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51.
Rooha Khurram Zaib Un Nisa Aroosa Javed Zhan Wang Mostafa A. Hussien 《Molecules (Basel, Switzerland)》2022,27(4)
This study describes the preparation of graphitic carbon nitride (g-C3N4), hematite (α-Fe2O3), and their g-C3N4/α-Fe2O3 heterostructure for the photocatalytic removal of methyl orange (MO) under visible light illumination. The facile hydrothermal approach was utilized for the preparation of the nanomaterials. Powder X-ray diffraction (XRD), Scanning electron microscopy (SEM), Energy dispersive X-ray (EDX), and Brunauer–Emmett–Teller (BET) were carried out to study the physiochemical and optoelectronic properties of all the synthesized photocatalysts. Based on the X-ray photoelectron spectroscopy (XPS) and UV-visible diffuse reflectance (DRS) results, an energy level diagram vs. SHE was established. The acquired results indicated that the nanocomposite exhibited a type-II heterojunction and degraded the MO dye by 97%. The degradation ability of the nanocomposite was higher than that of pristine g-C3N4 (41%) and α-Fe2O3 (30%) photocatalysts under 300 min of light irradiation. The formation of a type-II heterostructure with desirable band alignment and band edge positions for efficient interfacial charge carrier separation along with a larger specific surface area was collectively responsible for the higher photocatalytic efficiency of the g-C3N4/α-Fe2O3 nanocomposite. The mechanism of the nanocomposite was also studied through results obtained from UV-vis and XPS analyses. A reactive species trapping experiment confirmed the involvement of the superoxide radical anion (O2•−) as the key reactive oxygen species for MO removal. The degradation kinetics were also monitored, and the reaction was observed to be pseudo-first order. Moreover, the sustainability of the photocatalyst was also investigated. 相似文献
52.
压印光刻中套刻需要粗、精两级对正.实验采用一对斜纹结构光栅作为对正标记.利用物镜组观察光栅标记图像的边界特征进行粗对正,其准确度在精对正信号的捕捉范围内;利用光电接收器件阵列组合接收光栅莫尔信号,在莫尔信号的线区进行精对正.由于线性区的斜率大, 精对正过程中得到相应x,y方向的对正误差信号灵敏度高,利用高灵敏度对正误差信号作为控制系统的驱动信号,对承片台进行驱动定位,实现精对正.最终使X,Y方向上的重复对正准确度分别达到了± 21 nm(± 3σ)和±24 nm(± 3σ). 相似文献
53.
仿真和实验研究了一种控制Nd:YAG脉冲激光能量通断的光纤直接连接型光开关。建立光纤耦合模型,分析了光纤对准误差中对耦合效率的影响,其中横向偏移的影响最显著。采用微机电系统V型槽固定光纤,微小型凸轮作为制动器,步进电机驱动凸轮旋转,微小型凸轮与移动光纤相切,带动光纤移动,实现两光纤的错开和对准。制造了这种高功率直接连接型光纤光开关原理样机,并进行了主要性能测试。测试结果表明,这种光开关能够满足激光点火系统的大容量、高隔离度的要求。 相似文献
54.
Zbigniew Kisiel Lech Pszczó?kowski Steven B. Charnley 《Journal of Molecular Spectroscopy》2007,241(2):220-229
The rotational spectrum of pyruvic acid has been investigated for the first time in the millimeter-wave region, at 160-314 GHz, and also in supersonic expansion, at 10-17.4 GHz. The analysis of the broadband spectra recorded in this work was carried out with the newly developed AABS software package for Assignment and Analysis of Broadband Spectra, and precise spectroscopic constants are reported for the ground state, the first excited state of the low-frequency skeletal torsional mode ν24, and the first excited state of the methyl torsional mode ν23. Limited results have also been obtained for several higher excited states. The dataset for the ground state currently exceeds 1500 lines and for both the A and E internal rotor sublevels spans the complete range of values of Ka at the mid values of J for the measured transitions. The results were analysed with three freely available computer programs employing different strategies for dealing with internal rotation and a comparative discussion of their merits is made. 相似文献
55.
安装于紫金山天文台盱眙观测站用以观测近地天体的大型Schmidt望远镜,采用了平场Schmidt光学系统,改正镜通光口径为1m,球面反射镜口径为1.2m,焦距为1.8m,接收器用了4K×4K的高灵敏度CCD。本文叙述了该仪器光轴调整的方法及调整后观测获得的初步结果。叙述了望远镜光轴校正方法、校正结果、CCD靶面的调整及望远镜极轴高度、方位的调整及相应的照片。经实际观测的结果是:露光1s可拍到18等星;露光4s可拍到19.3等星;露光20s可拍摄到21.2等星。 相似文献
56.
F. Hegelund R. Wugt Larsen R.A. Aitken K.M. Aitken M.H. Palmer 《Journal of Molecular Spectroscopy》2007,246(2):198-212
The Fourier transform infrared spectrum of gaseous 1,3,4-oxadiazole, C2H2N2O, has been recorded in the 800–1600 cm−1 wavenumber region with a resolution around 0.0030 cm−1. The four fundamental bands ν9(B1; 852.5 cm−1), ν14(B2; 1078.5 cm−1), ν4(A1; 1092.6 cm−1), and ν2(A1; 1534.9 cm−1) are analyzed by the standard Watson model. Ground state rotational and quartic centrifugal distortion constants are obtained from a simultaneous fit of ground state combination differences from three of these bands and previous microwave transitions. Upper state spectroscopic constants are obtained for all four bands from single band fits using the Watson model. The ν4 and ν14 bands form a c-Coriolis interacting dyad, and the two bands are analyzed simultaneously by a model including first and second order Coriolis resonance using the ab initio predicted Coriolis coupling constant . An extended local resonance in ν2 is explained as higher order b-Coriolis type resonance with ν6 + ν10, which is further perturbed globally by the ν15 + ν10 level. A fit of selected low-J transitions to a triad model including ν2(A1), ν6 + ν10(B1), and ν15 + ν10(A2) using an ab initio calculated Coriolis coupling constant is performed.The rotational constants, ground state quartic centrifugal distortion constants, anharmonic frequencies, and vibration–rotational constants (α-constants) predicted by quantum chemical calculations using a cc-pVTZ and TZ2P basis with B3LYP methodology, are compared with the present experimental data, where there is generally good agreement. A complete set of anharmonic frequencies and α-constants for all fundamental levels of the molecule is given. 相似文献
57.
The accurate measurement of small spin–spin coupling constants in macromolecules dissolved in a liquid crystalline phase is important in the context of molecular structure investigation by modern liquid state NMR. A new spin-state-selection filter, DIPSAP, is presented with significantly reduced sensitivity to J-mismatch of the filter delays compared to previously proposed pulse sequences. DIPSAP presents an attractive new approach for the accurate measurement of small spin–spin coupling constants in molecules dissolved in anisotropic solution. Application to the measurement of 15N–13C′ and 1HN–13C′ coupling constants in the peptide planes of 13C, 15N labeled proteins demonstrates the high accuracy obtained by a DIPSAP-based experiment. 相似文献
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