oscillating magnetic field and a demagnetizing field. Through the use of numerical techniques, chaotic behavior is found and analyzed. By reducing the system to a discrete map (numerically), bifurcation diagrams for the system are computed. The system is found to exhibit a period doubling cascade route to chaos, and it obeys certain convergence rules for chaotic transitions outlined by Feigenbaum. A connection is drawn between the route to chaos and the geometry of the system, and comparisons are made with similar systems. Within the chaotic regime, windows of arbitrarily large period are suspected to exist, and explicitly illustrated and discussed for a period three window.     

Extension of the GHJW theorem for operator ensembles

The Gisin-Hughston-Jozsa-Wootters theorem plays an important role in analyzing various theories about quantum information, quantum communication, and quantum cryptography. It means that any purifications on the extended system which yield indistinguishable state ensembles on their subsystem should have a specific local unitary relation. In this Letter, we show that the local relation is also established even when the indistinguishability of state ensembles is extended to that of operator ensembles.     

Effects of the bond dilution on the phase diagrams of a spin-1 transverse Ising model with crystal field interaction on a honeycomb lattice

A bond diluted spin-1 Ising model with crystal and transverse field interactions is examined for honeycomb lattice by introducing an effective field approximation that takes into account the correlations between different spins that emerge when expanding the identities. The effects of the crystal field as well as the transverse field and dilution on the phase diagrams and order parameter m_z are discussed in detail. A number of interesting and unusual phenomena such as reentrant phenomena and three successive phase transitions originating from the crystal field as well as the transverse field and bond dilution have been found.