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891.
Ichiro Uchiyama 《International Journal of Computational Fluid Dynamics》2018,32(2-3):59-67
ABSTRACTIn this paper, we present a shape optimisation method for wall structures due to the wave force induced by a solitary wave. The fluid is assumed to be incompressible. Introducing the adiabatic assumption in addition, the acoustic velocity method presented by the author's group, the SUPG finite element method, is effectively used. To evaluate the wave force, we use the performance functional, which consists of the sum of the square of the wave force integrated between the starting and final times. The coordinates of the wall structure are regulated to obtain the minimum performance functional. The adjoint equation method is utilised to derive the gradient of the performance functional with respect to the coordinates. The simple weighted gradient method is employed as the minimisation procedure. Two numerical studies show that the results are consistent with existing structures and provide useful information on the practical design of coastal structures. 相似文献
892.
Octavian Filip Matthias BickermannBoris M. Epelbaum Paul HeimannAlbrecht Winnacker 《Journal of Crystal Growth》2010,312(18):2522-2526
Bulk AlN–SiC mixed single crystals are prepared by sublimation growth employing pure AlN or mixed AlN–SiC sources and 6H-SiC seed crystals. As the growth temperature is increased from 1900 to 2050 °C, using seeds with different off-axis orientations, inclined up to 42° from the basal plane toward the (0 1 –1 0)-plane, or using different source materials, crystals with different Si/C contents are obtained. Dependent on the Si and/or C content, crystal coloration changes from yellowish to greenish to blackish. Modification in crystals’ coloration and corresponding changes in below band-gap optical absorption and cathodoluminescence spectra are discussed. 相似文献
893.
894.
The influence of sulfur-aromatic interactions on the chromatographic separation behavior of hybrid RP phases, containing thiol-groups and/or embedded sulfide-groups (S-RP) has been investigated. To allow a precise outline of this new interaction mode, a wide variety of S-RP phases with different alkyl chain length, with and without residual thiol-groups and silanol-endcapping were prepared and tested in comparison to some conventional monomerical as well as polymerical n-alkyl type RP phases. The solute test sets employed in this study comprised the classical chromatographic column tests from Engelhardt and Tanaka as well as test assemblies containing polycyclic aromatic hydrocarbons, stilbene-based cis/trans isomers and functional isomers of benzene. In general, a pronounced strong planar recognition ability as well as a strong increase in the retention for aromatic compounds have been noticed. It was furthermore found that not only the sulfur atom incorporated into the alkyl chain, but also the residual thiol-groups of the 3-propylthiol silica backbone contribute to the overall retention behavior of these novel S-RP type phases. 相似文献
895.
Huang Rong-jin Song Chun-mei Li Lai-feng 《Journal of Physics and Chemistry of Solids》2007,68(7):1400-1404
The alloys with the general formula of Bi85Sb15−xAgx (x=0, 1, 3, 5, 7) were prepared by mechanical alloying and subsequent pressureless sintering (Bi85Sb15 alloy was used for comparison). Their transport properties involving electrical conductivity, Seebeck coefficient, and thermal conductivity had been investigated in the temperature range of 80-300 K. The maximum absolute value of Seebeck coefficient (120 μV/K) was found at 160 K in the alloy Bi85Sb15−xAgx (x=3). The figure-of-merit of alloy Bi85Sb15−xAgx (x=1) reached a maximum value of 2.16×10−3 K−1 at 219 K, which is as large again as that of the reference sample Bi85Sb15. 相似文献
896.
Ruslinda A. Rahim Hiroaki Kurahashi Katsuhiro Uesugi Hisashi Fukuda 《Surface science》2007,601(22):5112-5115
Metal-insulator-semiconductor (MIS) structures with a nanocrystal carbon (nc-C) embedded in SiO2 thin films were fabricated using a focused ion beam (FIB) system with a precursor of low-energy Ga+ ion and carbon source. The crystallinity of nc-C was investigated by Raman spectroscopy and atomic force microscopy (AFM). Raman spectra indicate the evidence of crystallization of nc-C after annealed at 600 °C by the sharp peak at 1565 cm−1 in graphite (sp2), while no peak of diamond (sp3) could be seen at 1333 cm−1. The AFM images showed the nc-C dots controlled with diameter of 100 nm, 200 nm and 300 nm, respectively. The above results revealed that the nc-C dots had sufficiently stuck onto SiO2 films. The hysterisis loop in the capacitance-voltage characteristics appeared in the MIS device with SiO2/nc-C/SiO2 structure in which voltage shift is 0.32 V for radical oxidation and 0.14 V for dry oxidation, respectively. 相似文献
897.
Víctor Soto-Verdugo 《Surface science》2007,601(23):5332-5339
We use density functional theory (DFT) with the generalized gradient approximation (GGA) and the revised Perdew-Burke-Ernzerhoff (rPBE) functional, to study the surface composition of the (1 1 1) and (1 0 0) dilute Pd/Au alloy. We find that the energy of Pd atoms is lower when they substitute an Au atom in the bulk than when they substitute an Au atom in the surface layer, or when they are adsorbed on the surface. Whether they are in the surface layer or in the bulk, the Pd atoms interact very weakly with each other. CO adsorbs on the Pd atom in the surface layer and the energy of this complex is lower than that of CO in gas and Pd atom in the bulk. The interaction between the PdCO complexes formed when CO adsorbs on a Pd atom imbedded in the surface layer, is also negligible. We use these energies, equilibrium thermodynamics, and a simple lattice-gas model to examine the equilibrium composition of the surface layer, as a function of temperature, CO pressure and the Pd/Au ratio. We find that the surface Pd concentration for a nanoparticle of an Au/Pd alloy differs from that in a bulk sample. The difference is due mainly to the fact that in a nanoparticle the migration of Pd atoms to the surface depletes the bulk concentration while in a large sample; the bulk provides an infinite source of Pd atoms to populate the surface sites. This system is of interest because Pd/Au alloys are selective catalysts for vinyl acetate synthesis when the Pd concentration on the surface is very low. 相似文献
898.
Takahisa Miyata 《Proceedings of the American Mathematical Society》2001,129(9):2783-2788
Dydak and Yokoi introduced the notion of shape aspherical compactum. In this paper, we use this notion to obtain a generalization of Kan and Thurston theorem for compacta and pro-homology. As an application, we obtain a characterization of cohomological dimension with coefficients in and ( prime) in terms of acyclic maps from a shape aspherical compactum, which improves the theorems of Edwards and Dranishnikov. Furthermore, we obtain the shape version of the theorem and as a consequence we show that every compactum has the stable shape type of a shape aspherical compactum.
899.
Joseph L. McCauley 《Physica A》2007,382(2):445-452
The purpose of this comment is to correct mistaken assumptions and claims made in the paper “Stochastic feedback, nonlinear families of Markov processes, and nonlinear Fokker-Planck equations” by T. D. Frank [T.D. Frank, Stochastic feedback, non-linear families of Markov processes, and nonlinear Fokker-Planck equations, Physica A 331 (2004) 391]. Our comment centers on the claims of a “non-linear Markov process” and a “non-linear Fokker-Planck equation.” First, memory in transition densities is misidentified as a Markov process. Second, the paper assumes that one can derive a Fokker-Planck equation from a Chapman-Kolmogorov equation, but no proof was offered that a Chapman-Kolmogorov equation exists for the memory-dependent processes considered. A “non-linear Markov process” is claimed on the basis of a non-linear diffusion pde for a 1-point probability density. We show that, regardless of which initial value problem one may solve for the 1-point density, the resulting stochastic process, defined necessarily by the conditional probabilities (the transition probabilities), is either an ordinary linearly generated Markovian one, or else is a linearly generated non-Markovian process with memory. We provide explicit examples of diffusion coefficients that reflect both the Markovian and the memory-dependent cases. So there is neither a “non-linear Markov process”, nor a “non-linear Fokker-Planck equation” for a conditional probability density. The confusion rampant in the literature arises in part from labeling a non-linear diffusion equation for a 1-point probability density as “non-linear Fokker-Planck,” whereas neither a 1-point density nor an equation of motion for a 1-point density can define a stochastic process. In a closely related context, we point out that Borland misidentified a translation invariant 1-point probability density derived from a non-linear diffusion equation as a conditional probability density. Finally, in the Appendix A we present the theory of Fokker-Planck pdes and Chapman-Kolmogorov equations for stochastic processes with finite memory. 相似文献
900.
When people attempt to recall as many words as possible from a specific category (e.g., animal names) their retrievals occur sporadically over an extended temporal period. Retrievals decline as recall progresses, but short retrieval bursts can occur even after tens of minutes of performing the task. To date, efforts to gain insight into the nature of retrieval from this fundamental phenomenon of semantic memory have focused primarily upon the exponential growth rate of cumulative recall. Here we focus upon the time intervals between retrievals. We expected and found that, for each participant in our experiment, these intervals conformed to a Lévy distribution suggesting that the Lévy flight dynamics that characterize foraging behavior may also characterize retrieval from semantic memory. The closer the exponent on the inverse square power-law distribution of retrieval intervals approximated the optimal foraging value of 2, the more efficient was the retrieval. At an abstract dynamical level, foraging for particular foods in one's niche and searching for particular words in one's memory must be similar processes if particular foods and particular words are randomly and sparsely located in their respective spaces at sites that are not known a priori. We discuss whether Lévy dynamics imply that memory processes, like foraging, are optimized in an ecological way. 相似文献