数字微镜近红外光谱仪光学系统设计与实验

针对传统光谱仪体积大、成本高、检测速度慢、需样品前处理等不足,提出了利用数字微镜面阵(DMD)实现光谱谱面分割分时选通的近红外光谱仪光学系统.首先,对比传统光路介绍单探测器微型光谱仪系统测量原理;然后结合DMD特性提出光路方案,根据几何光学原理进行初步光学元件选型和光路结构设计,利用ZEMAX光学软件对光路进行仿真,确...     

Luminescence properties of Y3Al5O12:Ce nanoceramics

Comparative analysis of the luminescent properties of Y₃Al₅O₁₂:Ce (YAG:Ce) transparent optical ceramics (OС) with those of single crystal (SC) and single crystalline film (SCF) analogues has been performed under excitation by pulsed synchrotron radiation in the fundamental absorption range of YAG host. It has been shown that the properties of YAG:Ce OC are closer to the properties of the SCF counterpart, where Y_Al antisite defects are completely absent, rather than to the properties of SC of this garnet with large concentration of Y_Al antisite defects. At the same time, the luminescence spectra of YAG:Ce OC show weak emission bands in the 200-470 nm range related to Y_Al antisite defects and charged oxygen vacancies (F⁺ and F centers). YAG:Ce ОС also possesses significantly larger contribution of slow components in the Ce³⁺ luminescence decay under high-energy excitation in comparison with SC and SCF of this garnet due to the involvement of antisite defects, charged oxygen vacancies as well as boundaries of grains in the energy transfer processes from the host to the Ce³⁺ ions.     

宽量程高时间分辨扫描变像管

 为改善大偏转角度的偏转像质,设计了一种高时间分辨、大扫描长度的扫描变像管电子光学和行波偏转系统。对变像管后加速技术进行了实验研究,结合图像外增强技术,解决了大面积扫描图像的探测灵敏度问题,达到了同时扩展扫描变像管的时间量程和提高时间分辨力的目的,研制出了宽时间量程、高时间分辨力的扫描变像管。初步实验表明,在量程为5 ns时,时间分辨力达到5 ps,也就是时间分辨力与时间量程之比达到1/1 000。     

Spin-spin coupling edition in chiral liquid crystal NMR solvent

The application of the G-SERFph pulse sequence is presented on enantiomeric mixtures dissolved in a chiral liquid crystal. It aims at editing, within one single 2D spectrum, every proton coupling which is experienced by a given proton site in the molecule, and leads to real phased T-edited spectroscopy (T=J+2D). This NMR experiment is based on the combination of homonuclear semi-selective refocusing techniques with a spatial frequency encoding of the sample. This approach, which consists in handling selectively each coupling in separate cross sections of the sample, is applied to the visualization of enantiomers dissolved in a chiral liquid crystalline phase. Advantages and limits of this methodology are widely discussed.     

Refractive index, birefringence, third-order non-linearity and piezoelectric resonance studies of L-lysine monohydrochloride dihydrate single crystals

The principal refractive indices of L-lysine monohydrochloride dihydrate (L-LMHCl) single crystal for different wavelengths were measured by minimum deviation method at room temperature. The experimental values of refractive indices fit well with the theoretical Cauchy's equations. The birefringence and the crossing angle between the optical axes were calculated. The parameters of Sellmeier's single term dispersion equation were determined by least square method. A simple interferometric technique was used to observe the interference patterns along the optic plane and to qualitatively analyze the optical homogeneity of the grown crystal. The nonlinear refractive index (n₂) and nonlinear absorption coefficient (β) were also determined using Z-scan technique. The piezoelectric resonance in dielectric dispersions was observed at room temperature.     

Growth, optical, mechanical and dielectric studies on NLO active pure and metal ion doped single crystals of bis-thiourea zinc chloride

Good quality single crystals of pure and metal ion (Ni²⁺) doped bis-thiourea zinc chloride (BTZC) possessing excellent nonlinear optical properties have been grown from aqueous solution by the slow solvent evaporation technique. The lattice parameters of the grown crystals are determined by single crystal X-ray analysis. The well defined sharp peaks in the powder X-ray diffraction pattern reveals the crystalline perfection and the EDAX spectrum confirms the presence of dopant in the lattice of the parent crystal. The DRS UV-visible spectral study reveals improved transparency for the doped crystal, ascertaining the inclusion of metal ion in the lattice. The optical band gap of the pure and doped crystals was calculated to be 4.8 and 5.2 eV respectively from the UV transmission spectrum. The vickers hardness test brings forth higher hardness value for Ni²⁺doped BTZC as compared to pure BTZC crystal. The dielectric measurement exhibits very low dielectric constant and dielectric loss at higher frequencies for both the pure and Ni²⁺doped BTZC. The existence of second harmonic generation signals in the crystal also has been confirmed by performing the Kurtz powder test.     

Studies on the growth and characterization of tris (glycine) calcium(ΙΙ) dichloride—a nonlinear optical crystal

A systematic characterization of a novel nonlinear optical material tris (glycine) calcium(ΙΙ) dichloride (TGCC) is performed. The solubility and metastable zone width of TGCC were studied. TGCC single crystal of dimensions 34×23×5 mm³ was grown by the slow evaporation technique. Single crystal X-ray diffraction studies reveal that the crystal belongs to orthorhombic system. Energy dispersive X-ray analysis confirms the presence of elements in the crystal. Structural perfection of the as-grown single crystal was studied through multicrystal X-ray diffraction analysis. The thermal characteristics of TGCC were analyzed by thermogravimetric and differential thermal analysis and differential scanning calorimetry. The transmittance of TGCC crystal has been used to calculate the optical band gap of the crystal. Chemical etching studies of TGCC crystal was carried out. The dielectric and mechanical behavior of the crystals were analyzed. The second harmonic conversion property of TGCC was identified by the Kurtz and Perry powder technique and was observed to be higher than that of KDP.     

Toluene sensing properties of SnO2-ZnO hollow nanofibers fabricated from single capillary electrospinning

SnO₂-ZnO hollow nanofibers were fabricated through a facile single capillary electrospinning technology. The structure and toluene sensing properties of the hollow fibers were investigated. The results indicated that the fibers possess a hollow structure, a rough porous surface after being annealed at 600 °C and the diameters are in the range of 80-160 nm. A sensor fabricated from these fibers exhibits considerable sensitivity and good stability against toluene at 190 °C, which can be attributed to the special 1D hollow structure and the promoting effect of the SnO₂/ZnO heterojunction. The formation mechanism and toluene sensing mechanism of SnO₂-ZnO hollow nanofibers were also discussed.