全文获取类型
收费全文 | 1930篇 |
免费 | 26篇 |
国内免费 | 296篇 |
专业分类
化学 | 1915篇 |
晶体学 | 23篇 |
力学 | 6篇 |
综合类 | 1篇 |
数学 | 3篇 |
物理学 | 304篇 |
出版年
2024年 | 1篇 |
2023年 | 33篇 |
2022年 | 29篇 |
2021年 | 30篇 |
2020年 | 35篇 |
2019年 | 37篇 |
2018年 | 39篇 |
2017年 | 35篇 |
2016年 | 45篇 |
2015年 | 42篇 |
2014年 | 82篇 |
2013年 | 106篇 |
2012年 | 112篇 |
2011年 | 111篇 |
2010年 | 112篇 |
2009年 | 127篇 |
2008年 | 129篇 |
2007年 | 132篇 |
2006年 | 122篇 |
2005年 | 122篇 |
2004年 | 120篇 |
2003年 | 81篇 |
2002年 | 66篇 |
2001年 | 54篇 |
2000年 | 49篇 |
1999年 | 58篇 |
1998年 | 40篇 |
1997年 | 38篇 |
1996年 | 44篇 |
1995年 | 42篇 |
1994年 | 34篇 |
1993年 | 33篇 |
1992年 | 24篇 |
1991年 | 16篇 |
1990年 | 14篇 |
1989年 | 17篇 |
1988年 | 12篇 |
1987年 | 2篇 |
1986年 | 6篇 |
1985年 | 4篇 |
1984年 | 1篇 |
1983年 | 2篇 |
1982年 | 3篇 |
1981年 | 2篇 |
1980年 | 2篇 |
1977年 | 1篇 |
1974年 | 3篇 |
1973年 | 1篇 |
1972年 | 1篇 |
1971年 | 1篇 |
排序方式: 共有2252条查询结果,搜索用时 15 毫秒
991.
Nobukazu Taniguchi 《Tetrahedron》2018,74(13):1454-1460
Cobalt-catalyzed iodosulfonylation of alkynes can be achieved using sodium sulfinates in the presence of KI. This procedure produces numerous stereoselective (E)-β-iodoalkenyl sulfones with good yields and suppresses the formation of diiodoalkenes. Furthermore, when this reaction is performed in the absence of sodium sulfinates, the expected (E)-diiodoalkenes are obtained. 相似文献
992.
Lingxian Liu Zengguang Li Changjun Chen Huanrong Li Lijin Xu Zhiyong Yu 《Tetrahedron》2018,74(20):2447-2453
An efficient protocol for dealkylation of aryl alkyl ethers under the catalysis of inexpensive and easily reusable Cu2O has been described. The phenol products were obtained in high yields, and a range of functional groups were well tolerated. The choice of solvent is critical to the catalysis, and CH3OH proved to be the optimal choice. Mechanistic investigations showed that this reaction possibly proceeds via a single-electron transfer (SET) process. 相似文献
993.
A newly developed chemoselective reaction of sodium arylsulfinates or arylsulfonyl chlorides with nitroarenes has been disclosed. The chemistry, in which non-toxic water and recyclable iron-based metal-organic frameworks are employed as the solvent and catalyst, respectively, provides an efficient approach for the generation of N-arylsulfonamides, which are widely present in biologically active compounds and drugs, rendering this methodology attractive to both synthetic and medicinal chemistry. 相似文献
994.
Graham E. Jackson Keith Wilson Susan A. Bourne 《Journal of chemical crystallography》1998,28(3):213-216
The crystal structure of the 2:1 sodium perchlorate · diethylene glycol complex has been determined by single crystal X-ray diffraction. It crystallizes in space group P21212 with a = 7.853(3), b = 7.900(2), c = 10.120(2) Å and Z = 2. Both the sodium ion and the diethylene glycol molecule are disordered, and were modeled with partial site occupancy factors. One sodium position is 7-coordinate and the other is 8-coordinate. The sodium perchlorate ions pack in layers parallel to [100] and [010], with the glycol molecules in channels between layers. 相似文献
995.
Roger H. Mitchell 《Journal of solid state chemistry》2005,178(9):2586-2593
The ternary stoichiometric perovskite compounds, Na0.75Ln0.25Ti0.5Nb0.5O3 (Ln=La, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm) are intermediate members of the NaNbO3-Na0.5Ln0.5TiO3 solid solution series. The compounds were synthesized by standard ceramic methods at 1300 °C followed by annealing at 800 °C and quenching to ambient conditions. Rietveld analysis of the powder X-ray diffraction patterns shows that the compounds with Ln ranging from Pr to Tm adopt the orthorhombic space group Pbnm (a≈b≈√2ap; c≈2ap; Z=4) and the GdFeO3 structure. In contrast, Na0.75La0.25Ti0.5Nb0.5O3 adopts the orthorhombic space group Cmcm (a≈b≈c≈2ap; Z=4). All cations located at the A- and B-sites are disordered in these compounds. The unit cell parameters and cell volumes of the compounds decrease regularly with increasing atomic number of the Ln cation. The Pbnm compounds with Ln from Sm to Tm have A-site cations in eight-fold coordination. A-site cations in the Pr and Nd compounds are considered to be in ten-fold coordination. Analysis of the crystal chemistry of the Pbnm compounds shows that B-site cations enter the second coordination sphere of the A-site cations for compounds with Ln from Tb to Tm as the A-B intercation distances are less than the maximum A-IIO(2) bond lengths. The [111] tilt angles of the (Ti,Nb)O6 polyhedra in the Pbnm compounds increase with increasing atomic number from 11.1° to 15.8° and are less than those observed in lanthanide orthoferrite and orthoscandate perovskites. These data are considered as relevant to the sequestration of lanthanide fission products in perovskite and the structure of lanthanide-bearing perovskite-structured minerals. 相似文献
996.
Jacek ?cianowski 《Tetrahedron letters》2005,46(19):3331-3334
A one-step method for the synthesis of dialkyl diselenides, by reaction of alkyl tosylates with sodium diselenide is described. Three variants of the synthesis, using as an example the preparation of optically active di(cis-myrtanyl) diselenide, are compared. 相似文献
997.
998.
Sha Peng Yan-Xi Song Jun-Yi He Shan-Shan Tang Jia-Xi Tan Zhong Cao Ying-Wu Lin Wei-Min He 《中国化学快报》1990,30(12):2287-2290
An eco-friendly protocol for the synthesis of various 2-sulfonyl quinolines/pyridines through sulfonylation of heteroaromatic N-oxides with sodium sulfinates in water under metal-and oxidant-free conditions has been developed. The high reaction efficiency, operational simplicity, short reaction time, air-and moisture-insensitive conditions and remarkable functional group compatibility make the developed protocol very attractive for the preparation of 2-sulfonyl N-heteroaromatic compounds. 相似文献
999.
1000.
The metal-support interaction in the system of platinum supported on titanium oxides of different crystalline structures was investigated. Titanium oxide powders used as supports were prepared by neutralization of TiOCl2-analogue solution with either NaOH or NH3 base at varied pH. Pt was introduced onto the supports by impregnation. The phenomenon of strong metal-support interaction (SMSI) was determined by the suppression of chemisorption of H2 over samples reduced at 773 K, in comparison with the behavior of samples reduced at 473 K. The loss of adsorption capacity was proved not due to metal sintering by examining the recovery of adsorption capacity after reduction, reoxidation and reduction cycle, accompanied with examination of the size of Pt particle with an x-ray diffractiometer and a transmission-electron microscope. The results showed that SMSI phenomenon was common to Pt supported on titanium oxides of all the varied crystalline structures. However, the chemisorption capacity of Pt reduced at 473 K varied greatly with the sodium content in the supports, which in turns affects the crystalline structure of titanium oxide. These results are attributed mainly to electronic effect endowed by the support. 相似文献