三维荧光光谱结合交替惩罚三线性分解同时对水中三种酚类测定

酚类化合物对动植物机理有着严重危害,利用三维荧光光谱结合交替惩罚三线性分解（APTLD）算法,完成了不含干扰物和干扰物共存时激发-发射荧光光谱重叠严重的麝香草酚、对苯二酚和苯酚的直接快速准确定性、定量分析。研究了温度对三种酚类化合物荧光强度的影响。对扫描所得激发-发射矩阵信号（EEM）进行二次去散射和光谱校正预处理,最大程度保留了原光谱信息,避免光谱严重失真。将APTLD算法与平行因子（PARAFAC）和交替三线性分解（ATLD）算法进行对比,突显该算法的优势。实验得出,APTLD算法能够较好的解析荧光光谱数据的重叠峰,分别得到三种目标分析物的荧光光谱,实现快速定性分析;定量分析时平均回收率为（97.4±4.5）%~（103.1±3.0）%;预测均方根误差（RMSEP）低于1.664×10-2 μg·mL-1,且检测限低于国家标准;处理过程简洁快速,为水环境中酚类化合物实现现场检测和在线实时监测提供了有力依据。     

基于变刚度结构的光纤布拉格光栅低温环境下的温度増敏方法研究

光纤布拉格光栅采用非电磁信号测试方式,具有显著的抗电磁干扰以及可嵌入被测结构内部等特性,已成为近些年广受关注的光学应变、温度传感与测试新技术。但在极端条件下(如超低温环境),光纤由于受到其自身材料特性的局限,传感特性不明显甚至限制了其应用。基于结构变刚度的力学増敏方法,本文提出了一种适用于低温区的光纤布拉格光栅温度传感増敏的结构设计方法。研究结果表明：该传感结构可有效感应低温下的温度变化,増敏效果明显;并获得増敏效果随结构材料与几何特性的依赖关系,经过优化可使得光栅区对温度和应变的敏感性大大提高,甚至提高1个数量级。最后,完成了这一増敏结构的设计和制备,实验验证了所提方法的有效性和可靠性。     

Fast fat-suppressed reduced field-of-view temperature mapping using 2DRF excitation pulses

The purpose of this study is to develop a fast and accurate temperature mapping method capable of both fat suppression and reduced field-of-view (rFOV) imaging, using a two-dimensional spatially-selective RF (2DRF) pulse. Temperature measurement errors caused by fat signals were assessed, through simulations. An 11×1140μs echo-planar 2DRF pulse was developed and incorporated into a gradient-echo sequence. Temperature measurements were obtained during focused ultrasound (FUS) heating of a fat-water phantom. Experiments both with and without the use of a 2DRF pulse were performed at 3T, and the accuracy of the resulting temperature measurements were compared over a range of TE values. Significant inconsistencies in terms of measured temperature values were observed when using a regular slice-selective RF excitation pulse. In contrast, the proposed 2DRF excitation pulse suppressed fat signals by more than 90%, allowing good temperature consistency regardless of TE settings. Temporal resolution was also improved, from 12 frames per minute (fpm) with the regular pulse to 28 frames per minute with the rFOV excitation. This technique appears promising toward the MR monitoring of temperature in moving adipose organs, during thermal therapies.     

CO2-broadened water in the pure rotation and ν2 fundamental regions

The CO₂-broadened water coefficients (half-widths, line shifts, and temperature dependence of the widths) are predicted using a fully complex Robert-Bonamy formulation for the 937 allowed and forbidden perpendicular type transitions of (000)-(000) between 200 and 900 cm⁻¹ in order to facilitate atmospheric remote sensing of Mars and Venus. In addition, empirical Lorentz line widths and pressure-induced frequency-shifts of CO₂-broadened H₂¹⁶O are obtained at room temperature for 257 perpendicular transitions of the (010)-(000) fundamental. For this, calibrated spectra recorded at 0.0054 cm⁻¹ resolution are measured assuming Voigt line shapes. For transitions between 1287 and 1988 cm⁻¹ with rotational quanta up to J = 13 and K_a = 6, the widths vary from 0.045 to 0.212 cm⁻¹ atm⁻¹ at 300 K; the pressure-shifts are quite large and range from −0.0386 to +0.0436 cm⁻¹ atm⁻¹. For the (010)-(000) band, the RMS and mean observed and calculated differences for CO₂-broadened H₂O half-widths are 12% and −1.9%, respectively, while the RMS and mean ratios of the observed and calculated pressure-induced shift coefficients are 1.6 and 0.79, respectively. For pairs of transitions involving K_a = 0 and 1, such as 2_0 2 ← 3_1 3 and 3_1 3 ← 2_0 2, both the calculated and observed pressure induced shifts in positions are opposite in sign and often similar in magnitude. The data are too limited to characterize vibrational dependencies of the widths, however.     

Cavity effects in coiled coil IR reference source

We performed a high resolution imaging of a coiled coil filament used in tungsten lamps, a standard reference source in spectroscopy. The radiometric results using two-wavelength thermometry indicate that its configuration also introduces cavity effects and non-uniformity of filament temperature distribution, with the average temperature calculated to be 2869 K. Considering the tungsten source as an extended body, significant temperature variations of up to +19 K are found above its nominal 2850 K value.     

Temperature dependence of the properties of strong-coupling bipolaron in a quantum dot

Temperature dependence of the properties of strong-coupling bipolaron in a quantum dot (QD) is studied based on the Lee-Low-Pines-Huybrechts variational method and quantum statistical theory. Results of the numerical calculation show that the vibration frequency as well as the absolute value of the induced potential and the effective potential all increase with increasing coupling strength and temperature, respectively, and they also increase with decreasing relative distance of electrons. The bipolarons are closer and more stable when the temperature is higher and coupling strength is larger. The influence of radius of QD and dielectric constant ratio on the effective potential is little.     

光纤光栅温度与轴向应变响应机制分析

本文对温度和轴向应变对长周期光纤光栅和Bragg光纤光栅耦合波长的影响机制作出分析,通过有代表性的举例计算数值给出了各因素对耦合波长的影响,指出轴向应变对耦合波长的影响除了来自光弹性效应带来的光纤折射率的改变外,光纤半径的变化,特别是光栅周期的改变也起重要作用.对比分析找到了长周期光纤光栅与Bragg光纤光栅温度,应变响应系数数量级异同的原因.     

谱带吸收式光纤温度传感器

本文提出了一种新颖的半导体谱带吸收式光纤温度传感器系统结构.分析了半导体谱带吸收式光纤温度传感器的原理,推导了其数学模型.该传感器用反射式传感结构,以砷化镓半导体材料作为温度敏感元件,并利用除法器消除了传感器光源的波动及光纤的连接损耗,使传感器具有结构简单、抗环境干扰、高可靠性特点.文中对传感器的整个系统进行了设计和分析,并进行了实验测试,实验结果显示:该传感器在－20～110℃的温度范围内有1℃的测量精确度,并且温度从110℃降到15℃时的时间响应为25s.     

紫膜（BR）水溶液共振Raman光谱的温度相关性

本文报道了ＢＲ水溶性Ｒａｍａｎ光谱的温度相关性及吸收光谱变化。讨论了导致光谱变化的热诱导引起的结构变化。