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61.
The specific features of the triplet-triplet (T-T) transfer of electronic excitation energy in a gas phase upon nonequilibrium
vibrational excitation of the triplet molecules of a donor were studied for an anthraquinone-diacetyl donor-acceptor pair
using the time-resolved slow fluoresence of anthraquinone and sensitized phosphorescence of diacetyl. It is shown that in
the gas phase, which allows regular control of the number of collisions, competition between the processes of T-T transfer
and intermolecular vibrational relaxation is observed for nanosecond time resolution. The T-T transfer rate for the molecular
system investigated exceeded the rate of intermolecular vibrational relaxation kV in the triplet state T1 of the donor. The effectiveness of the T-T transfer of energy by vibrationally excited molecules turned out to be higher
than the effectiveness of transfer by thermalized ones, but even the highest of them was much less than unity. An increase
in the equilibrium temperature of vapors led to a decrease in the effectiveness of transfer for both vibrationally excited
and thermalized triplet molecules, thus indicating the importance of the collisional complex in the intermolecular process
studied.
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 67, No. 4, pp. 474–479, July–August, 2000. 相似文献
62.
63.
Dietmar Tietz 《Journal of chromatography. A》2009,1216(52):9028-9033
This article provides an overview of a 2D agarose electrophoretic procedure for the characterization of semi-synthetic Haemophilus influenzae type b meningitis vaccines that were prepared for the immunization of small children. The analysis of such vaccines has been particularly challenging because the vaccine particles (i) are highly negatively charged, (ii) are as large as or even larger than intact viruses, and (iii) have a continuous (polydisperse) size distribution because of randomizing steps in the vaccine production (sonification and crosslinking). As a result of these characteristics, 1D electrophoresis of the vaccines produced smears without discernable peaks, but with a second dimension of separation a characteristic vaccine fingerprint was obtained. Whereas O’Farrell gels can accomplish a 2D separation according to size and charge for samples with protein-sized particles, nondenaturing 2D agarose electrophoresis achieves a similar result for much larger virus-sized particles. The separation principle, however, is different. Even though the 2D electrophoretic method was developed from 1983 to 1995, it remains a promising tool for vaccine quality control and for predicting vaccine effectiveness. Modern technology makes the analysis significantly more practical and affordable than it was more than 10 years ago, and the method is applicable to a variety of conjugated vaccines and complex mixtures of virus-sized particles. 相似文献
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65.
Sabina Yasmin Z. Siti Rozaila Bijoy Sonker Barua Faruque-Uz-Zaman Chowdhury Md. Abdur Rashid 《辐射效应与固体损伤》2018,173(7-8):657-672
One sign of a vibrant Bangladeshi economy has been the move away from the use of more traditional housing materials towards a preference for modern constructional media. Glass, one such example, used both decoratively and in a structural context, offers various advantageous properties and facets including a protective feature against radiation that has not previously been considered. Current interest examines the dosimetric possibilities offered by the commercial glass as a secondary shield and also in retrospective ionising radiation exposure analysis. Four popular brands of window glass are investigated, all available within the local market (PHP-Bangladesh, Usmania-Bangladesh, Nasir-Bangladesh and Rider-China), all with the same thickness and colour, varying in terms of elemental weight fractions as evaluated by energy dispersive X-ray analysis. As potential attenuators of transmitted radiation thereby forming secondary barriers against radiation exposure from penetrating radiations, the four brands of glass have been studied using photon energies from 59 up to 1332 keV, a range of values representative of that potentially encountered in incidents. Use has been made of a well-shielded high-purity germanium γ-ray spectrometer and associated electronics, providing for evaluation of the characteristic barrier parameters of half-value layer, radiation protection efficiency and effective atomic number (Zeff). Of the four brands investigated, Rider provides superior secondary shielding performance. Concerning potential retrospective dosimetry the effective atomic number of the glass samples are comparable with that of the commercial thermoluminescence (TL) dosimeter TLD-200. At high doses, the TL yields are sufficient to provide for retrospective accident dosimetry. 相似文献
66.
以国家重大区域规划中的长三角为实证研究对象,利用加权灰色关联度筛选出与政策效果评价关联性高度相关的政策指标:中央财政专项拨款、中央补助收入、中央固定资产投资额,进而建立政策指标与规划目标的第三产业增加值的对数回归函数,通过过去的数据预测某一特定年份第三产业增加值,并与该年份的实际值进行对比、评价国家重大区域规划的政策效果。本文的特色与创新一是通过灰色关联度剔除与政策效果评价关联度小的指标,筛选出对重大区域规划政策效果有显著影响的关键因素。二是通过时间权向量对政策指标的关联度进行加权,体现时间越近的年份、加权灰色关联度越大,指标越应该保留的思路,保证年份越近的指标数据、对评价结果影响越显著。三是通过历史数据的预测,得到在没有规划政策下、区域自然发展的目标效果,并把其与同一时点、政策实施后的实际效果进行对比,得到政策实施后的政策绩效。实证结果表明应该增大对上海和浙江影响显著的中央财政专项拨款的政策投入,减少对上海和浙江影响不显著的中央固定资产投资额的投入。 相似文献
67.
低速增压风洞是满足我国航空工业科技发展而建设的一座气动力重大基础试验设施。为了保障该设施的高效率和可靠地运行,以各机电设备、电气测控设备、机械装置为对象,根据其故障模式和故障特点选取合适的监测点,获取实时工作状态数据,再以数据为基础,进行状态监测、故障诊断、故障预测,实现预先性决策和针对性快速维修。基于OSA-CBM 体系构建的风洞健康管理系统,根据设备的运行状态,实现对试验数据的有效性进行实时判定,并实现了风洞装备由事后维修向视情维修转变;实现了装备从使用、维护、管理模式由分散式管理向集约式管理的转变;实现了装备系统故障诊、预测及判读从人工智能向机器智能的转变。 相似文献
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69.
This paper is concerned with the steady-state propagation of an antiplane semi-infinite crack in couple stress elastic materials. A distributed loading applied at the crack faces and moving with the same velocity of the crack tip is considered, and the influence of the loading profile variations and microstructural effects on the dynamic energy release rate is investigated. The behavior of both energy release rate and maximum total shear stress when the crack tip speed approaches the critical speed (either that of the shear waves or that of the localized surface waves) is studied. The limit case corresponding to vanishing characteristic scale lengths is addressed both numerically and analytically by means of a comparison with classical elasticity results. 相似文献
70.