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941.
HU Qiao-Sheng HU Chang-MingLaboratory of Organofluorine Chemistry Shanghai Institute of Organic Chemistry Chinese Academy of Sciences Shanghai China 《中国化学》1997,15(3):286-288
Initiated by CrCl3/Fe redox couple, per(poly)fluoroalkyl iodides added to methyl a-acetylamino acrylate, giving B-per(poly)fluoroalkyl a-amino acid derivatives in good yields. 相似文献
942.
惯性约束中子测温的误差研究 总被引:1,自引:0,他引:1
综合分析了ICF(惯性约束)中子测温系统的误差与其参数的关系,这些参数包括靶核温度,探测的中子数、靶到探测器的距离、探测器的响应函数以及闪烁体厚度等,考虑到中子与探测器的相互作用,探测器的响应与靶的烧蚀过程,在此基础上提出了新的统计误差计算方法,该方法对于改善中子测温的相对误差并应用于闪烁体的设计具有重要意义。 相似文献
943.
T. Charitat B. Fourcade 《The European Physical Journal B - Condensed Matter and Complex Systems》1998,1(3):333-336
An o-ring takes spontaneously the shape of a chair when strong enough torsion is applied in its tangent plane. This state
is metastable, since work has to be done on the o-ring to return to the circular shape. We show that this metastable state
exists in a Hamiltonian where curvature and torsion are coupled via an intrinsic curvature term. If the o-ring is constrained to be planar (2d case), this metastable state displays a kink-anti-kink
pair. This state is metastable if the ratio is less than , where C and A are the torsion and the bending elastic constants [#!landau!#]. In three dimensions, our variational approach shows that
. This model can be generalized to the case where the bend is induced by a concentration field which follows the variations
of the curvature.
Received: 27 August 1997 / Revised: 23 October 1997 / Accepted: 12 November 1997 相似文献
944.
Polyethyleneimine (PEIM) samples crosslinked by a commercial epoxy resin (Epon 828) were prepared, and their adsorption capacity for acidic gases was studied. The swelling and deswelling characteristics of the crosslinked samples were also examined as part of this program. Reactivation of these adsorbents could be carried out by heat, or by a combination of heat and treatment in dilute alkalies. 相似文献
945.
本文采用高压X光衍射方法在金刚石对顶压砧中在位地(in situ)研究了Fe68Co24Ni8(wt%)合金在室温下的压致bcc→hcp结构相变和直到40.5 GPa的等温压缩行为。实验结果表明该合金在常压下为bcc结构,晶格常数a0=(0.287 0±0.000 1) nm,体积V0=(7.119±0.007) cm3/mol,密度ρ0=(7.981±0.008) g/cm3;在20.9 GPa附近出现bcc→hcp结构相变,两相共存压力区约10 GPa,在此区域内有晶面间距d(002)hcp=d(110)bcc,且原子平面(002)hcp//(110)bcc,hcp相比bcc相体积减小(0.33±0.02) cm3/mol;高压相hcp结构的晶格参数比值c/a=1.608±0.004;相变后原子配位数的增加使得hcp相(002)平面内及(002)平面间的最近邻原子间距比bcc相最近邻原子间距分别增大约1.6%和0.5%;用Murnaghan状态方程对实验数据进行最小二乘法拟合,得到bcc相B0=(130±13) GPa,B0'=12.6±0.5;hcp相V0=(6.62±0.04) cm3/mol,B0=(243±21) GPa,B0'=6.8±0.3;对于该合金的bcc→fcp相变时的结构转变机制做了详细的讨论。 相似文献
946.
Summary. This paper introduces and analyzes the convergence properties of a method that computes an approximation to the invariant
subspace associated with a group of eigenvalues of a large not necessarily diagonalizable matrix. The method belongs to the
family of projection type methods. At each step, it refines the approximate invariant subspace using a linearized Riccati's
equation which turns out to be the block analogue of the correction used in the Jacobi-Davidson method. The analysis conducted
in this paper shows that the method converges at a rate quasi-quadratic provided that the approximate invariant subspace is
close to the exact one. The implementation of the method based on multigrid techniques is also discussed and numerical experiments
are reported.
Received June 15, 2000 / Revised version received January 22, 2001 / Published online October 17, 2001 相似文献
947.
阐述了紫外无机非线性光学晶体分子工程学探索方法的基本特点,具体分析深紫外无机非线性光学晶体硼铍酸锶(SBBO)以氟硼铍酸钾(KBBF)为主要参考晶体的分子设计方法,随后根据晶体结构研究、单晶培养、和非线性光学性能测定等实验结果讨论SBBO作为新型深紫外无机晶体的主要优点,即它既具有更短的紫外吸收边(接近155nm)和较大的非线性光学系数(d22(SBBO)=06×d22(BBO)=138pm/V),同时晶体无明显层状习性,并肯有良好的化学稳定性和机械性能 相似文献
948.
测量了Cr^4+,YAG、Cr^4+,Mg2SiO4晶体在室温和液氮温度下的荧光光谱,吸收光谱和激发态寿命,讨论了温度变化时,两种晶体中Cr^4+近红外辐射积分强度变化与激光发态寿命变化的关系,得出结论:在77K ̄300K范围内,Cr^4+的^3T2能级荧光辐射截面本身受温度影响不大,Cr^4+辐射荧光的变化,主要是由无辐射弛豫速率随温度变化而引起的。 相似文献
949.
The electron-stimulated desorption (ESD) of D− and H− ions from condensed D2O and H2O films is investigated. Three low-energy peaks are observed in the ESD anion yield, which are identified as arising from excitation of 2B1, 2A1 and 2B2 dissociative electron attachment (DEA) resonances. Additional structure is observed between 18 and 32 eV, which may be due to ion pair formation or to DEA resonances involving the 2a1 orbital. The ion yield resulting from excitation of the 2B1 resonance increases as the film is heated. We attribute the increase in the ion yield to thermally induced hydrogen bond breaking near the surface, which enhances the lifetimes of the excited states that lead to desorption. 相似文献
950.
A multidimensional version of the first Darboux problem is considered for a model second-order degenerating hyperbolic equation. Using the technique of functional spaces with a negative norm, the correct formulation of this problem in the Sobolev weighted space is proved. 相似文献