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Fan Wang Rui Liao Prof. Dr. Feng Wang 《Angewandte Chemie (International ed. in English)》2023,62(36):e202305827
Controlling the nanoscale orientation of π-conjugated systems remains challenging due to the complexity of multiple energy landscapes involved in the supramolecular assembly process. In this study, we have developed an effective strategy for programming the pathways of π-conjugated supramolecular polymers, by incorporating both electron-rich methoxy- or methanthiol-benzene as donor unit and electron-poor cyano-vinylenes as acceptor units on the monomeric structure. It leads to the formation of parallel-stacked supramolecular polymers as the metastable species through homomeric donor/acceptor packing, which convert to slip-stacked supramolecular polymers as the thermodynamically stable species facilitated by heteromeric donor-acceptor packing. By further investigating the external seed-induced kinetic-to-thermodynamic transformation behaviors, our findings suggest that the donor-acceptor functionality on the seed structure is crucial for accelerating pathway conversion. This is achieved by eliminating the initial lag phase in the supramolecular polymerization process. Overall, this study provides valuable insights into designing molecular structures that control aggregation pathways of π-conjugated nanostructures. 相似文献
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R. Calvani 《Fiber and Integrated Optics》1999,18(1):33-40
We demonstrate an original all-fiber self-injection seeding technique based on a noninterferometric reflector for the optical timing jitter reduction in a chirp compen sated gain-switched Distributed FeedBack (DFB) laser. Two experiments, at 2.5 and 5 GHz, show standard deviations of the optical timing jitter of 0.28 ps and a reduction factor of 17 in the best case. The self-injection seeding sensitivity to polarization effects and to modulating frequency changes was measured in terms of standard deviation. A final experiment at 10 GHz, with no external feedback, shows an optical timing jitter down to 0.4 ps due to a time dynamics of spontaneous emission fluctuations slower than the pulse period. 相似文献
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研究了以抗坏血酸和氯金酸为生长溶液制备金纳米花的反应机理. 结果表明, 通过改变生长溶液中抗坏血酸浓度可以调节小尺寸的初级金粒子在种子表面的聚集方式及金纳米花的熟化速度, 从而影响金纳米花的形貌和光学性质. 协同改变抗坏血酸浓度和pH值, 可实现对金纳米花形貌及光学性质的有效调控. 表面增强拉曼散射(SERS)性能评价结果表明, 抗坏血酸还原法制备的金纳米花表面较清洁, 对罗丹明6G有较好的拉曼增强效果. 相似文献