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101.
The flow induced by a finite disc rotating near horizontal ground is considered, including the effects of an underbody. This paper concentrates on determining the shape of the free layer beyond the rim of the disc which is horizontal in the absence of the underbody and ground but forced to deform to ensure that conditions across the layer are satisfied when the underbody or ground is added. The far-field behaviour, the inviscid flow produced by a nominally infinite disc near the ground and the global solution for small ground clearances are considered analytically, and the full problem is posed as an integral problem. This is then solved numerically and analytically. Results are presented for various heights of the disc above the ground and for discs with an axisymmetric underbody present. A universal form is found for the farfield shape (which is controlled by entrainment into the free layer) but both the underbody and the ground effects are found to increase very significantly for reduced clearances. 相似文献
102.
103.
The electrocatalytic oxidation of 2-propanol was investigated using on line differential electrochemical mass spectrometry (DEMS) on electrodeposited Pt and an arrange of bimetallics: Pt0.84Rh0.16, Pt0.70Rh0.30, Pt0.55Rh0.45. It has been observed that the Pt0.84Rh0.16 bimetallic electrode presented the best catalytic activity for 2-propanol electrochemical oxidation. Since 2-propanol is a secondary alcohol, only acetone and CO2 are produced. The total yield of CO2 and acetone has been determined from the DEMS measurements. It is found that acetone is the major product, as reported before for other electrodes. The acetone and CO2 yield depends on the electrode composition. High amount of rhodium in the electrode composition strongly diminish the reaction rate as indicated by the decrease of both the acetone and CO2 yield. However, acetone inhibition is much more intense. The only bimetallic electrode that presents considerable mass spectroscopy signals intensity for CO2 and acetone is the Pt0.84Rh0.16 electrode. This electrode shows a slight increase in CO2 selectivity, compared to the other electrodes studied in this work. Only very low coverages of stable adsorbates were present during the reaction. Two and one carbon adsorbate were observed for all the electrodes. Three carbon adsorbates were detected only for the Pt0.84Rh0.16 electrode. Therefore, acetone production does not require a stable adsorbate. 相似文献
104.
We introduce a candidate for the group algebra of a Hausdorff group which plays the same role as the group algebra of a finite group. It allows to define a natural bijection betweenk-continuous representations of the group in a Hilbert space and continuous representations of the group algebra. Such bijections are known, but to our knowledge only for locally compact groups. We can establish such a bijection for more general groups, namely Hausdorff groups, because we replace integration techniques by functorial methods, i.e., by using a duality functor which lives in certain categories of topological Banach balls (resp., unit balls of Saks spaces).This paper was written while the authors were supported by the Swiss National Science Foundation under grant 21-33644.92. 相似文献
105.
For improved mechanical and water‐swelling properties of chitosan films, a series of transparent films were prepared with dialdehyde starch as a crosslinking agent. Fourier transform infrared and X‐ray analysis results demonstrated that the formation of Schiff's base disturbed the crystallization of chitosan. The mechanical properties and water‐swelling properties of the films were significantly improved. The best values of the tensile strength and breaking elongation were 113.1 MPa and 27.0%, respectively, when the dialdehyde starch content was 5%. All the crosslinked films still retained obvious antimicrobial effects toward S. aureus and E. coli, and they showed potential for biomedical applications. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 993–997, 2003 相似文献
106.
Panagiotis Soules 《Archiv der Mathematik》2003,80(5):449-457
For soluble groups, the Fitting length is bounded by a function of the maximum order
of the Fitting subgroups of 2-generator subgroups. 相似文献
107.
The orientational relaxation of optically induced anisotropy in rarefied gases and at a damped rotation has been investigated. It has been found that the anisotropy relaxation in rarefied gases is described by a reduced kinetic equation depending only on free rotation integrals. The behavior of the integral anisotropy of luminescence for free symmetric and asymmetric top molecules has been elucidated. The law of luminescence depolarization has been obtained for asymmetric top molecules in the Gordon J-diffusion model. It represents the sum of two Stern–Volmer-type dependences, whose relative contribution is determined by the orientation of the dipole moments of transitions with absorption and emission of light in the molecular coordinate system and by the principal moments of inertia of the molecular top. It has been established that in the limit of a strongly damped rotation, kinetic equations of the general form reduce to equations of rotational diffusion. A number of modified diffusion equations correctly describing the contribution of inertial effects to the orientational relaxation of anisotropy have been obtained. 相似文献
108.
F. Despa R. S. Berry 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2003,24(1-3):37-40
Interpretive theoretical tools prove valuable in guiding
the analysis of experiments in the realm of atomic clusters.
Here, we review basic elements of an analytic approach that
makes it possible to find and visualize the effective
electrostatic potential and Coulomb correlations in multicenter
problems. To illustrate the utility of these concepts we apply
them to exploring molecular-doped metallic clusters. This study
is aiming at a systematic, visual assessment of changes induced
in screening, Coulomb correlation and effective potential by
varying the charge of the electronegative impurity and its
position in the cluster cage. 相似文献
109.
颗粒物质的两个典型效应及其研究现状的分析 总被引:6,自引:0,他引:6
概述了颗粒物质领域中粮仓现象和巴西坚果效应两个典型现象及其解释理论,分析其理论的成功和不足之处,并给出了一些看法。 相似文献
110.
2-Cyanoethyl anilines were controllably cleaved by 1 equiv of potassium t-butoxide in dry THF with a reaction that can be used in situ with the Wittig reaction to synthesize conjugated primary and secondary anilines. 相似文献