无界区域抛物方程自然边界元方法

本文应用自然边界元方法求解无界区域抛物型初边值问题。首先将控制方程对时间进行离散化,得到关于时间步长离散化的椭圆型问题。通过Fourier展开,导出相应问题的自然积分方程和Poisson积分公式。研究了自然积分算子的性质,并讨论了自然积分方程的数值解法,最后给出数值例子。从而解决了抛物型问题的自然边界归化和自然边界元方法。     

Thin-walled Beams: A Derivation of Vlassov Theory via Γ-Convergence

This paper deals with the asymptotic analysis of the three-dimensional problem for a linearly elastic cantilever having an open cross-section which is the union of rectangles with sides of order ε and ε ², as ε goes to zero. Under suitable assumptions on the given loads and for homogeneous and isotropic material, we show that the three-dimensional problem Γ-converges to the classical one-dimensional Vlassov model for thin-walled beams.      

Improvement of the properties of polyarylate reinforced with liquid crystalline polymers

Blends of polyarylate of bisphenol A, PAr, with two commercial main chain liquid crystalline polymers, Vectra A950 and Vectra B950, are studied. From dynamic viscoelastic measurements it is deduced that both systems (PAr/Vectra A950 and PAr/Vectra B950) are immiscible and scanning electron microscopy (SEM) micrographs show the presence of spherical domains of the liquid crystalline polymer when PAr constitutes the matrix. Extrusion capillary measurements reveal that, under conditions of temperature and shear rate similar to those of processing, the viscosity is reduced to approximately 10% of its value when the content of liquid crystalline polymer is only 20%. This great improvement of the rheological properties is observed in both PAr/Vectra A950 and PAr/Vectra B950 blends. The effect of draw ratio on Young's modulus for different compositions is also analyzed, pointing out the reinforcing action of both liquid crystalline polymers on polyarylate: for instance, 20% of Vectra B950 in the blend gives rise to a 700% increase of the modulus of fibres prepared at a draw ratio of 50. SEM of the extrudates reveals that the spherical domains are elongated at the entrance of the capillary giving rise to a microfibrillar morphology which is related to the excellent rheological and mechanical properties of the blends.     

Synthesis of perfluoroheptanal by ozonolysis of perfluoro-1-octene

Perfluoro-1-octene was used as a model for developing a method for the preparative ozonolysis of perfluoro-1-alkenes to the corresponding perfluoro-nor-alkenals. Perfluoroheptanal was synthesized.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1146–1147, June, 1994.     

A Diepoxide Belonging to the Rare C1 Point Group

2,6- and 2,7-Dimethylanthracenes were reduced seriatim with lithium in liquid ammonia and lithium in methylamine to their 1,4,5,8,9,10-hexahydro derivatives. Two-fold epoxidation of these tetraenes provided the cis and trans diepoxides resulting from electrophilic attack at the inner double bonds. Trans diepoxide 1 has the very unusual characteristic of lacking a σ plane of symmetry but possessing an inversion center. As a consequence, the ¹H NMR spectrum of C₁-symmetric 1 is simplified relative to those of its isomers 5, 9, and 10.     

辽河冷家油田特稠油降粘剂LJVR-1及其性能评价

采用荧光法测定了辽河冷家油田冷47-556井特稠油乳化HLB值,然后以混合型表面活性剂、非离子型表面活性剂为主剂,快速渗透剂为辅剂按一定比例制备了水基降粘剂LJVR-1.实验结果表明,该降粘剂具有良好的乳化降粘性能,开采后易于破乳脱水,是一种较为理想的特稠油降粘剂.     

A new method for the reduction of nitronyl nitroxides

Reduction of nitronyl nitroxides using hexamethylenetetramine is a very convenient method for preparing the corresponding imino nitroxides and 2-imidazoline N-oxides.     

置换环上的稳定矩阵

本文证明了置换环上的正则稳定矩阵是幂等矩阵和可逆矩阵的积,进一步证明了置换环上的正则稳定矩阵可以对角化。     

选择性远程DEPT~(13)C NMR新技术用于新阔叶千里光碱氮氧化合物的结构测定和谱峰归属研究

从湖北蟹甲草根茎中分得一个新的生物碱,选择性远程DEPT~(13)C NMR新技术用于识别NMR信号归属和连接被季碳及杂原子分割的质子自旋系统,确定其结构为新阔叶千里光碱的氮氧化物,如(1)所示。     

Schedule-an expert-like system for machine scheduling

The construction of an expert-like system for machine scheduling called SCHEDULE is presented. Essential parts of SCHEDULE were developed by students in a laboratory course Operations Research on Microcomputers at the University of Karlsruhe, Germany. SCHEDULE consists of the components data base, knowledge base, inference engine, explanation facility, dialog component, and knowledge acquisition component. The knowledge base contains an algorithm base for solving different types of scheduling problems. To establish the rules of the knowledge base the well-known three-field classification of deterministic machine scheduling problems and the concept of the reduction digraph are exploited. Experiences gained during building and demonstrating SCHEDULE are reported.