全文获取类型
收费全文 | 987篇 |
免费 | 115篇 |
国内免费 | 106篇 |
专业分类
化学 | 781篇 |
晶体学 | 7篇 |
力学 | 19篇 |
综合类 | 2篇 |
数学 | 26篇 |
物理学 | 373篇 |
出版年
2024年 | 6篇 |
2023年 | 57篇 |
2022年 | 30篇 |
2021年 | 32篇 |
2020年 | 35篇 |
2019年 | 37篇 |
2018年 | 41篇 |
2017年 | 42篇 |
2016年 | 34篇 |
2015年 | 30篇 |
2014年 | 49篇 |
2013年 | 56篇 |
2012年 | 41篇 |
2011年 | 71篇 |
2010年 | 52篇 |
2009年 | 69篇 |
2008年 | 48篇 |
2007年 | 50篇 |
2006年 | 51篇 |
2005年 | 51篇 |
2004年 | 40篇 |
2003年 | 37篇 |
2002年 | 28篇 |
2001年 | 23篇 |
2000年 | 20篇 |
1999年 | 13篇 |
1998年 | 21篇 |
1997年 | 13篇 |
1996年 | 9篇 |
1995年 | 11篇 |
1994年 | 10篇 |
1993年 | 9篇 |
1992年 | 7篇 |
1991年 | 8篇 |
1990年 | 8篇 |
1989年 | 11篇 |
1988年 | 7篇 |
1987年 | 8篇 |
1986年 | 7篇 |
1985年 | 13篇 |
1984年 | 2篇 |
1983年 | 3篇 |
1982年 | 7篇 |
1981年 | 2篇 |
1980年 | 2篇 |
1979年 | 4篇 |
1978年 | 1篇 |
1977年 | 2篇 |
排序方式: 共有1208条查询结果,搜索用时 15 毫秒
71.
72.
Xiyue Xiong Zihui Yang Yongbin Huang Linbo Jiang Yingzhuang Chen Yao Shen Bo Chen 《Journal of separation science》2013,36(5):923-931
A novel construction strategy of monolithic capillary column for selectively enriching perfluorinated persistent organic pollutants was proposed. The organic–inorganic hybrid fluorous monolithic capillary column was synthesized by a “one‐pot” approach via the polycondensation of γ‐methacryloxypropyltrimethoxy‐silane, then in situ copolymerization of 1H,1H,7H‐dodecafluoroheptyl methacrylate and vinyl group on the precondensed siloxanes. The obtained monolithic columns were systematically characterized. The results demonstrated that the optimal column possessed good mechanical stability and high permeability. The adsorption capacities of the optimized monolithic column for perfluorooctanoic acid and perfluorooctane sulfonate were 0.257 and 0.513 μg/mg, respectively. Adsorption capacities of the monoliths were proved to increasing with increasing the amounts of fluorinated monomers in the fluorous monoliths. Sodium 1‐octanesulfonate, as a comparison compound, was hardly adsorbed on the fluorous monolith. In addition, the trace amounts of perfluorooctanoic acid and perfluorooctane sulfonate in water samples can be successfully concentrated about 160 times to their original concentrations by this monolithic column. These results demonstrated that the capacity and selectivity of the affinity fluorous column is high and can be applied to the selective enrichment for the perfluorinated persistent organic pollutants from environmental samples. 相似文献
73.
The tunable nature of lasers provides for a wide range of applications. Most applications rely on finding available laser wavelengths to meet the needs of the research. This article presents the concept of compositional tuning, whereby the laser wavelength is designed by exploiting nonstoichiometry. For research where precise wavelengths are required, such as remote sensing, this is highly advantageous. A theoretical basis for the concept is presented and experimental results in spectroscopic measurements support the theoretical basis. Laser operation nicely demonstrates the validity of the concept of designer lasers. 相似文献
74.
Y. Uzawa M. Takeda A. Kawakami Z. Wang T. Noguchi 《International Journal of Infrared and Millimeter Waves》2005,26(1):41-54
We describe a novel method of designing a tuning circuit with two half-wave distributed junctions separated by a half-wavelength microstripline, which analytically determines the circuit parameters such as the minimum current density of the junctions and the characteristic impedances of the distributed junctions and the microstripline. The tuning circuit was approximated by simple transmission theory and then simplified with ideal circuit components for analysis. We applied Chebyshevs band-pass filter theory, in part, to optimize the circuit design. The analytical results revealed that a high characteristic-impedance ratio between the distributed junctions and the microstripline is necessary to obtain broadband matching using low-current-density junctions. The experimental results for all-NbN SIS mixers we designed with this method demonstrated double-sideband (DSB) receiver-noise temperatures of 6–10 quanta from 710 to 810 GHz for a mixer with a current density of only 4 kA/cm2 (estimated CJRN product of 37 at 750 GHz). The RF bandwidth was broader than that of a conventional full-wave distributed SIS mixer with the same current density. 相似文献
75.
Multiple-separation and -detection are two approaches applied at the identification of analytes in chromatography. Using them depends on the physico-chemical properties and elemental content of the analytes. When physico-chemical properties are similar multiple-separation gives better opportunities for the identification. In this case, the efficiency of the columns is very important. When analytes contain some characteristic groups as--NO2, halogen, or nitrogen atoms then multiple-detection will be more useful. The sensitivity and/or selectivity of the detectors increase reliability of identification significantly. 相似文献
76.
Overlapping voltammetric signals, accrued from redox processes of nucleobases, do not permit discrimination between short oligonucleotides and chromosomal DNA molecules when conventional electrochemical techniques are used. This article describes a new genoelectronic route for discriminating between short oligonucleotides and chromosomal DNA, based on the polypyrrole (PPy) doping process. Such a route relies on the profound effect of short nucleic acid dopants upon the redox activity of PPy, and hence on the square-wave voltammetric signal of the polymer-modified electrode in a blank electrolyte solution. The electropolymeric growth of PPy thus serves for preferential accumulation (by doping) of short oligonucleotides. High selectivity is demonstrated for voltammetric measurements of oligo(dG)20 and oligo(dT)20 in the presence of otherwise interfering ss- and ds-DNA. The signals for the oligonucleotides are also not affected by a large excess of chloride or phosphate ions. The response of the new preconcentration (doping)–medium-exchange–voltammetric protocol is proportional to the concentration of the oligonucleotide dopant. Such a new recognition process, based on the doping of conducting-polymer networks, enhances the scope of electroanalysis of nucleic acids. 相似文献
77.
Volker Schurig 《Journal of chromatography. A》2009,1216(10):1723-1736
The retention increment approach is described which quantifies the association equilibria of a selectand and a selector in complexation and inclusion chromatography. A thermodynamic treatment of enantioselectivity based on retention phenomena in chromatography including entropy/enthalpy compensation and the isoenantioselective temperature is advanced. Kinetic parameters of enantiomerization are discussed. Non-linear effects, both existent and elusive, are described and proposed, respectively. The enantioselectivity pertaining to catalysis vs. chromatography is compared and a unified nomenclature is proposed. Through an educational effort, this account is aimed at providing a deeper insight into chemoselective aspects of chromatography thereby stimulating further research of both established and speculative phenomena of the most intriguing manifestation of chemoselectivity, that is, of enantioselectivity. 相似文献
78.
79.
The advantages and the practical limitations of injection locking are discussed. Experimental results for a system working in the regime between ideal injection locking and regenerative amplification are presented. 相似文献
80.