全文获取类型
收费全文 | 121703篇 |
免费 | 9944篇 |
国内免费 | 15442篇 |
专业分类
化学 | 80841篇 |
晶体学 | 1381篇 |
力学 | 5458篇 |
综合类 | 1136篇 |
数学 | 22036篇 |
物理学 | 36237篇 |
出版年
2024年 | 165篇 |
2023年 | 969篇 |
2022年 | 2206篇 |
2021年 | 2597篇 |
2020年 | 3190篇 |
2019年 | 3022篇 |
2018年 | 2726篇 |
2017年 | 3740篇 |
2016年 | 4053篇 |
2015年 | 3462篇 |
2014年 | 4980篇 |
2013年 | 9170篇 |
2012年 | 8023篇 |
2011年 | 7033篇 |
2010年 | 5926篇 |
2009年 | 7853篇 |
2008年 | 8084篇 |
2007年 | 8294篇 |
2006年 | 7445篇 |
2005年 | 6381篇 |
2004年 | 5837篇 |
2003年 | 5001篇 |
2002年 | 6124篇 |
2001年 | 3813篇 |
2000年 | 3597篇 |
1999年 | 3285篇 |
1998年 | 2881篇 |
1997年 | 2287篇 |
1996年 | 1879篇 |
1995年 | 1722篇 |
1994年 | 1539篇 |
1993年 | 1305篇 |
1992年 | 1240篇 |
1991年 | 870篇 |
1990年 | 781篇 |
1989年 | 763篇 |
1988年 | 580篇 |
1987年 | 494篇 |
1986年 | 457篇 |
1985年 | 393篇 |
1984年 | 396篇 |
1983年 | 224篇 |
1982年 | 339篇 |
1981年 | 290篇 |
1980年 | 299篇 |
1979年 | 285篇 |
1978年 | 250篇 |
1977年 | 199篇 |
1976年 | 178篇 |
1973年 | 130篇 |
排序方式: 共有10000条查询结果,搜索用时 281 毫秒
981.
A. V. Tarasov P. O. Yablonsky Yu. A. Moskvichev 《Chemistry of Heterocyclic Compounds》2003,39(1):119-122
Various methods were studied for the oxidation of 2-methyl-5-(phenylsulfonyl)benzenesulfamide and its derivatives. The oxidation by sodium dichromate in sulfuric acid was found most efficient. The effects of temperature, concentration, reagent ratio, and time of the oxidation reaction on the yield of the desired product were investigated. Conditions were proposed for obtaining the desired product in yields up to 95%. A synthesis was developed for a series of new saccharin derivatives. 相似文献
982.
采用PM 3半经验方法对肾上腺素和二甲亚砜与肾上腺素形成的 1∶1复合物的结构进行了几何优化 .在此基础上用密度泛函理论 (DFT)的B3LYP方法 ,分别在 6 31G、6 31G 、6 31+G 基组水平上进行了精确计算 ,并通过单点能计算考察了它们之间在形成各种复合物前后的能量和分子结构参数变化特点 .在各基组水平上所有物种的能量均进行零点振动能 (ZPVE)校正 .计算结果表明 ,二甲亚砜与肾上腺素能形成 6种稳定的复合物 ,在这些复合物中都具有较强的氢键作用 .计算结果能够解释有关实验现象 相似文献
983.
基于Karhunen-Loève变换和小波谱特征矢量量化的三维谱像数据压缩 总被引:1,自引:1,他引:0
提出了基于Karhunen Lo埁ve变换的小波谱特征矢量量化三维谱像数据压缩方法耍幔颍瑁酰睿澹?Lo埁ve变换 /小波变换 /小波谱特征矢量量化方法应用了Karhunen Lo埁ve变换的消除谱相关性优良性能 ,应用二维小波变换消除空间相关性 ,在小波变换域内应用二维集分割嵌入块编码和一维谱特征矢量量化对三维谱像数据压缩 ,获得较高的压缩性能。实验结果表明 :Karhunen Lo埁ve变换 /小波变换 /小波谱特征矢量量化编码比Karhunen Lo埁ve变换 /小波变换 /改进对块零树编码和Karhunen Lo埁ve变换 /小波变换 /快速矢量量化编码方法在同样压缩比条件下 ,峰值信噪比提高 2dB和 1dB以上 ,而速度提高了 1.5和 8倍 ,整体压缩性能有较大的提高 相似文献
984.
Finite chains of a two-state random Potts spin model with periodic boundary conditions are studied within Glauber dynamics. The spin exchange is assumed random with frustration between ferro and antiferromagnetic values (±J). Time-dependent fluctuations are induced by periodic temperature oscillations. Master type differential equations for spin correlation functions are solved within linear response theory. The spectrum of relaxation times are calculated at different temperatures. The ±J Potts glass chains undergo a zero temperature phase transition. The barriers against inversion of the spin chain take only two values; 0 and 2|J|. The temperature behaviour of specific heat is characterized by rounded peaks. The frequency dependence displays two plateaus for the real part of specific heat and two corresponding peaks for the imaginary part. The dynamic specific heat is not affected by the longest relaxing mode like susceptibility. The time separation of the modes is demonstrated by the Cole-Cole plots. 相似文献
985.
For the purpose of testing the spherical uniformity based on i.i.d. directional data (unit vectors) zi, i=1,…,n, Anderson and Stephens (Biometrika 59 (1972) 613–621) proposed testing procedures based on the statistics Smax=maxu S(u) and Smin=minu S(u), where u is a unit vector and nS(u) is the sum of squares of u′zi's. In this paper, we also consider another test statistic Srange=Smax−Smin. We provide formulas for the P-values of Smax, Smin, Srange by approximating tail probabilities of the limiting null distributions by means of the tube method, an integral-geometric approach for evaluating tail probability of the maximum of a Gaussian random field. Monte Carlo simulations for examining the accuracy of the approximation and for the power comparison of the statistics are given. 相似文献
986.
Veli B. Shakhmurov 《Journal of Mathematical Analysis and Applications》2004,292(2):605-620
This study focuses on nonlocal boundary value problems (BVP) for degenerate elliptic differential-operator equations (DOE), that are defined in Banach-valued function spaces, where boundary conditions contain a degenerate function and a principal part of the equation possess varying coefficients. Several conditions obtained, that guarantee the maximal Lp regularity and Fredholmness. These results are also applied to nonlocal BVP for regular degenerate partial differential equations on cylindrical domain to obtain the algebraic conditions that ensure the same properties. 相似文献
987.
Michael Szydlo 《Journal of Number Theory》2004,104(1):75-99
Kodaira and Néron classified and described the geometry of the special fibers of the Néron model of an elliptic curve defined over a discrete valuation ring with a perfect residue field. Tate described an algorithm to determine the special fiber type by manipulating the Weierstrass equation. In the case of non-perfect residue fields, we discover new fiber types which are not on the Kodaira-Néron list. We describe these new types and extend Tate's algorithm to deal with all discrete valuation rings. Specifically, we show how to translate a Weierstrass equation into a form where the reduction type may be easily determined. Having determined the special fiber type, we construct the regular model of the curve with explicit blow-up calculations. We also provide tables that serve as a simple reference for the algorithm and which succinctly summarize the results. 相似文献
988.
989.
L Guangshi School of Mathematics System Sciences Shandong University Jinan China. 《数学年刊B辑(英文版)》2005,(2)
§1. IntroductionIn the additive theory of prime numbers, one studies the representation of positive in-tegers by powers of primes. For the quadratic case, Hua [1] proved that each large integercongruent to 5 modulo 24 can be written as the sum of ?ve squ… 相似文献
990.
Balanced sampling plans excluding contiguous units (or BSEC) were first introduced by Hedayat, Rao, and Stufken in 1988. In this paper, we generalize the concept of a cyclic BSEC to a cyclic balanced sampling plan to avoid the selection of adjacent units (or CBSA for short) and use Langford and extended Langford sequences to construct a cyclic BSA(ν, 3, λ; α) with α = 2, 3. We finally establish the necessary and sufficient conditions for the existence of a cyclic BSA(ν, 3, λ; α) where α = 2, 3. © 2005 Wiley Periodicals, Inc. J Combin Designs. 相似文献