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151.
A flexible approach to ethyl (3R,4S)-N-Boc-4-amino-3-hydroxy-5-phenylpentanoate (N-Boc-AHPPA-OEt), the γ-amino-β-hydroxy acid moiety of hapalosin is described. The synthetic method features a ring-opening ethanolysis of an activated N-Boc-lactam, which is obtained via a diastereoselective reductive-alkylation of (R)-malimide derivative. The flexibility of the method resides in the introduction of the alkyl side chain by Grignard reagent addition. 相似文献
152.
Changes of the rheological properties of hyaluronic acid (sodium-magnesium salt) solutions after exposure to UV radiation
indicate a vigorous decrease in their viscosity, but its still strong shear rate dependence. Whereas the presence of the singlet
oxygen sensitizer (anthracene-1-sulphonic acid) brings about a loss of shear dependence; the studied solutions show newtonian
behavior. 相似文献
153.
Shyan-Ming Yuan 《BIT Numerical Mathematics》1991,31(1):53-68
To maintain consistency on a distributed database system, a commit protocol is often employed to ensure that either all the sub-transactions of a transaction commit or all abort. Special care needs to be taken to ensure the correct functioning of a commit protocol in the face of node failures during the execution of the protocol. A protocol is said to be fault-tolerant if it properly commits or aborts, even if nodes fail.In this paper, we present a fault tolerant decentralized commit protocol which is message optimal in the absence of failures. Furthermore, the protocol (FTDCP) ensures that all sites can achieve a consistent final decision by at most 4 extra messages in the single site failure situation. 相似文献
154.
Ch. Ohn 《Letters in Mathematical Physics》1992,25(2):85-88
We obtain Zakrzewski's deformation of Fun SL(2) through the construction of a *-product on SL(2). We then give the deformation of
dual to this, as well as a Poincaré basis for both algebras.Aspirant au Fonds National belge de la Recherche Scientifique. Partially supported by EEC contract SC1-0105-C. 相似文献
155.
M. Scheunert 《Letters in Mathematical Physics》1992,24(3):173-181
It is pointed out that, for m, n 2, the naive Serre presentation corresponding to the simplest Cartan matrix of sl(m, n) does not define the Lie superalgebra sl(m, n) but a larger algebra s(m, n) of which sl(m, n) is a nontrivial quotient. The supplementary relations for the generators are found and the definition of the q-deformed universal enveloping algebra of sl(m, n) is modified accordingly. 相似文献
156.
M. D. Gould 《Letters in Mathematical Physics》1992,24(3):183-196
It is shown that the braid generator is diagonalizable on arbitrary tensor product modules V V, V an irreducible module for a quantum group. A generalization of the Reshetikhin form for the braid generator is thereby obtained in the general case. As an application, a general closed formula is determined for link polynomials. 相似文献
157.
M. Pollnau E. Heumann G. Huber 《Applied Physics A: Materials Science & Processing》1992,54(5):404-410
A pump- and probe-beam technique is used for measuring time-resolved excited-state absorption (ESA) and stimulated-emission (SE) spectra of Er3+ doped YAlO3. The Er3+
4
I
15/2 4
F
7/2 transition of the sample is excited at 488 nm by an excimer laser pumped dye laser. The ESA and SE of broadband xenon flashlamp light is monitored between 300 and 860 nm by an optical multichannel analyzer (OMA). The analysis of the experimental results provides information on the effective cross sections ESA and SE originating from several levels and on the populations of these levels. To our knowledge this represents the first detailed investigation of time-resolved ESA and SE over a broad spectral range in rare-earth doped materials. 相似文献
158.
We expose and discussPenrose's thesis: Nature produces harnessable noncomputable processes, but none at the classical level. We then suggest a partial counterexample to it, based on aGedanken experiment about an undecidable family of integrable Hamiltonian systems that could lead to a sort of idealized solution to the Halting problem for Turing machines.1. Partially supported by a Fulbright/CNPq-Brazil grant. Permanent address after November 5, 1990: Center for the Study of Mathematical Theories of Communication, IDEA/School of Communications, Federal University of Rio de Janeiro, Av. Pasteur 250, 22290 Rio de Janeiro, RJ Brazil. 相似文献
159.
Tao Tang 《Numerische Mathematik》1992,61(1):373-382
Summary We discuss the application of a class of spline collocation methods to first-order Volterra integro-differential equations (VIDEs) which contain a weakly singular kernel (t–s)– with 0<<1. It will be shown that superconvergence properties may be obtained by using appropriate collocation parameters and graded meshes. The grading exponents of graded meshes used are not greater thanm (the polynomial degree) which is independent of . This is in contrast to the theories of spline collocation methods for Volterra (or Fredholm) integral equation of the second kind. Numerical examples are given to illustrate the theoretical results. 相似文献
160.
Narotham V. Maddireddy Himanshu M. Godbole Girij P. Singh Suvarna G. Kini Gautham G. Shenoy 《合成通讯》2020,50(18):2810-2818
AbstractAn efficient asymmetric oxidation of sulfides was achieved using (R)-6,6'-dibromo-BINOL as chiral ligand in combination with Ti(OiPr)4 using 70% aqueous tertiary butyl hydroperoxide as oxidant. The resulting sulfoxides had high enantiopurities and good yields. A range of aryl alkyl and aryl benzyl sulfides were oxidized to the corresponding sulfoxides with 78–95% ee in 72–80% yields. 相似文献