温和条件下元素对M~(2+)/Fe~(2+)/Fe~(3+)-LDHs转化成尖晶石铁氧体过程的影响(英文)

研究了二价金属离子在温和条件下(低于100℃,暴露于空气中)从水滑石M2+/Fe2+/Fe3+-LDHs(M=Co,Ni,Mn,Zn)转化成尖晶石铁氧体的过程中所起的作用。结果表明,该转化过程不仅与晶化温度有关,还与M2+在元素周期表中所处的位置有关。当这些二价金属离子处于同一周期并且相邻较近时,M2+的半径越大,水滑石微晶向尖晶石铁氧体的转化就越容易。此外,Fe2+在转化过程中起着至关重要的作用,如果没有Fe2+的参与,在此条件下的转化将无法进行。     

二价与四价金属离子等摩尔共掺杂的锂离子电池正极材料LiMn1.9Mg0.05Ti0.05O4的制备与表征

以氢氧化锂、乙酸锰、硝酸镁和钛酸丁酯为原料, 以柠檬酸为螯合剂, 采用溶胶-凝胶法制备了二价镁离子与四价钛离子等摩尔共掺杂的尖晶石型锂离子电池正极材料LiMn_1.9Mg_0.05Ti_0.05O₄. 采用热重分析(TGA), X射线衍射(XRD), 扫描电子显微镜(SEM), 透射电子显微镜(TEM)和电化学性能测试(包括循环伏安(CV)和电化学交流阻抗谱(EIS)测试)对所得样品的结构、形貌及电化学性能进行了表征. 结果表明: 780℃下煅烧12 h 得到了颗粒均匀细小的尖晶石型结构的LiMn_1.9Mg_0.05Ti_0.05O₄材料, 该材料具有良好的电化学性能, 在室温下以0.5C倍率充放电, 在4.35-3.30 V电位范围内放电比容量达到126.8 mAh·g^-1, 循环50 次后放电比容量仍为118.5mAh·g^-1, 容量保持率为93.5%. 在55℃高温下循环30次后的放电比容量为111.9 mAh·g^-1, 容量保持率达到91.9%, 远远高于未掺杂的LiMn₂O₄的容量保存率. 二价镁离子与四价钛离子等摩尔共掺杂LiMn₂O₄, 改善了尖晶石锰酸锂的电子导电和离子导电性能, 使其倍率性能和高温性能都得到了明显的提高.     

铁酸铜负极材料的微波合成和电化学性能

以十六烷基三甲基溴化铵(CTAB)为模板,硝酸铁和硝酸铜为起始物,采用一步微波法,再经过简单的热处理制备了CuFe₂O₄负极材料,采用X射线粉末衍射(XRD)、扫描电子显微镜(SEM)、透射电子显微镜(TEM)、傅里叶红外光谱(FT-IR)等测试技术表征材料的结构和形貌。 电化学测试表明,在100 mA/g电流密度,0.01~3.0 V电压条件下,材料的首周嵌脱锂比容量分别为1202.2和873.2 mA·h/g,循环50周后,嵌锂比容量仍保持在近650 mA·h/g,显示出优异的电化学性能。     

铁酸钴纳米微粒的共沉淀法制备和磁性质(英)

The cobalt ferrite nanoparticles were prepared by coprecipitation in the presence of poly (N-vinylpyrrolidone) (PVP) and characterized by XRD, TEM, EDX and magnetometry. XRD results suggest the formation of pure cobalt ferrite. The mean particle sizes of CoFe₂O₄ samples annealed at 400 ℃ and 600 ℃ were ca. 6 and 25 nm, respectively as obtained by transmission electron microscopy (TEM). The magnetic measurements indicated that nano-particles obtained at 400 ℃ were superparamagnetic while that prepared at 600 ℃ were ferrimagnetic.     

尖晶石型LiMn2O4电池材料的元素掺杂

尖晶石型LiMn2O4正极材料因资源丰富、无毒、安全及制备简单、技术较成熟等优点而成为最具竞争力的新一代商用锂离子二次电池的正极材料之一.由于LiMn2O4的循环稳定性、高温(＞55℃)稳定性和大电流放电等因素限制了推广应用.本文从材料的结构组成对锂离子嵌脱过程的作用机理,论述了元素掺杂对尖晶石型LiMn2O4正极材料电化学特性的影响,指出了元素掺杂本体改性锰酸锂正极材料的方法和特点.     

磁化铁氧体覆盖二维导体目标FDTD分析的移位算子方法

采用移位算子方法把时域有限差分法推广应用于二维磁各向异性色散介质—磁化铁氧体中.证明了电磁波横向入射二维轴向磁化铁氧体目标情形下,电磁波可按目标的轴向分解为横电波(TE波)和横磁波(TM波),且TE波的散射特性与铁氧体介质无关,而TM波的散射特性与介质电磁参量密切相关,同时对其物理原因进行了分析.通过采用移位算子方法处理磁化铁氧体频域本构关系,得到该情形下目标电磁散射的移位算子时域有限差的迭代计算公式,同时解决了电磁波在各向异性和频率色散介质中传播的问题.计算了轴向磁化铁氧体涂敷VonKarman型导体柱的TM波双站雷达散射截面,分析了铁氧体参量对目标双站雷达散射截面的影响.结果表明:恰当地选择铁氧体参量能有效地减少目标的雷达散射截面,本文时谐因子取exp〔jωt〕.     

Influence of Co amount on the efficiency of energy absorption of Fe-Co ferrite nanoparticles

We present the chemical synthesis, structural characterization and efficiency of AC field energy absorption of Fe-Co ferrite particles sized between 35 and 100 nm and containing different cobalt amounts up to 3 wt%. Dynamic magnetic measurements in an AC field with frequency of 430 Hz and amplitude of up to 1200 Oe were performed for both solid and liquid dispersions of obtained particles. The energy absorption per one field cycle in function of the field amplitude and Co content was always bigger in liquid systems, under the same conditions, than in solid systems. The obtained results are of significance for the technology of low-frequency ferromagnetic hyperthermia of tumors.     

Nickel‐substituted cobalt ferrite nanoparticles supported on arginine‐modified graphene oxide nanosheets: Synthesis and catalytic activity

The amino acid arginine was used to modify the surface of graphene oxide nanosheets and then nickel‐substituted cobalt ferrite nanoparticles were supported on those arginine‐grafted graphene oxide nanosheets (Ni_0.5Co_0.5Fe₂O₄@Arg–GO). The prepared Ni_0.5Co_0.5Fe₂O₄@Arg–GO was characterized using flame atomic absorption spectroscopy, inductively coupled plasma optical emission spectrometry, energy‐dispersive spectroscopy, Fourier transform infrared spectroscopy, ultraviolet–visible spectroscopy, Raman spectroscopy, X‐ray diffraction, thermogravimetric analysis, scanning electron microscopy and transmission electron microscopy. The application of Ni_0.5Co_0.5Fe₂O₄@Arg–GO as a catalyst was examined in a one‐pot tandem oxidative cyclization of primary alcohols with o ‐phenylenediamine to benzimidazoles under aerobic oxidation conditions. The results showed that 2‐phenylbenzimidazole derivatives were successfully achieved using Ni_0.5Co_0.5Fe₂O₄@Arg–GO nanocomposite catalyst via the one‐pot tandem oxidative cyclization strategy.     

Multiferroic behaviour of epitaxial NiFe2O4--BaTiO3 heterostructures

Multiferroic NiFe2O4 （NFO）-BaTiO3 （BTO） bilayered thin films are epitaxially grown on （001） Nb-doped SrTiO3 （STO） substrates by pulsed-laser deposition （PLD）. Different growth sequences of NFO and BTO on the substrate yield two kinds of epitaxial heterostructures with （001）-orientation, i.e. （001）-NFO/（001）-BTO/substrate and （001）- BTO/（001）-NFO/substrate. Microstructure studies from x-ray diffraction （XRD） and electron microscopies show differences between these two heterostructures, which result in different multiferroic behaviours. The heterostructured composite films exhibit good coexistence of both ferroelectric and ferromagnetic properties, in particular, obvious magnetoelectric （ME） effect on coupling response.     

Modeling of the DTG Curves for Oxidation of a Nanosized Molybdenum Ferrite Coupling Mechanics and Diffusion

From a model for isothermal oxidation kinetics in nanosized ferrite spinels based on a diffusion-induced stress effect, the authors present a modeling of the DTG curves for the oxidation of Fe²⁺ and Mo³⁺ cations on octahedral sites of a molybdenum ferrite. This has been made by considering that the chemical diffusion coefficient is given by the relation , when D _o is a pre-exponential factor, E _a ^′ an activation energy and V _a an activation energy induced by the oxidation. This revised version was published online in July 2006 with corrections to the Cover Date.