High‐performance catalysts and photovoltaics are required for building an environmentally sustainable society. Because catalytic and photovoltaic reactions occur at the interfaces between reactants and surfaces, the chemical, physical, and structural properties of interfaces have been the focus of much research. To improve the performance of these materials further, inorganic porous materials with hierarchic porous architectures have been fabricated. The breath figure technique allows preparing porous films by using water droplets as templates. In this study, a valuable preparation method for hierarchic porous inorganic materials is shown. Hierarchic porous materials are prepared from surface‐coated inorganic nanoparticles with amphiphilic copolymers having catechol moieties followed by sintering. Micron‐scale pores are prepared by using water droplets as templates, and nanoscale pores are formed between the nanoparticles. The fabrication method allows the preparation of hierarchic porous films from inorganic nanoparticles of various shapes and materials.
Pure and indium doped antimony telluride (Sb2Te3) crystals find applications in high performance room temperature thermoelectric devices. Owing to the meagre physical properties exhibited on the cleavage faces of melt grown samples, an attempt was made to explore the thermoelectric parameters of p‐type crystals grown by the physical vapor deposition (PVD) method. The crystal structure of the grown platelets (9 mm× 8 mm× 2 mm) was identified as rhombohedral by x‐ray powder diffraction method. The energy dispersive analysis confirmed the elemental composition of the crystals. The electron microscopic and scanning probe image studies revealed that the crystals were grown by layer growth mechanism with low surface roughness. At room temperature (300 K), the values of Seebeck coefficient S (⊥ c) and power factor were observed to be higher for Sb1.8In0.2Te3 crystals (155 μVK−1, 2.669 × 10−3 W/mK2) than those of pure ones. Upon doping, the thermal conductivity κ (⊥ c) was decreased by 37.14% and thus thermoelectric efficiency was improved. The increased figure of merit, Z = 1.23 × 10−3 K−1 for vapour grown Sb1.8In0.2Te3 platelets indicates that it could be used as a potential thermoelectric candidate. 相似文献
Abstract Performance characteristics of electrochemical detectors for high performance liquid chromatooraphy are difficult to predict from presently avaliable information relating response to design parameters. A fiqure of merit is proposed which allows an operational comparison to be made, based upon specific response, noise and band spread. On this basis, it is shown that a meaningful comparison of an amperometric design with a coulometric design can be obtained and that, contrary to previous predictions, this coulometric type is generally superior. 相似文献
