全文获取类型
收费全文 | 547篇 |
免费 | 41篇 |
国内免费 | 31篇 |
专业分类
化学 | 292篇 |
力学 | 42篇 |
综合类 | 1篇 |
数学 | 71篇 |
物理学 | 213篇 |
出版年
2023年 | 22篇 |
2022年 | 31篇 |
2021年 | 14篇 |
2020年 | 17篇 |
2019年 | 5篇 |
2018年 | 13篇 |
2017年 | 26篇 |
2016年 | 36篇 |
2015年 | 19篇 |
2014年 | 27篇 |
2013年 | 51篇 |
2012年 | 43篇 |
2011年 | 42篇 |
2010年 | 23篇 |
2009年 | 44篇 |
2008年 | 34篇 |
2007年 | 31篇 |
2006年 | 22篇 |
2005年 | 18篇 |
2004年 | 16篇 |
2003年 | 13篇 |
2002年 | 9篇 |
2001年 | 9篇 |
2000年 | 11篇 |
1999年 | 4篇 |
1998年 | 9篇 |
1997年 | 2篇 |
1996年 | 1篇 |
1993年 | 4篇 |
1992年 | 5篇 |
1991年 | 2篇 |
1990年 | 3篇 |
1989年 | 5篇 |
1988年 | 1篇 |
1987年 | 2篇 |
1982年 | 2篇 |
1981年 | 1篇 |
1980年 | 1篇 |
1978年 | 1篇 |
排序方式: 共有619条查询结果,搜索用时 140 毫秒
31.
异辛醇中酶催化高效合成阿莫西林的研究 总被引:1,自引:1,他引:0
通过比较6种有机溶剂作为反应介质时对阿莫西林合成的影响,发现反应介质在保持酶的催化活性和稳定性方面发挥着非常重要的作用,确定异辛醇为酶催化合成阿莫西林的反应介质.通过研究不同温度下异辛醇中酶催化合成阿莫西林的时间曲线,确定了最佳反应温度和反应时间,通过对底物浓度和酶浓度进行响应面优化,最终得到阿莫西林合成的最优反应条件,在最优条件下可得到91.37%的最大阿莫西林产率. 相似文献
32.
TANG Jian MA Rui-li LI Qian-qian JIANG Chun-bao CHEN Rui OUYANG Zhen CHEN Hai-sheng 《高等学校化学研究》2013,(6):1072-1077
For the efficient extraction of kamebakaurin(KA), the ultrasound-assisted extraction(UAE) of KA from Rabdosia excisa(R, excisa) via response surface methodology(RSM) was investigated with high-performance liquid chromatography(HPLC). Effects of the experimental parameters such as extraction solvent, ratio of liquid to plant material, extraction time and extraction temperature on the extracting efficiency of KA from R. excisa were evaluated, and the purity of KA in residual was calculated. The optimized conditions were 65.5%(volume fraction) acetone, 35 ℃, time of 24.6 min with ultrasound of 80 W/L, 40 kHz, ratio of liquid to plant material at 30:1(mL/g). The maximum yield of KA is 0.708 mg/kg, with mean purity of 6.09%, indicating that ultrasound-assisted extraction is a feasible and useful method for extracting KA from R. excisa. 相似文献
33.
Solid-phase microextraction and gas chromatography-mass spectrometry of volatile compounds from avocado puree after microwave processing 总被引:1,自引:0,他引:1
Microwave processing offers an alternative to blanch fruits and vegetables, since the application of high temperature and short time often results in minimum damage. An experimental design was used to investigate the effect of microwave time, pH, and avocado leaves (independent variables) on avocado flavor (response) using solid-phase microextraction (SPME)-GC-MS. Among the fully characterized flavor volatiles, 19 compounds were derived from lipid oxidation and only 4 from the avocado leaves. The main components derived from lipids were aldehydes, ketones and alcohols. Terpenoids, estragole, and 2-hexenal [E] were volatiles derived from avocado leaves. When leaves were added to fresh and microwaved avocado terpenoids and 2-hexenal [E]/hexanal ratio increased, this behavior was considered to have a positive effect on the sensorial quality of the product. From the statistical analysis of the experimental design, it was possible to determinate that the most important factors influencing the abundance of flavor compounds derived from lipids were microwave time and pH. Maximum values of these compounds were detected at high levels of microwave time and low values of pH. On the other hand, response surface of terpenoids and estragole showed an increment when microwave time and avocado leaf was increased. The region of optimum response was 30 s microwave time, pH 5.5, and 1% of avocado leaf. 相似文献
34.
35.
A. Pautrat A. Daignere C. Goupil Ch. Simon B. Andrzejewski A.I. Rykov S. Tajima 《The European Physical Journal B - Condensed Matter and Complex Systems》2003,33(3):279-284
We report complex impedance measurements in an untwinned YBaCuO crystal. Our broad frequency range covers both the quasi static
response and the resistive response of the vortex lattice. It allow us to characterize the irreversibility line without the
need of any frequency dependent pinning parameters. We confirm the validity of the two modes model of vortex dynamic, and
extract both the surface critical current and the flux flow resistivity around the first order transition Tm. This latter is identified by the abrupt loss of pinning and by an unexpected step of (T) at Tm.
Received 22 November 2002 / Received in final form 17 February 2003 Published online 20 June 2003
RID="a"
ID="a"e-mail: alain.pautrat@ismra.fr
RID="b"
ID="b"UMR 6508 associée au CNRS 相似文献
36.
A. Maeyens J. Tempere 《The European Physical Journal B - Condensed Matter and Complex Systems》2007,58(3):231-236
We consider a superconducting material that exists in the liquid state, more
precisely, in which the Meissner-Ochsenfeld effect persists in the liquid
state. First, we investigate how the shape of such a hypothetical Meissner
liquid will adapt to accomodate for an applied external field. In particular,
we analyse the case of a droplet of Meissner fluid, and compute the elongation
of the droplet and its quadrupole frequency as a function of the applied
field. Next, the influence of an applied field on the flow of the liquid is
studied for the case of a surface wave. We derive the dispersion relation for
surface waves on an incompressible Meissner fluid. We discuss some candidate
realizations of the Meissner fluids and for the case of a superconducting
colloid discuss which regime of wave lengths would be most affected by the
Meissner effect. 相似文献
37.
N. Sankara Subramanian R. Vivek Sabaapathy P. Vickraman G. Vimal Kumar R. Sriram B. Santhi 《Ionics》2007,13(5):323-328
P-type porous silicon (PS) structure has been prepared by anodic electrochemical etching process under optimized conditions.
Photoluminescence studies of the PS structure show emission at longer wavelengths (red) for the excitation at 365 nm. Scanning
electron microscope investigations of the PS surface confirm the formation of uniform porous structure, and the pore diameter
have been estimated as 25 μm. Pd:SnO2/PS/p-Si heterojunction with top gold ohmic contact developed by conventional methods has been used as the sensor device.
Sensing properties of the device towards liquefied petroleum gas (LPG) and NO2 gas have been investigated in an indigenously developed sensor test rig. The response and recovery characteristics of the
sensor device at different operating temperatures show short response time for LPG. From the studies, maximum sensitivity
and optimum operating temperature of the device towards LPG and NO2 gas sensing has been estimated as 69% at 180 °C and 52% at 220 °C, respectively. The developed sensor device shows a short
response time of 25 and 57 s for sensing LPG and NO2 gases, respectively.
Paper presented at the Third International Conference on Ionic Devices (ICID 2006), Chennai, Tamilnadu, India, Dec. 7–9, 2006. 相似文献
38.
A laser power meter based on water as an absorbing medium has been developed to measure multi-kilowatt CO2 laser power with high sensitivity and accuracy. Water absorbs CO2 laser radiation readily within a very thin layer. Though water has large thermal capacity, due to short absorption length, it could vapourize at high laser powers. In order to circumvent this problem, this power meter has a centre cone and a rapidly spinning water film as the calorimetric medium. The unique feature in this development is the centre cone, which diverges the beam and reduces the power density thus reduces the possibility of vapourization. This minimizes the error in measurements. Due to the rapidly moving fluid film, it exhibits fast response at low as well as high power levels. 相似文献
39.
Relationships between an assembler and a vendor in a supply chain are investigated in two-period models when the assembler wants to reduce response time by incentive systems. The assembler may offer myopic or farsighted incentive contracts to the vendor, under short-term or long-term relationships. Incentive schemes, effort levels, and expected payoffs under different perspectives and relationships are examined. We find that a farsighted assembler provides the vendor with a higher incentive than a myopic assembler in the first period. A long (short)-term relationship is preferred if the value of farsightedness under a long-term relationship is greater (less) than the switching option value under a short-term relationship. We propose several sufficient conditions regarding which perspectives and relationships are preferred. 相似文献
40.
We investigated dielectric properties of a hockey-stick-shaped liquid crystal (HLC). Two dielectric relaxation modes were observed at 0.91 kHz and 4.51 MHz. The low frequency relaxation modes in isotropic, smectic, and nematic phases are related to the motion of ions, collective tilt fluctuation, and rotation around the long molecular axis, respectively. Meanwhile, the high frequency relaxation modes in nematic and smectic phases was due to the rotation around the short axis of the molecules and hindered by the resistance of the ITO layers. We also examined the electrooptical response of the 5.0 wt% HLC-doped commercial nematic liquid crystal (LC) mixtures. The birefringence of the LC mixture was slightly increased, while the falling time and the rotational viscosity was decreased in the nematic phase. 相似文献