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991.
The polarographic behaviour of uranium and tellurium has been studied in the presence of increasing concentration of complex forming agent viz. ?-caprolactam at pH 4.4 for U(VI) and at pH 10.0 for Te(IV) at μ=0.1 M KNO3. In both cases the waves have been found to be diffusion controlled and irreversible. The values of kinetic parameters (σπa and K°f,h) have been calculated as a function of the ligand concentration. Method is suitable for the quantitative determination of these metals individually and simultaneously with the effect of diverse ions. 相似文献
992.
《Analytical letters》2012,45(2):445-456
Abstract The ternary complexes of copper (II) with glycine, alanine, aspartate or glutamate as primary ligand and pyruvate as secondary ligand have been investigated using differential pulse polarography. the reversible diffusion controlled reduction of the complexed ion reveals two mixed complexes to be formed with stoichiometries 1:1:1 and 1:2:1. Their overall formation constants in a sodium perchlorate supporting electrolyte have been calculated at μ =0.1 and 25°C. 相似文献
993.
This paper presents a more detailed interaction of an electromagnetics light with a metallic surface-relief subwavelength grating utilizing the rigorous coupled-wave analysis. The focus of this work is the accurate modeling of undetermined aspects of diffraction patterns produced by binary metallic grating structures, specially gold grating. First-order diffraction efficiency for rectangular-groove gold grating with equal groove and ridge widths are presented for various wavelengths as a function of period, groove depth, polarization and angle of incidence. We also studied diffraction efficiency of both of TE and TM polarization modes against increasing of incident angle as well as TE polarization against increment of grating period. As a result, very low reflectivity at zero-order was found out for TE and TM polarizations at the pitch of Λ = 2λ. Having been studied diffraction efficiency of metallic surface-relief gratings, we also examined polarization-dependent efficiency of diffraction orders, for different groove depths. Simulation results have been completely presented. 相似文献
994.
Influence of roughness on the detection of mechanical characteristics of low-k film by the surface acoustic waves 下载免费PDF全文
The surface acoustic wave (SAW) technique is a precise and nondestructive method to detect the mechanical charac- teristics of the thin low dielectric constant (low-k) film by matching the theoretical dispersion curve with the experimental dispersion curve. In this paper, the influence of sample roughness on the precision of SAW mechanical detection is inves- tigated in detail. Random roughness values at the surface of low-k film and at the interface between this low-k film and the substrate are obtained by the Monte Carlo method. The dispersive characteristic of SAW on the layered structure with rough surface and rough interface is modeled by numerical simulation of finite element method. The Young's moduli of the Black DiamondTM samples with different roughness values are determined by SAWs in the experiment. The results show that the influence of sample roughness is very small when the root-mean-square (RMS) of roughness is smaller than 50 nm and correlation length is smaller than 20 μm. This study indicates that the SAW technique is reliable and precise in the nondestructive mechanical detection for low-k films. 相似文献
995.
本文采用一维流体模型导出了慢波介质自由电子激光器的线性色散方程,建立了电子和波相互作用的同向回旋同步机理和反向回旋同步机理. 相似文献
996.
997.
998.
短波近红外光谱法同时测定分析水中的麦芽糖、乳糖和蔗糖 总被引:1,自引:0,他引:1
用紫外-可见分光光度计的短波近红外光谱区域(800—1100nm),测量了3种二糖麦芽糖、乳糖和蔗糖混合水溶液的近红外光谱,并用偏最小二乘方法建立了同时定量分析水溶液中麦芽糖、乳糖和蔗糖的模型,并对光谱数据预处理方法进行了讨论。通过对校正集样品的建模和对预测集样品的检验,结果良好。对浓度范围分别在0—60mg·L^-1,0—12mg·L^-1,0—60mg·L^-1的麦芽糖、乳糖和蔗糖预测模型相关系数分别为0.9904、0.9971和0.9926,模型交叉检验均方差分别为0.0213、0.2525和0.1859。预测集相对标准偏差分别为3.54%、3.55%和3.32%。并将此模型应用在简单成份的实际样品中进行了初步探索。该方法对同时定量分析多组分体系,具有简便、快速价廉、易于推广应用等优点。 相似文献
999.
1000.
T. R. Amanbaev 《Journal of Applied Mechanics and Technical Physics》2003,44(5):634-639
The gas flow in plane shock waves slipping along an impermeable surface with a rectangular cavity where solid disperse particles are suspended is considered numerically. The motion of the gas and particles (gas suspension) is modeled by equations of mechanics of multiphase media. Some laws of the behavior of the dusty cloud in the cavity are established for the case of wave interaction with the cavity. 相似文献