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991.
Alexander JS Ruhlandt-Senge K 《Chemistry (Weinheim an der Bergstrasse, Germany)》2004,10(5):1274-1280
Progress in the field of sigma-bonded alkaline earth organometallics has been handicapped by numerous complications, such as high reactivity, low solubility, and the limited availability of suitable starting materials. Here we present two synthetic methods, hydrocarbon elimination and desilylation, as alternative routes into this chemistry. A novel barium diphenylmethanide was prepared using these routes delineating that both methods provide a powerful, versatile synthetic access route to an extended library of organometallic alkaline earth derivatives. 相似文献
992.
Koji Watanabe 《Tetrahedron letters》2005,46(23):3991-3995
A convergent synthetic route to the FGHI ring system of yessotoxin, a marine ladder polyether, has been developed. The synthesis features convergent coupling of the diol and the aldehyde to form α-cyano ethers via acetal formation followed by ring closing metathesis and reductive etherification to construct the oxocane ring G and tetrahydropyran ring H, respectively. The β-methyl group on the G ring was stereoselectively introduced by alkylation of the corresponding ketone. 相似文献
993.
Novel cleavage patterns of CC bonds and CSi bonds were achieved via alkyne- or ketone-induced reactions of zirconacyclobutene-silacyclobutene fused ring compounds; thermodynamically favored six-membered zirconacyclohexadiene derivatives were formed in excellent yields from the four-membered zirconacyclobutenes via this unprecedented alkyne-induced CC bond and CSi bond cleavage process. 相似文献
994.
Steven D. Dong Kurt Sundermann Karen M.J. Smith Joseph Petryka Fenghua Liu David C. Myles 《Tetrahedron letters》2004,45(9):1945-1947
A facile and efficient route to epothilone analogs has been developed from the natural product epothilone D (1). Degradation of 1 via an oxidative cleavage sequence provides acid intermediate 4 rapidly in six steps. From 4, a variety of epothilone analogs have been prepared utilizing ring-closing metathesis to reconstruct the trisubstituted-12,13-double bond. Using this approach, we report a number of epothilone analogs with varying C-15 aromatic side chains and C-14 allylic substitutions and their biological activities. 相似文献
995.
2-Oxo-5-(1-arylvinyl)-4-piperidin-1-yl-2,5-dihydrofuran-3-carbonitriles 3 have been synthesized through ring contraction of suitably functionalized 2H -pyran-2-ones 1 by a carbanion generated in situ from nitromethane 2 in good yield. In some cases their counterpart tautomers 2-oxo-5-(1-arylethylidene)-4-piperidin-1-yl-2,5-dihydrofuran-3-carbonitriles 4 have also been isolated and characterized as minor products. 相似文献
996.
Makoto Tokunaga Yuki Shirogane Hiroshi Aoyama Yasushi Obora Yasushi Tsuji 《Journal of organometallic chemistry》2005,690(23):5378-5382
A novel CC bond cleavage reaction of aromatic enol ethers (1) to give ketones (2) using molecular oxygen as oxidant is described. Among the examined catalysts (Cu(II), Pd(II), Ru(II), and H+), CuCl2 exhibited the highest activity. The reaction proceeded smoothly with several kinds of substrates. 相似文献
997.
The palladium-catalyzed allylation of aryl halides with homoallyl alcohols via retro-allylation proceeds at 200-250 °C in a toluene-DMF mixed solvent using microwave heating. Even at such high temperatures, the regio- and stereospecificity of the allyl transfer reaction is still satisfactory. The amount of the palladium catalyst can be reduced to 0.5 or 0.05 mol %. 相似文献
998.
四氢呋喃开环均聚以及四氢呋喃和环硫氯丙烷共聚新催化体系 总被引:4,自引:0,他引:4
研究发现无水稀土氯化物 50%发烟硫酸体系是四氢呋喃(THF)均聚和四氢呋喃与环硫氯丙烷(CMT)共聚合的优良新催化体系.考察了THF均聚反应特征,在合适条件下,THF聚合以65%转化率制得粘均分子量达10,000~15,000的白色聚四氢呋喃(PTHF)固体.端羟基分析法测得聚合物的分子链两端均为羟基.考察了影响THF CMT共聚合反应诸因素,如聚合温度和时间、两单体的比例等,制得数均分子量为1,000左右的淡黄色粘性固体共聚物. 相似文献
999.
Three batches of leather samples were coloured with nine azo dyes that can yield eight proven or suspected carcinogenic aromatic
amines under reduction conditions. The samples were milled to grains and bottled in jars. A group of five laboratories has
established the mass fraction of the amines in a ring test using different analytical methods. The methods included a reduction
step in order to cleave the azo dyes into the aromatic amines. Quantification was by standard addition: sub-samples of the
leathers were spiked with known amounts of azo dyes of known purity. It was possible to establish the mass fractions of six
of the eight aromatic amines in three of the leather samples. 相似文献
1000.
Werner Schroth Monika Richter Bodo Dobner Roland Spitzner Sabine Freitag 《Monatshefte für Chemie / Chemical Monthly》1988,119(4):463-476
The title compounds3 have been prepared by ring transformation reactions of the isomeric 2-sec-amino-1,3-thiazine-6-thiones1 via ring-opening products2 and by special cyclocondensation reactions with thiocarboxamides8, and with iminium salts10, starting from 2,2-dichlorovinyl ketones6 in all cases. The pathways differ specifically in scope and limitations. On the other hand the intermediates2 react with alkylating agents to 2,6-di-sec-amino-1,3-thiazinium salts4, which are also available via alkylation of3 to 2-methylthio-1,3-thiazinium salts11 and aminolysis. Moreover,11 serve as useful precursors for other 1,3-thiazine derivatives by nucleophilic methylthio displacement (examples12). 相似文献