正交投影用于红外光谱图中光谱提取及背景扣除

利用正交投影方法以及原始信号及其投影与背景矢量之间的线性关系,确定背景光谱,从而将待测组分的红外光谱从混合物光谱中提取出来,达到扣除背景及分辨重叠光谱之目的。本方法用于二氯乙烷及丙酮中各组分红外光谱的提取,获得了满意的结果。     

Measurement of lateral and axial resolution of confocal Raman microscope using dispersed carbon nanotubes and suspended graphene

A confocal Raman microscope (CRM) facilitates visualization of the spatial distribution of molecular bonds or phonon modes at the submicron level and has been extensively used in the characterization of nanomaterials and devices. The lateral and axial resolution is a key specification that defines the performance of CRM, however, the interpretation of spatial resolution in the literature is often ambiguous, making it often difficult to directly compare Raman images obtained under different conditions. In this report, a convenient and reliable measurement protocol using dispersed carbon nanotubes and suspended graphene as test specimens is proposed to facilitate the determination of the lateral and axial resolutions of a CRM. Spatial resolution values comparable to the results based on Rayleigh criterion calculations were obtained using Raman mapping images of test specimens. This was achieved without the need for complex deconvolution processes or the consideration of an asymmetric dielectric environment.     

微通道板近紫外量子效率测量及成像研究

提出了一种通过测量微通道板输出电流及增益来计算光电流,从而测量出微通道板量子效率的方法,并用该方法测量了微通道板在近紫外(200~380nm)的量子效率.测量结果表明,微通道板的量子效率很低,并且随波长增加而快速下降,200nm波长处的量子效率为10-4数量级,320nm波长处的量子效率为10-8数量级,大于340nm波长处的量子效率极低且趋近于零.微通道板及荧光屏组成的成像器件可以对酒精灯火焰成像,但图像较稀疏,而传统Cs2Te光电阴极紫外成像器件的图像却较密实,这与微通道板量子效率低,Cs2Te光电阴极量子效率高的情形一致.在该成像器件的前端放置一片350nm波长的高通滤光片后,所成的酒精灯火焰图像消失.对被照射目标成像时,如果照射光源为254nm的汞灯,则可以成像;但如果照射光源为365nm汞灯,则不能成像.说明微通道板的光谱响应主要在350nm波长以下,与其量子效率的测量结果一致.最后测量得到该成像器件的分辨力为32lp/mm,与传统Cs2Te光电阴极紫外成像器件的分辨力相同.微通道板及荧光屏组成的成像器件由于不使用光电阴极,具有价格低、寿命长且可靠性高的优点,因此可在紫外信号较强或成像距离较短的条件下使用.     

超二代及三代像增强器不同响应波段的参数测量及比较

对A光源分别进行550 nm、625 nm以及675 nm的短波截止,对比测量了超二代和三代像增强器的光谱响应、阴极灵敏度、增益、分辨力以及信噪比.在10-1 lx照度条件下,当对A光源进行675 nm的短波截止之后,三代像增强器的分辨力未出现下降,而超二代像增强器的分辨力却下降到初始值的94％;但在10-4 lx照度...     

Dynamic Stereochemistry of M8Pd6 Supramolecular Cages Based on Metal-Center Lability for Differential Chiral Induction,Resolution, and Recognition

A series of isostructural supramolecular cages with a rhombic dodecahedron shape have been assembled with distinct metal-coordination lability (M₈Pd₆-MOC-16, M=Ru²⁺, Fe²⁺, Ni²⁺, Zn²⁺). The chirality transfer between metal centers generally imposes homochirality on individual cages to enable solvent-dependent spontaneous resolution of Δ₈/Λ₈−M₈Pd₆ enantiomers; however, their distinguishable stereochemical dynamics manifests differential chiral phenomena governed by the cage stability following the order Ru₈Pd₆ > Ni₈Pd₆ > Fe₈Pd₆ > Zn₈Pd₆. The highly labile Zn centers endow the Zn₈Pd₆ cage with conformational flexibility and deformation, enabling intrigue chiral-Δ₈/Λ₈−Zn₈Pd₆ to meso-Δ₄Λ₄−Zn₈Pd₆ transition induced by anions. The cage stabilization effect differs from inert Ru²⁺, metastable Fe²⁺/Ni²⁺, and labile Zn²⁺, resulting in different chiral-guest induction. Strikingly, solvent-mediated host–guest interactions have been revealed for Δ₈/Λ₈−(Ru/Ni/Fe)₈Pd₆ cages to discriminate the chiral recognition of the guests with opposite chirality. These results demonstrate a versatile procedure to control the stereochemistry of metal-organic cages based on the dynamic metal centers, thus providing guidance to maneuver cage chirality at a supramolecular level by virtue of the solvent, anion, and guest to benefit practical applications.     

A NOTE ON 2_(IV)~(m-p) DESIGNS WITH THE MAXIMUM NUMBER OF CLEAR TWO-FACTOR INTERACTIONS

In this article, the authors obtain some theoretical results for 2_(IV)~(m-p) designs to have the maximum number of clear two-factor interactions by considering the number of two-factor interactions that are not clear. Several 2_(IV)~(m-p) designs with the maximum number of clear two-factor interactions, judged using these results, are provided for illustration.     

苏制дФC－8－3型摄谱仪功能的扩展与应用

本文叙述了前苏联制造的摄谱仪和单色仪的特点，对苏制摄谱仪进行了改装，使其既是摄谱仪，又具有单色仪的功能。经过多次实验，使用效果较好。     

Every place admits local uniformization in a finite extension of the function field

We prove that every place P of an algebraic function field F|K of arbitrary characteristic admits local uniformization in a finite extension F of F. We show that F|F can be chosen to be Galois, after a finite purely inseparable extension of the ground field K. Instead of being Galois, the extension can also be chosen such that the induced extension FP|FP of the residue fields is purely inseparable and the value group of F only gets divided by the residue characteristic. If F lies in the completion of an Abhyankar place, then no extension of F is needed. Our proofs are based solely on valuation theoretical theorems, which are of particular importance in positive characteristic. They are also applicable when working over a subring R⊂K and yield similar results if R is regular and of dimension smaller than 3.     

提高微细图形光刻分辨力的相移滤波技术研究

详细研究了提高投影成像光刻分辨力的相移滤波技术的基本理论,给出了理论模型,进行了模拟计算.对不同掩模图形设计制作的不同优化滤波器进行光刻对比实验并取得实验结果.研究表明,相移滤波能显著提高部分相干成像系统光刻分辨力和增大焦深,同时能提高光能利用率,有利于提高光刻生产率,是一种有效提高光刻分辨力和焦深的波前工程技术.