全文获取类型
收费全文 | 3009篇 |
免费 | 244篇 |
国内免费 | 742篇 |
专业分类
化学 | 2419篇 |
晶体学 | 13篇 |
力学 | 261篇 |
综合类 | 22篇 |
数学 | 283篇 |
物理学 | 997篇 |
出版年
2024年 | 29篇 |
2023年 | 355篇 |
2022年 | 97篇 |
2021年 | 106篇 |
2020年 | 92篇 |
2019年 | 97篇 |
2018年 | 92篇 |
2017年 | 86篇 |
2016年 | 116篇 |
2015年 | 89篇 |
2014年 | 116篇 |
2013年 | 212篇 |
2012年 | 124篇 |
2011年 | 160篇 |
2010年 | 111篇 |
2009年 | 165篇 |
2008年 | 168篇 |
2007年 | 176篇 |
2006年 | 169篇 |
2005年 | 165篇 |
2004年 | 152篇 |
2003年 | 99篇 |
2002年 | 106篇 |
2001年 | 70篇 |
2000年 | 72篇 |
1999年 | 81篇 |
1998年 | 78篇 |
1997年 | 84篇 |
1996年 | 68篇 |
1995年 | 61篇 |
1994年 | 48篇 |
1993年 | 42篇 |
1992年 | 29篇 |
1991年 | 28篇 |
1990年 | 28篇 |
1989年 | 20篇 |
1988年 | 26篇 |
1987年 | 11篇 |
1986年 | 18篇 |
1985年 | 20篇 |
1984年 | 13篇 |
1983年 | 6篇 |
1982年 | 14篇 |
1981年 | 20篇 |
1980年 | 9篇 |
1977年 | 9篇 |
1976年 | 12篇 |
1975年 | 7篇 |
1973年 | 9篇 |
1972年 | 5篇 |
排序方式: 共有3995条查询结果,搜索用时 15 毫秒
31.
This paper introduces a mathematical model which makes it possible both to determine the concentration of photosynthetic herbicides and to obtain a quantitative parameter in order to compare their activity using a previously described sensing system. The working principle involves the changes in absorption properties at 860 nm of the reaction centre (RC) isolated from the bacteria Rhodobacter sphaeroides when photosynthetic herbicides are present. The method has been used for the determination and activity comparison of five photosynthetic herbicides: diuron, atrazine, terbutryn, terbuthylazine and simazine. Detection limits obtained were 2.2, 0.75, 0.046, 0.25, and 1.4 μM, respectively. The resulting order for the different herbicides according to their action on RC was: terbutryn > terbuthylazine > atrazine > simazine > diuron. 相似文献
32.
《Journal of organometallic chemistry》1995,500(1-2):283-288
Reactions of -, β- and γ-hydrogen elimination in cyclopentadienylnickel compounds formed in the reactions of nickelocene with lithium or magnesium compounds are discussed. Elimination of -hydrogen from CpNiR where R is CH3, CH2C(CH3)3, CH2Si(CH3)3, CH2Ph or CH=C(CH3)2 leads to the formation of trinickel clusters (CpNi)3CR′, bis(cyclopentadienyl)(μ-cyclopentadiene)dinickel and (η5-cyclopentadienyl)(η3-cyclopenteny)nickel. β-hydrogen and γ-hydrogen elimination in vinylnickel compounds not possesing -hydrogen have been studied. Elimination and transfer of hydrogen forms (η3-allyl)(η5-cyclopentadienyl)nickel compounds. The mechanisms of these reactions are discussed. 相似文献
33.
Rh上乙醇的生成机理,目前主要有两类.一是Ichikawa等为代表提出的“CO解离—CH_x(x=2或3)—乙酰基—乙醇”机理;另一是蔡启瑞等的“CO缔合—甲酰基(金属氧卡宾)—卡宾—乙烯酮—乙酰基—乙醇”机理.本文用Shustorovich的键级守恒—Morse势(BOC-MP)法对其进行了研究 相似文献
34.
一代树状碳硅烷液晶的光化学研究--端基含12个4-丁氧基氮苯介晶基元 总被引:2,自引:0,他引:2
研究了新的含12个丁氧基偶氮苯介晶基元的五代树状碳硅烷液晶D1及偶氮苯介 晶基元化合物M5在氯仿、四氢呋喃、N,N-二甲基甲酰胺、乙醇和苯等溶剂中的量 子产率、反-顺光异构化、光回复异构、反/顺异构组分比、热回复异构及活化能 。D1和M5的光致变色速率常数为10~(-1)s~(-1),而含同一偶氮基元的光致变色液 晶聚硅氧烷的光致变色速率常数为10~(-8)s~(-1),因此,液晶树状物D1的光响应 速度比后者快10~7倍。 相似文献
35.
Luis A.?León Rafael?Notario Jairo?QuijanoEmail author Ederley?Vélez Claudia?Sánchez J. Camilo?Quijano Nouria?Al-Awadi 《Theoretical chemistry accounts》2003,110(6):387-394
Theoretical studies on the thermolysis in the gas phase of 4-arylideneimino-1,2,4-triazol-3(2H)-ones and 4-arylideneimino-1,2,4-triazol-3(2H)-thiones were carried out using density functional theory methods, at the B3LYP/6-31G(d) and B3LYP/6-311+G(2d,p) levels of theory. The proposed reaction mechanism occurs in one step, leading to the formation of 3-hydroxy-(2H)-1,2,4-triazole or 3-mercapto-(2H)-1,2,4-triazole and a 4-substituted benzonitrile, via a six-membered cyclic transition state. The progress of the reactions was followed by means of the Wiberg bond indices. The results indicate that the transition states have character intermediate between reactants and products, and the calculated synchronicities show that the reactions are slightly asynchronous, in the case of triazolones, and show a higher asynchronicity in the case of triazolthiones. The bond-breaking processes are slightly more advanced than the bond-forming ones, indicating a small bond deficiency in the transition states. Kinetic and activation parameters for the reactions studied have been calculated and compared with available experimental data.From the Proceedings of the 28th Congreso deQuímicos Teóricos de Expresión Latina (QUITEL 2002) 相似文献
36.
Ivar Ugi Johannes Bauer Klemens Bley Alf Dengler Andreas Dietz Eric Fontain Bernhard Gruber Rainer Herges Michael Knauer Klaus Reitsam Natalie Stein 《Angewandte Chemie (International ed. in English)》1993,32(2):201-227
The topic of this article is the development and the present state of the art of computer chemistry, the computer-assisted solution of chemical problems. Initially the problems in computer chemistry were confined to structure elucidation on the basis of spectroscopic data, then programs for synthesis design based on libraries of reaction data for relatively narrow classes of target compounds were developed, and now computer programs for the solution of a great variety of chemical problems are available or are under development. Previously it was an achievement when any solution of a chemical problem could be generated by computer assistance. Today, the main task is the efficient, transparent, and non-arbitrary selection of meaningful results from the immense set of potential solutions—that also may contain innovative proposals. Chemistry has two aspects, constitutional chemistry and stereochemistry, which are interrelated, but still require different approaches. As a result, about twenty years ago, an algebraic model of the logical structure of chemistry was presented that consisted of two parts: the constitution-oriented algebra of be- and r-matrices, and the theory of the stereochemistry of the chemical identity group. New chemical definitions, concepts, and perspectives are characteristic of this logic-oriented model, as well as the direct mathematical representation of chemical processes. This model enables the implementation of formal reaction generators that can produce conceivable solutions to chemical problems—including unprecedented solutions—without detailed empirical chemical information. New formal selection procedures for computer-generated chemical information are also possible through the above model. It is expedient to combine these with interactive methods of selection. In this review, the Munich project is presented and discussed in detail. It encompasses the further development and implementation of the mathematical model of the logical structure of chemistry as well as the experimental verification of the computer-generated results. The article concludes with a review of new reactions, reagents, and reaction mechanisms that have been found with the PC-programs IGOR and RAIN. 相似文献
37.
Bifurcations of reaction channels are related to valley-ridge inflection points and it is examined what happens when these do not coincide with transition states. Under such conditions there result bifurcating regions. There exist a number of different prototypes for such regions which are discussed explicitly on the basis of the pertinent Taylor expansions. When bifurcations occur close enough to transition states then there result bifurcating transition regions. An example for a bifurcating transition region is exhibited which is obtained from a quantum mechanical ab initio calculation for the ring opening of cyclopropylidene to aliene. In general there exist no orthogonal trajectory patterns which could serve as simplified models for channel bifurcations.Operated for the U.S. Department of Energy by Iowa State University under Contract No. W-7405-ENG-82. This work was supported by the Office of Basic Energy Sciences 相似文献
38.
动力学体系二维数据的秩分析及其应用 总被引:2,自引:0,他引:2
详细论证了动力学体系中存在的多种共线性情况,以及在此情况下二维数据阵的秩与独立反应数及组分数的关系.分析了通过增秩这一方式来判断体系组分数的条件.讨论了反应间存在物质交换对数据阵秩的影响.建立起一套通过秩分析判断未知动力学体系中存在的反应组分数、独立反应数以及可能反应机理的方法.将秩分析技术应用到聚苯胺与质子酸反应,初步分析了该体系存在的多种吸光性结构及结构变化.确定了[H+]=0.01~0.1 mol•L-1范围内,聚苯胺与质子酸反应存在一个三结构两步互变过程. 相似文献
39.
40.