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931.
The nuclear spin conversion of a molecule is the modification of the total nuclear spin I of its equivalent atoms. This phenomenon is observed by measuring the relaxation rate of a gas sample initially prepared with a population of spin isomers far from the equilibrium given by nuclear spin statistics. New experimental data obtained at low pressure show a surface-induced enhancement of the nuclear spin conversion in 13CH3F. Contrary to binary collisions in the gas phase, hitting the surface induces direct conversion. Several mechanisms are proposed. 相似文献
932.
The electronic structure of 3d transition-metal atoms on face-centered cubic Co(0 0 1) substrate is determined within ab initio density functional calculations in the gradient corrected approach. Calculations are performed for ordered surface configuration with coverage equal to 0.25, 0.5, 0.75 and 1 ML. For Ni and Fe a ferromagnetic coupling with the Co atoms is always obtained independently of the concentration. Moreover the values of the magnetic moments remain similar. For Mn a ferromagnetic coupling is obtained for low-coverage whereas an in-plane antiferromagnetic coupling is found for a complete Mn overlayer on Co(0 0 1). Also, for Sc, Ti, V and Cr a drastic modification of the magnetic map is observed when we go from low-coverage to the monolayer. Cr (Mn) adatoms present antiferromagnetic (ferromagnetic) coupling with Co(0 0 1) for x = 0.25 whereas an in-plane antiferrimagnetic coupling is obtained for x = 1.00. 相似文献
933.
Hybrid HF-DFT LCAO simulations of (0 0 1) surface properties and water adsorption on cubic SrZrO3 and SrTiO3 perovskites are performed using a single slab model framework. Three slab models with the different surface termination including 6-11 atomic planes were used for calculations. The effect of the symmetry reduction and the role of an extra atomic layer basis set have been considered for the bare surface slabs. The optimized structures and water adsorption energies have been calculated for the various types of surface coverage. It is shown that the formation of H-bonds between the water hydrogens and surface oxygens, as well as between the water molecules themselves, controls the structure of the water adsorption layers on the perovskite surfaces. Obtained results indicate that the dissociative type of water adsorption is the energetically more favourable for SrO-terminated zirconate surface than for similar titanate surface giving evidence to the more basic nature of oxygen atoms on SrO-terminated SrZrO3 surface. 相似文献
934.
M. R. Flannery E. Oks 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2008,47(1):27-31
A Rydberg atom embedded in a plasma can experience penetration by slowly moving electrons within its volume. The original
pure Coulomb potential must now be replaced by a screened Coulomb potential which contains either a screening length Rs or a screening factor A = Rs
-1 . For any given discrete energy level, there is a Critical Screening Factor (CSF) Ac beyond which the energy level disappears (by merging into the continuum). Analytical results are obtained for the classical
dependence of the energy on the screening factor, for the CSF, and for the critical radius of the electron orbit for Circular
Rydberg States (CRS) in this screened Rydberg atom. The results are derived for any general form of the screened Coulomb potential
and are applied to the particular case of the Debye potential. We also show that CRS can temporarily exist above the ionization
threshold and are therefore the classical counterparts of quantal discrete states embedded into continuum. The results are
significant not only to Rydberg plasmas, but also to fusion plasmas, where Rydberg states of multi-charged hydrogen-like ions
result from charge exchange with hydrogen or deuterium atoms, as well as to dusty/complex plasmas. 相似文献
935.
A. Pashov P. Popov H. Knöckel E. Tiemann 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2008,46(2):241-249
We report on high resolution Fourier-transform spectroscopy of fluorescence to the a3Σu
+ state induced by two-photon or two-step excitation from the X1Σg
+ state to the 23Πg state in the molecule K2. These spectroscopic data are combined with recent results of Feshbach resonances and two-color photoassociation spectra
for deriving the potential curves of X1Σg
+ and a3Σu
+ up to the asymptote. The precise relative position of the triplet levels with respect to the singlet levels was achieved
by including the excitation energies from the X1Σg
+ state to the 23Πg state and the frequencies of the fluorescence down to the a3Σu
+ state in the simultaneous fit of both potentials. The derived precise potential curves allow for reliable modeling of cold
collisions of pairs of potassium atoms in their 2S ground state.
Electronic supplementary material Supplementary Online Material 相似文献
936.
K. Doll 《Surface science》2004,573(3):464-473
The adsorption of CO on the Pt(1 1 1) surface in a pattern has been studied with the gradient corrected functional of Perdew and Wang and the B3LYP hybrid functional. A slab which is periodic in two dimensions is used to model the system. The Perdew-Wang functional incorrectly gives the fcc site as the most favorable adsorption site, in accord with a set of previous studies. The B3LYP functional gives the top site as the preferred site. This confirms results from cluster studies where it was suggested that the different splitting, dependent on the functional, between highest occupied and lowest unoccupied molecular orbital, could be the reason for this change of the adsorption site. This is supported by an analysis based on the projected density of states and the Mulliken population. 相似文献
937.
J. Tempere S.N. Klimin I.F. Silvera J.T. Devreese 《The European Physical Journal B - Condensed Matter and Complex Systems》2003,32(3):329-338
The properties of ripplonic polarons in a multielectron bubble in liquid helium are investigated on the basis of a path-integral
variational method. We find that the two-dimensional electron gas can form deep dimples in the helium surface, or ripplopolarons,
to solidify as a Wigner crystal. We derive the experimental conditions of temperature, pressure and number of electrons in
the bubble for this phase to be realized. This predicted state is distinct from the usual Wigner lattice of electrons: it
melts by dissociation of the ripplopolarons when the electrons shed their localizing dimple as the pressure on the multielectron
bubble drops below a critical value.
Received 20 February 2003 Published online 11 April 2003
RID="a"
ID="a"Also at: TU Eindhoven, Eindhoven, The Netherlands e-mail: devreese@uia.ua.ac.be 相似文献
938.
Equilibrium phase coexistence between two chemical species implies the equality of the chemical potentials and of the osmotic
pressures. We study this problem on a deformable membrane when one type of the molecules serves as anchor for polymeric chains
immersed in the surrounding medium (considered as a good solvent). We derive the general conditions for phase coexistence
when both the curvature of the membrane and the density field of the anchor molecule are free to adjust themselves. We show
that curvature favors phase segregation. Our model predicts that membranes decorated with polymeric chains exhibit new shape
bifurcations without equivalent in fixed density systems.
Received: 26 November 2002 / Accepted: 2 April 2003 / Published online: 12 May 2003
RID="a"
ID="a"e-mail: nicolas@drfmc.ceng.cea.fr
RID="b"
ID="b"e-mail: bfourcade@cea.fr 相似文献
939.
940.
We complement Catanese's results on isotrivially fibred surfaces by completely describing the components containing an isotrivial surface with monodromy group . We also give an example for deformation equivalent isotrivial surfaces with different monodromy group.