气相色谱-串联质谱法测定肉制品中10种挥发性N-亚硝胺类化合物

建立了气相色谱-串联质谱（GC-MS/MS）检测肉制品中10种挥发性N-亚硝胺类化合物残留量的方法。肉制品样品经同时蒸馏萃取法（SDE）萃取，采用冷冻去脂净化法，在多反应监测模式下分析，外标法定量。结果表明，采用优化后的条件，10种挥发性N-亚硝胺类化合物在1.00~1000 μg/L范围内线性关系良好，相关系数均在0.99以上。方法的检出限（LOD，S/N=3）和定量限（LOQ，S/N=10）分别为0.01~0.02 μg/kg和0.04~0.07 μg/kg。选取3种不同类型的肉制品（火腿肠、中式香肠和腌渍腊肉），在空白样品添加水平为LOQ水平、1.0、2.0 μg/kg时，10种挥发性N-亚硝胺类化合物的平均回收率为74.8%~94.3%，相对标准偏差小于8.3%。市售3类肉制品中6种挥发性N-亚硝胺类化合物（N-亚硝基二甲胺、N-亚硝基二乙胺、N-亚硝基吡咯烷、N-亚硝基哌啶、N-亚硝基二丁胺、N-亚硝基二丙胺）均有不同程度检出，且腌渍腊肉中每种挥发性N-亚硝胺类化合物的检出值最高。该方法操作简单，萃取充分，灵敏度高，试剂用量少，可满足实验室大量样品的日常检测需求。     

Limit of Solutions of a SDE with a Large Drift Driven by a Poisson Random Measure

We consider a sequence of {X _n} of R ^d-valued processes satisfying a stochastic differential equation driven by a Brownian motion and a compensated Poisson random measure, with _n ~ _n with a large drift. Let be a m-dimensional submanifold (m<d), where F vanishes. Then under some suitable growth conditions for _n ~ _n, and some conditions for F, we show that dist(X _n, )0 before it exits any given compact set, that is, the large drift term forces X _n close to . And if the coefficients converge to some continuous functions, any limit process must actually stay on and satisfy a certain stochastic differential equation driven by Brownian motion and white noise.     

Weak Solutions for SPDEs and Backward Doubly Stochastic Differential Equations

We give the probabilistic interpretation of the solutions in Sobolev spaces of parabolic semilinear stochastic PDEs in terms of Backward Doubly Stochastic Differential Equations. This is a generalization of the Feynman–Kac formula. We also discuss linear stochastic PDEs in which the terminal value and the coefficients are distributions.     

MULTIVALUED STOCHASTIC MCKEAN-VLASOV EQUATION

In this work, under global Lipschitz conditions, we prove the existence and uniqueness of strong solutions for multivalued stochastic McK ean-Vlasov equation. Moreover, under continuous and linear growth assumptions, we also obtain the existence of weak solutions.     

伊藤-泊松型随机微分方程的线性二次控制

本文研究伊藤-泊松型随机微分方程的线性二次控制问题,利用动态规划方法、伊藤公式等技巧,通过解HJB方程,我们得到了随机Riccati方程及另外两个微分方程,求出控制变量,解决了线性二次最优控制最优问题.     

Asymptotic behaviors for functionals of random dynamical systems

In this article, we consider asymptotic behaviors for functionals of dynamical systems with small random perturbations. First, we present a deviation inequality for Gaussian approximation of dynamical systems with small random perturbations under Hölder norms and establish the moderate deviation principle and the central limit theorem for the dynamical systems by the deviation inequality. Then, applying these results to forward-backward stochastic differential equations and diffusions in small time intervals, combining the delta method in large deviations, we give a moderate deviation principle for solutions of forward-backward stochastic differential equations with small random perturbations, and obtain the central limit theorem, the moderate deviation principle and the iterated logarithm law for functionals of diffusions in small time intervals.     

Enantiomeric Enrichments via the Self‐Disproportionation of Enantiomers (SDE) by Achiral,Gravity‐Driven Column Chromatography: a Case Study Using N‐(1‐Phenylethyl)acetamide for Optimizing the Enantiomerically Pure Yield and Magnitude of the SDE

This work explores the self‐disproportionation of enantiomers (SDE) via achiral, gravity‐driven column chromatography as typically used in laboratory settings for the purpose of enantiomeric enrichment using N‐(1‐phenylethyl)acetamide (PEA) as a case study. The major finding of this work is the very large magnitude of the SDE for PEA across a variety of conditions and broad range of starting ee values, thereby facilitating a simple, reliable, and predictable means of obtaining enantiomerically pure samples. For example, starting with a sample of PEA of ee as low as 28%, a single column run yielded an enantiomerically pure sample (>99.9% ee) from the first fractions and a significantly enantiomerically depleted sample (<17% ee) from the final fractions. An assessment of SDE via achiral, gravity‐driven column chromatography was also rendered with regard to the differing objectives that workers might target – a large magnitude of the SDE, obtaining an optimum sample of desired ee, or preparative‐scale separation of the excess enantiomer. Overall, it can be considered that the SDE phenomenon via achiral, gravity‐driven column chromatography – readily applicable in the usual laboratory settings – is a simple and convenient method for enantiomeric enrichment with a high degree of proficiency. Advantages of SDE via achiral, gravity‐driven column chromatography over conventional fractional recrystallization for the enantiomeric enrichment of amides/amines, and applicable also to many other classes of compounds as well, are discussed.     

环境噪声对具有捕获的种群竞争系统的影响

运用色噪声刻画环境变化性构造了随机的具有捕获的两种群竞争的Gompertz模型,讨论了环境变化和人工捕获对种群生长过程的影响.通过求解在平衡点处线性化的随机微分方程,计算出了两种群偏离平衡点处的期望和方差,研究得到环境随机性虽然会导致种群密度随机变化,但随着时间的增长,种群的密度变化只可能在平衡状态处摆动.最后还讨论了为减少两种群灭绝可能性,系统保持稳定的参数域.     

Pathwise uniqueness of multi-dimensional stochastic differential equations with H?lder diffusion coefficients

We extend Yamada-Watababe’s criterion [J. Math. Kyoto Univ., 1971, 11: 553–563] on the pathwise uniqueness of one-dimensional stochastic differential equations to a special class of multi-dimensional stochastic differential equations.     

GC-MS法测定大葱、细香葱、小葱中的挥发性物质

葱是多年生草本百合科植物,有大葱、香葱、小葱、青葱等多个品种。葱类蔬菜具有强烈的杀菌作用,尤其是对痢疾杆菌以及皮肤真菌抑制作用强烈。葱能增加纤维蛋白的溶解活性和降低血脂的作用,对心血管疾病有一定的疗效,还可降胆固醇,减少血小板凝集,调节血糖,增加淋巴细胞与巨噬细胞血性,提高免疫力和抗癌。本试验采用同时蒸馏-萃取方法(simultaneousdistillationandextraction,SDE)提取其中的挥发性成分,GC-MS分析并初步确定了化合物的化学组成和相对百分含量。