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131.
The preparation and properties of smooth and stable films of cyclodextrin polymers are described. The commercially available water soluble prepolymers of-, -, and-cyclodextrin of low molecular masses were crosslinked with glutaric dialdehyde. Side-chain unreacted aldehyde groups were reduced with sodium borohydride. For the-cyclodextrin polymer, optimum film performance was found for a 1:10 mass ratio of glutaric dialdehyde to prepolymer, which corresponds to a molar ratio of glutaric dialdehyde to cyclodextrin units of about 1.75: 1. Such films, of thickness 2.4 µm, were prepared on metallic or glassy-carbon substrates for characterization by scanning-electron microscopy, and for studies with the electrochemical quartz-crystal microbalance.  相似文献   
132.
分子筛改性气—液毛细管柱及其性能考察   总被引:1,自引:0,他引:1  
以原位合成法制备的分子筛膜对玻璃毛细管内壁进行改性后,成功地制备了常规口径及大口径分配SCOT柱,并对毛细管柱的性能进行了评价。  相似文献   
133.
We have studied the adsorption of a copolymer of acrylonitrile and methacrylate of nonaethyleneglycol on a kidney dialysis membrane, which contains mostly nitrile groups. The kinetics study reveals at first a rapid increase of the adsorbance, followed by slow variations suggesting rearrangements at the interface. The isotherms do not present a true plateau at high concentration. The high adsorbance observed at low pH or high salt concentration could be related to the ability of polyethyleneoxide to form a complex with cations.  相似文献   
134.
《Electroanalysis》2006,18(2):115-120
Electrochemical method of detection of heparin polyion was developed based on voltammetry of heparin on a rotating glassy carbon (GC) electrode coated with a plasticized PVC membrane. The membrane was deposited on the GC disk by spin‐coating technique using a mixture of solutions of PVC in tetrahydrofuran, and 1,1′‐dimethylferrocene (DMFc) and hexadecyltrimethylammonium tetrakis(4‐chlorophenyl)borate (HTMATPBCl) in o‐nitrophenyl octyl ether. UV/vis reflection spectrometry was used to evaluate the membrane thickness, which exhibits a linear correlation with the membrane resistance measured by impedance spectroscopy. It is shown that this electrode can be used for amperometric or coulometric detection of heparin in aqueous samples of medically relevant concentrations (1–10 U mL?1), with a detection limit of 1.4 U mL?1. Evidence is provided indicating that the current determining step is the reversible adsorption of the ion‐pair of heparin polyion with HTMA+ cation at the membrane/aqueous electrolyte interface, which is driven by oxidation of DMFc at the GC/membrane interface.  相似文献   
135.
One to three endothermal peaks atributted to melting of bulk and interfacial water were observed by DSC in the regenerated cellulose — water system. The profiles of thermal effects depend on water content, time of conditioning, film pretreatment and the conditions applied during the preceding freezing-thawing cycles. The occurrence might be deduced of melting-crystallisation processes. A large amount of non-freezable strongly bounded water was also detected. Although cellulose absorbs water quickly after immersion, the structural changes consisting on ordering of polymer fraction occur during further conditioning due to increase in strength of water binding. Using the membranes in the separation module at 90°C causes weakening of these bonds. Differences between interaction of particular cellulose films with water can be detected during the first, the second and the third heating. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   
136.
137.
Electrochemical formation of poly(phenylmethylsilane) in a divided cell containing a Teflon® neutral membrane was studied. The electrolysis of dichlorosilanes was carried out in a solution containing tetrahydrofuran + hexamethylphosphoramide as the solvent, tetrabutylammonium perchlorate as the support electrolyte and stainless steel as the cathode, with Pt and graphite as the resistant anodes or stainless steel as the sacrificial anode. Polysilanes with a number-average molecular weight in the range from 2,600 to 130,000 g/mol were obtained, depending on the conditions used.  相似文献   
138.
Separation efficiencies and selectivities in solvent extraction of Co(II) and Ni(H) ammine cations from aqueous solutions into chloroform and toluene and in transport through bulk toluene membranes by proton-ionizable crown ethers have been determined. Six proton-ionizable crown ethers with differing lipophilicities, polyether cavity sizes and ionizable groups (carboxylic and sulfonic acid functions) were examined. Higher selectivity and efficiency for Co(II) ammine cation extraction was observed for the more lipophilic, proton-ionizable crown ethers. Highly lipophilic crown carboxylic acids provided effective and selective transport of Co(II) ammine cations through bulk toluene membranes.Presented in part at the 6th International Symposium on High Purity Materials in Science and Technology: Preparation, Characterization and Application of Well-Defined Materials, Dresden, GDR, May 1985, Poster D91, Poster Abstracts, pp. 144, 145.All extraction and transport experiments were conducted at this location.  相似文献   
139.
研究了不同烃基乙烯基亚砜接枝聚乙烯醇(PVA-RVSO,R=Me,Et,t-Bu,Ph)膜对纯SO2、N2的透过性能以及SO2/N2混合气体的分离性能.结果表明上述膜对SO2具有高的选择性.对不同烃基乙烯基亚砜接枝膜进行了比较.  相似文献   
140.
分子印迹壳聚糖膜分离手性苯丙氨酸   总被引:11,自引:0,他引:11  
以L-苯丙氨酸(L-Phe)为印迹分子,采用相转化法制备了分子印迹壳聚糖膜。分别采用碱液处理和硫酸交联两种方法对膜进行处理,降低了壳聚糖膜的溶胀度,印迹膜内识别位点的结构得以保持。采用FT-IR和SEM对膜的化学组成和结构形态进行了表征。通过渗透实验考察了分子印迹壳聚糖膜和非印迹空白壳聚糖膜对D,L-苯丙氨酸(D,L-Phe)混合物的手性拆分性能,并与空白膜进行了比较。印迹膜的分离因子达到1.43。  相似文献   
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