全文获取类型
收费全文 | 6022篇 |
免费 | 222篇 |
国内免费 | 696篇 |
专业分类
化学 | 5009篇 |
晶体学 | 94篇 |
力学 | 39篇 |
综合类 | 27篇 |
数学 | 606篇 |
物理学 | 1165篇 |
出版年
2024年 | 5篇 |
2023年 | 61篇 |
2022年 | 163篇 |
2021年 | 125篇 |
2020年 | 105篇 |
2019年 | 213篇 |
2018年 | 269篇 |
2017年 | 106篇 |
2016年 | 142篇 |
2015年 | 119篇 |
2014年 | 201篇 |
2013年 | 359篇 |
2012年 | 257篇 |
2011年 | 333篇 |
2010年 | 324篇 |
2009年 | 436篇 |
2008年 | 399篇 |
2007年 | 388篇 |
2006年 | 362篇 |
2005年 | 334篇 |
2004年 | 325篇 |
2003年 | 226篇 |
2002年 | 269篇 |
2001年 | 170篇 |
2000年 | 130篇 |
1999年 | 121篇 |
1998年 | 112篇 |
1997年 | 89篇 |
1996年 | 107篇 |
1995年 | 95篇 |
1994年 | 104篇 |
1993年 | 93篇 |
1992年 | 72篇 |
1991年 | 44篇 |
1990年 | 40篇 |
1989年 | 36篇 |
1988年 | 33篇 |
1987年 | 18篇 |
1986年 | 21篇 |
1985年 | 13篇 |
1984年 | 14篇 |
1983年 | 7篇 |
1982年 | 13篇 |
1981年 | 15篇 |
1980年 | 12篇 |
1979年 | 16篇 |
1978年 | 11篇 |
1977年 | 8篇 |
1976年 | 8篇 |
1974年 | 5篇 |
排序方式: 共有6940条查询结果,搜索用时 15 毫秒
91.
We present the optical emission characteristics of the sodium plasma produced at the surface of sodium nitrate (NaNO3) also known as Chile saltpeter. We used a Q-switched Nd:YAG (Quantel Brilliant) pulsed laser having a pulse duration of 5?ns and 10?Hz repetition rate which is capable of delivering 400?mJ at 1064?nm and 200?mJ at 532?nm. The target material was placed in front of laser beam in air (atmospheric pressure). The experimentally observed line profiles of neutral sodium have been used to extract the electron temperature using the Boltzmann plot method, whereas the electron number density has been determined from the Stark broadening. The electron temperature is calculated by varying the distance from the target surface along the line of propagation of the plasma plume and also by varying the laser irradiance. Besides, we have studied the variation of number density as a function of laser irradiance as well as its variation with the distance from the target surface. It is observed that electron temperature and electron number density increase as the laser irradiance is increased. 相似文献
92.
93.
阐述了紫外无机非线性光学晶体分子工程学探索方法的基本特点,具体分析深紫外无机非线性光学晶体硼铍酸锶(SBBO)以氟硼铍酸钾(KBBF)为主要参考晶体的分子设计方法,随后根据晶体结构研究、单晶培养、和非线性光学性能测定等实验结果讨论SBBO作为新型深紫外无机晶体的主要优点,即它既具有更短的紫外吸收边(接近155nm)和较大的非线性光学系数(d22(SBBO)=06×d22(BBO)=138pm/V),同时晶体无明显层状习性,并肯有良好的化学稳定性和机械性能 相似文献
94.
Saim Özkar 《Applied Surface Science》2009,256(5):1272-1277
The use of nanoclusters in systems with confined void spaces such as inside mesoporous or microporous solids appears to be an efficient way of preventing aggregation of nanoclusters in their catalytic application. Zeolite-Y is considered as a suitable host providing highly ordered supercages with a diameter of 1.3 nm. Intrazeolite metal(0) nanoclusters were prepared at room temperature by ion-exchange of metal cations with the extra framework Na+ ions in Zeolite-Y, followed by the reduction of the metal cations in the cavities of Zeolite-Y with sodium borohydride in aqueous solution, whereby the Zeolite-Y is reloaded with Na+ ions. Hence, host framework remains intact as shown by using a multi-prong approach. Intrazeolite transition-metal(0) nanoclusters were isolated by suction filtration and drying in vacuum at room temperature and characterized by a combination of analytical methods. Intrazeolite metal(0) nanoclusters were tested as catalyst in the hydrolysis of sodium borohydride and ammonia-borane, both of which have been considered as a promising hydrogen storage materials. High catalytic activity and the outstandingly long lifetime of intrazeolite transition-metal(0) nanoclusters catalyst in the hydrogen generation from the hydrolysis of both sodium borohydride and ammonia-borane is demonstrated. The results are attributed to the small size of the nanoclusters within the zeolite cages as well as prevention of agglomeration of the nanoclusters. 相似文献
95.
Carlo Cavallotti Marco Derudi Renato Rota 《Proceedings of the Combustion Institute》2009,32(1):115-121
The C7H7 potential energy surface was studied from first principles to determine the benzyl radical decomposition mechanism. The investigated high temperature reaction pathway involves 15 accessible energy wells connected by 25 transition states. The analysis of the potential energy surface, performed determining kinetic constants of each elementary reaction using conventional transition state theory, evidenced that the reaction mechanism has as rate determining step the isomerization of the 1,3-cyclopentadiene, 5-vinyl radical to the 2-cyclopentene,5-ethenylidene radical and that the fastest reaction channel is dissociation to fulvenallene and hydrogen. This is in agreement with the literature evidences reporting that benzyl decomposes to hydrogen and a C7H6 species. The benzyl high-pressure decomposition rate constant estimated assuming equilibrium between the rate determining step transition state and benzyl is k1(T) = 1.44 × 1013T0.453exp(−38400/T) s−1, in good agreement with the literature data. As fulvenallene reactivity is mostly unknown, we investigated its reaction with hydrogen, which has been proposed in the literature as a possible decomposition route. The reaction proceeds fast both backward to form again benzyl and, if hydrogen adds to allene, forward toward the decomposition into the cyclopentadienyl radical and acetylene with high-pressure kinetic constants k2(T) = 8.82 × 108T1.20exp(1016/T) and k3(T) = 1.06 × 108T1.35exp(1716/T) cm3/mol/s, respectively. The computed rate constants were then inserted in a detailed kinetic mechanism and used to simulate shock tube literature experiments. 相似文献
96.
建立了一种反相高效液相色谱法测定2-硝基芴酮含量的方法。液相色谱条件为:EliteHypersil ODS2C18色谱柱(4.6mm×250mmi.d.,5μm),甲醇-四氢呋喃-水为流动相(体积比为65∶15∶35)。在流速1.0mL/min,检测波长254nm,柱温25℃条件下,产物2-硝基芴酮与原料芴酮、副产物2,7-二硝基芴酮在2-硝基芴酮浓度为5—30mg/L范围内分离效果良好,峰面积与质量浓度呈良好的线性关系,相关系数为0.9985;平均回收率值大于99.00%,相对标准偏差小于1.00%。结果表明,该方法具有操作简便、精密度和准确性高的特点,可适用于工业生产2-硝基芴酮含量的测定。 相似文献
97.
在表面活性剂十二烷基苯磺酸钠(SDBS)存在下,传统意义上的自由基清除剂甲酸钠反而对铬酸钾一鲁米诺-腺嘌呤化学发光体系表现出了很好的化学发光增敏效果,文章通过化学发光发射光谱,紫外可见光谱及化学反应等手段探讨了这一化学发光体系的增敏机理,结果表明:化学发光体系的增敏是由于反应体系中甲酸钠的存在使原有发光体系中的羟基自由基(OH·)转化为氧自由基(O2·)所致.以此为基础建立了流动注射化学发光法测定腺嘌呤的高灵敏方法,腺嘌呤在2.45×10-11~8.18×10-9 mol·L-1范围内成良好的线性关系(R2=0.999 3),检出限为8.72×10-12 mol·L-1.该法已成功用于测定维生素B4药品中的腺嘌呤的含量,结果令人满意. 相似文献
98.
Y. Zhang M. Izumi Y. Kimura Y. Xu 《Physica C: Superconductivity and its Applications》2009,469(15-20):1169-1172
We have succeeded in synthesizing a powder form of Gd2Ba4CuFeOy (Gd2411) in air. GdBa2Cu3O7−δ (Gd123)/Gd2BaCuO5 (Gd211) precursor powders added with different amounts of Gd2Ba4CuFeOy (x = 0, 0.002, 0.004, 0.02) in molar ratio to Gd123 have been fabricated successfully into the form of large, single grains by the top seeded melt growth (TSMG) process. The relation between the additions amounts of Gd2411/Gd211 and critical current density (JC) was analyzed. We found Gd2411 particles stably exist in the Gd123 matrix without degradation of superconducting properties owing to the existence of the Fe magnetic ion. The trapped field was observed to increase significantly compared with the bulk without Gd2411 additions. 相似文献
99.
间接原子吸收光谱法测定氢溴酸山莨菪碱 总被引:3,自引:0,他引:3
研究了原子吸收光谱法间接测定氢溴酸山莨菪碱。在溶液pH为 5 1~ 5 3,当四苯硼钠过量时可完全沉淀氢溴酸山莨菪碱 ;加入过量的氯化钾沉淀滤液中剩余的四苯硼钠 ;干过滤 ,用原子吸收分光光度计在76 6 5nm波长下测定滤液中过量的钾 ,因四苯硼钠与氢溴酸山莨菪碱和氯化钾均按 1∶1的计量关系生成沉淀 ,可以直接计算得到氢溴酸山莨菪碱的含量。对氢溴酸山莨菪碱注射液进行了测定 ,测定结果准确。方法简单快速 ,回收率在 96 %~ 10 3%之间 ,相对标准偏差为 1 4 %。该方法可进一步推广原子吸收光谱法在其他相关药物测定方面的应用。 相似文献
100.
阿莫西林的荷移光谱测定方法研究 总被引:6,自引:0,他引:6
在丙酮介质中阿莫西林与 7,7,8,8-四氰基对二次甲基苯醌 (TCNQ)荷移反应 ,形成 1∶ 1络合物 ,在74 4nm和 84 5 nm处有较强光吸收 ,表观摩尔吸光系数分别为 1.2× 10 4L· mol-1· cm-1和 1.8× 10 4L·mol-1· cm-1,阿莫西林的浓度在 10— 15 0 mg· L-1范围内符合比耳定律。在乙醇介质中 ,阿莫西林与对苯醌 (p- BQ)反应 ,形成 1∶ 1络合物 ,最大吸收波长为 4 80 nm,表观摩尔吸光系数为 1.92× 10 3 L· mol-1·cm-1。阿莫西林的浓度在 2 0— 2 0 0 mg·L-1范围内符合比耳定律。两种方法相对标准偏差分别为 1.2 %和1.5 % (n=8) ,用于测定阿莫西林制剂的含量 ,结果与标准方法一致。 相似文献