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51.
52.
Shabbir Hussain Saira Shahzadi Muhammad Shahid Asif Ali Tahir Syed Mustansar Abbas 《Journal of Coordination Chemistry》2017,70(24):4070-4092
Bimetallic chlorodi-/triorganotin(IV) derivatives of general formulas R2(H2O)SnLCSSSn(Cl)R2 (R=Me: 1; Ph: 2) and R3Sn(Na)LCSSSnR3·H2O (R=Bu: 3; Ph: 4) were prepared by reaction of iminodiacetic acid disodium salt hydrate (Na2LH) with CS2 and R2SnCl2/R3SnCl in methanol. The reaction between Na2LH, CS2, and PdCl2 produced [Na2LCSS]2Pd·2H2O (5) which was treated with R3SnCl to synthesize the heterobimetallic derivatives [R3Sn(Na)LCSS]2Pd·2H2O (R=Me: 6; Ph: 7). The complexes were characterized by microanalysis, spectroscopic, and thermogravimetric analyses. Elemental analysis data, mass fragmentation, and thermal degradation patterns supported the molecular composition of the complexes. FT-IR data indicated monodentate binding of carboxylate while a chelating coordination mode of the dithiocarboxylate was verified in the solid state. A five-coordinate tin(IV) was demonstrated in the solid state. In solution, a tetrahedral/trigonal bipyramidal configuration around Sn(IV) and a square planar geometry of Pd(II) was indicated by multinuclear NMR (1H and 13C) and UV-visible studies. The Pd(II) derivatives showed interaction with salmon sperm-DNA and caused an inhibition of alkaline phosphatase (ALPs). The antibacterial/antifungal potential of the coordination products varied with the nature of incorporated metal and a substitution pattern at tin(IV); the palladium metallation decreased the antimicrobial activities. The triorganotin(IV) products exhibited more powerful action against bacteria/fungi as compared to their diorganotin(IV) counterparts. The complexes displayed sufficiently lower hemolytic effects in vitro as compared to triton X-100 and slightly higher than PBS. 相似文献
53.
Maura Pellei Carlo Santini Giancarlo Gioia Lobbia Franco Cantalamessa Cinzia Nasuti Mariacristina Di Prinzio Rosita Gabbianelli Giancarlo Falcioni 《应用有机金属化学》2005,19(5):583-589
New organotin(IV) derivatives containing the anionic ligands bis(3,5‐dimethylpyrazol‐1‐yl)dithioacetate [LCS2]− and bis(3,5‐dimethylpyrazol‐1‐yl)acetate [LCO2]− have been synthesized from reaction between (CH3)2SnCl2 and lithium salts of the ligands. Mononuclear complexes of the type {[LCX2](CH3)2SnCl} (X = S or O) have been obtained and fully characterized by elemental analyses and FT‐IR in the solid state and by NMR (1H, 13C and 119Sn) spectroscopy, conductivity measurements and electrospray ionization mass spectrometry in solution. The acute toxicity of new organotin(IV) derivatives on rat was studied, comparing their effect with those of dimethyltin chloride (CH3)2SnCl2. The comparison of LD50 of organotin(IV) complexes and (CH3)2SnCl2 administered intraperitoneally, as a single dose, evaluated in vivo on rats, showed that toxicity decreases as follows: (CH3)2SnCl2 > LCO2 > LCS2. The effect of these organotin(IV) complexes on DNA was evaluated in vitro and in vivo on rats treated with different doses of these compounds (1/20 LD50 and 1/100 LD50). The lymphocyte DNA status was assessed by the comet assay, a rapid and sensitive single‐cell electrophoresis technique, used to detect primary DNA damage in individual cells. After 36 h from the start of treatment the two new organotin(IV) derivatives induced a significant rise in comet assay parameters, indicating an increasing presence of damaged DNA. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
54.
Christian Mazza 《Probability Theory and Related Fields》1999,113(2):171-190
We consider the ±J spin glass on a finite graph G=(V,E), with i.i.d. couplings. Our approach considers the Z
2 local gauge invariance of the system. We see the gauge group as a graph theoretic linear code ? over GF(2). The gauge is fixed by choosing a convenient linear supplement of ?. Assuming some relation between the disorder parameter
p and the inverse temperature of the thermal bath β
pb
, we study percolation in the random interaction random cluster model, and extend the results to dilute spin glasses.
Received: 5 May 1997 / Revised version: 9 April 1998 相似文献
55.
56.
Raúl?E.?CurtoEmail author Lawrence?A.?Fialkow 《Integral Equations and Operator Theory》2004,50(2):169-196
Given real numbers
with 00 >0 , the truncated parabolic moment problem for entails finding necessary and sufficient conditions for the existence of a positive Borel measure , supported in the parabola p(x, y) = 0, such that
We prove that admits a representing measure (as above) if and only if the associated moment matrix
is positive semidefinite, recursively generated and has a column relation p(X, Y) = 0, and the algebraic variety () associated to satisfies card
In this case, admits a rank
-atomic (minimal) representing measure.Submitted: August 25, 2003 相似文献
57.
3H-Perfluoroalk-2-enes react with aqueous ammonia to form polyfluorinated iminoenamines, from which hexafluoroacetylacetone and its analogs were synthesized. 相似文献
58.
D. Stauffer A. Aharony L. da Fontoura Costa J. Adler 《The European Physical Journal B - Condensed Matter and Complex Systems》2003,32(3):395-399
Neural networks are supposed to recognise blurred images (or patterns) of N pixels (bits) each. Application of the network to an initial blurred version of one of P pre-assigned patterns should converge to the correct pattern. In the “standard" Hopfield model, the N “neurons” are connected to each other via N2 bonds which contain the information on the stored patterns. Thus computer time and memory in general grow with N2. The Hebb rule assigns synaptic coupling strengths proportional to the overlap of the stored patterns at the two coupled
neurons. Here we simulate the Hopfield model on the Barabási-Albert scale-free network, in which each newly added neuron is
connected to only m other neurons, and at the end the number of neurons with q neighbours decays as 1/q
3. Although the quality of retrieval decreases for small m, we find good associative memory for 1 ≪ m ≪ N. Hence, these networks gain a factor N/m ≫ 1 in the computer memory and time.
Received 12 January 2003 Published online 11 April 2003
RID="a"
ID="a"e-mail: stauffer@thp.uni-koeln.de 相似文献
59.
Lin Qingquan 《高校应用数学学报(英文版)》2000,15(3):289-296
In this paper the existence and uniqueness of the smallest g-supersolution for BSDE is discussed in the case without Lipschitz condition imposing on both constraint function and drift
coefficient in the different method from the one with Lipschitz condition. Then by considering (ξ, g) as a parameter of BSDE, and (ξ
α, g
α) as a class of parameters for BSDE, where α belongs to a set
, for every
there exists a pair of solution {Y
a, Za} for the BSDE, the properties of
which is also a solution for some BSDE is studied. This result may be used to discuss optimal problems with recursive utility.
This work was supported by NSFC (79790130) 相似文献
60.
Elena Cordero Stevan Pilipović Luigi Rodino Nenad Teofanov 《Mediterranean Journal of Mathematics》2005,2(4):381-394
We study localization operators within the framework of ultradistributions. More precisely, given a symbol a and two windows φ1, φ2, we investigate the multilinear mapping from
to the localization operator
Results are formulated in terms of modulation spaces with weights which may have exponential growth. We give sufficient and
necessary conditions for
a to be bounded or to belong to a Schatten class. As an application, we study symbols defined by ultra-distributions with
compact support, that give trace class localization operators. 相似文献