全文获取类型
收费全文 | 21131篇 |
免费 | 1274篇 |
国内免费 | 1170篇 |
专业分类
化学 | 19335篇 |
晶体学 | 33篇 |
力学 | 638篇 |
综合类 | 72篇 |
数学 | 334篇 |
物理学 | 3163篇 |
出版年
2024年 | 51篇 |
2023年 | 284篇 |
2022年 | 597篇 |
2021年 | 461篇 |
2020年 | 661篇 |
2019年 | 633篇 |
2018年 | 592篇 |
2017年 | 761篇 |
2016年 | 939篇 |
2015年 | 880篇 |
2014年 | 860篇 |
2013年 | 1306篇 |
2012年 | 1380篇 |
2011年 | 1336篇 |
2010年 | 1042篇 |
2009年 | 1295篇 |
2008年 | 1142篇 |
2007年 | 1360篇 |
2006年 | 1094篇 |
2005年 | 1011篇 |
2004年 | 919篇 |
2003年 | 796篇 |
2002年 | 601篇 |
2001年 | 407篇 |
2000年 | 372篇 |
1999年 | 360篇 |
1998年 | 318篇 |
1997年 | 268篇 |
1996年 | 282篇 |
1995年 | 258篇 |
1994年 | 226篇 |
1993年 | 184篇 |
1992年 | 164篇 |
1991年 | 199篇 |
1990年 | 112篇 |
1989年 | 87篇 |
1988年 | 64篇 |
1987年 | 48篇 |
1986年 | 38篇 |
1985年 | 36篇 |
1984年 | 28篇 |
1983年 | 20篇 |
1982年 | 26篇 |
1981年 | 18篇 |
1980年 | 11篇 |
1979年 | 13篇 |
1978年 | 8篇 |
1976年 | 8篇 |
1973年 | 5篇 |
1959年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
91.
建立了散射背景下测定人体血清中Zn^2+含量的激光热透镜光谱分析方法。比较了蛋白质微粒散射对于分光光度法和激光热透镜光谱分析法测定的影响。结果表明,激光热透镜光谱分析方法能够避免溶液中存留蛋白质微粒散射的影响。Zn^2+量在0~1.6μg/mL范围内呈线性关系(r=0.9986),检出限为1ng/mL。应用于人体血清中Zn^2+含量的测定,与原子吸收法测定结果基本一致。 相似文献
92.
Multielemental characterisation of cobalt by glow discharge quadrupole mass spectrometry 总被引:5,自引:0,他引:5
Multielemental determination and the assessment of purity of cobalt metal used in the preparation of Ni-based super-alloys have been carried out by glow discharge quadrupole mass spectrometry (GD-QMS). Relative sensitivity factors (RSF) generated from certified iron matrix reference samples (NIST 663 and 664 low alloy steel pin standards) could be used for the determination of different trace element constituents of the sample. Different wet chemical procedures were also carried out for the determination of the trace constituents in the sample. The GD-QMS results are in reasonably good agreement with those obtained from wet chemical procedures, validating the use of the RSF values generated on low alloy steel standards for the computation of trace element concentrations in cobalt metal. A variety of molecular ions formed through the reaction of cobalt (matrix) with the discharge gas (argon) were also detected. 相似文献
93.
94.
The precision of isotopic measurements of Pb by thermal ionization mass spectrometry (TIMS) is limited by the fact that this element does not possess an invariant isotope ratio that can be used for the correction of mass fractionation by internal normalization. Multiple-collector inductively coupled plasma mass spectrometry (MC-ICPMS) can overcome this limitation, because with plasma ionization, elements with overlapping mass ranges are thought to display identical mass discrimination. With respect to Pb, this can be exploited by the addition of Tl to the sample solutions; the mass discrimination factor obtained for Tl can then be used for the correction of the measured Pb isotope ratios. In this article we present the results of a detailed study that investigates the accuracy and precision of such an external correction technique for mass discrimination based upon the results of multiple analyses of a mixed standard solution of NIST SRM-981 Pb and SRM-997 Tl. Our data indicate that normalization of the Pb isotope ratios to the certified isotopic composition of SRM-997 Tl produces Pb isotopic results that are significantly lower than recently published reference values by TIMS. This systematic offset can be eliminated by renormalization of the Pb data to a different Tl isotopic composition to obtain an empirically determined mass discrimination factor for Pb that generates accurate results. It is furthermore shown that a linear law is least suited for the correction of mass discrimination, whereas a power or exponential law function provide significantly more accurate and precise results. In detail, it appears that a power law may provide the most appropriate correction procedure, because the corrected Pb isotope ratios display less residual correlations with mass discrimination compared to the exponentially corrected data. Using an exponential or power law correction our results, obtained over a period of over seven months, display a precision (2σ) of better than 60 parts per million (ppm) for 208Pb/206Pb and 207Pb/206Pb and of better than 350 ppm for 206Pb/204Pb, 207Pb/204Pb/204Pb, and 208Pb/204Pb. This represents a significant improvement compared to conventional TIMS techniques and demonstrates the potential of MC-ICPMS for routine, high-precision measurements of Pb isotopic compositions. 相似文献
95.
96.
Jürgen Grotemeyer Edward W. Schlag 《Angewandte Chemie (International ed. in English)》1988,27(4):447-459
Mass spectrometry is one of the most important analytical tools in chemistry, biology, medicine and related areas. During the past 30 years, methods have been developed, both for the qualitative as well as the quantitative analysis of a wide variety of substances. The introduction of lasers into chemistry has also profited mass spectrometry, since its nonlinear properties and its tunability open up fundamentally new frontiers. Multiphoton ionization mass spectrometry combines UV-spectroscopy and mass spectrometry, thus providing a two-dimensional method that enables substance-specific and even state-specific analyses. This progress report presents the fundamentals and possibilities of MUPI mass spectrometry and discusses investigations on amino acids, peptides, chlorophylls and sugars. For each substance, multiphoton ionization can be tuned in such a way that only the molecular ion is formed. An increase of laser intensity induces substance-specific fragmentations of the molecule, thus contributing to a quick and easy identification of the substance. 相似文献
97.
98.
Vora A. Riga A. Dollimore D Alexander K. 《Journal of Thermal Analysis and Calorimetry》2004,75(3):709-717
This study attempts to identify the degradative process which folic acid undergoes in the solid-state under thermal stress.
In order to facilitate the process, the various pieces of the chemical structure, namely, p-amino benzoic acid, pterin and glutamic acid as both its d- and l-isomers were investigated as separate entities. These structured solid-state pieces were then compared to the composite solid
state folic acid degradative curves in order to identify the peaks seen and provide direction for the interpolation of the
degradative mechanism. It was observed that none of the structural pieces could be superimposed as assumed earlier and hence
an attempt was made to identify the decomposition products using various analytical techniques such as infrared spectroscopy,
mass spectroscopy and X-ray diffraction which suggested that the glutamic acid fragment is lost first as evidenced by acid
loss and amide enhancement in the IR spectra. The vitamin was ultimately degrading to carbon fragments and that further identification
was not necessary.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
99.
100.
Angelica pubescens and Angelica sinensis belong to the Umbelliferae family and both are used as traditional Chinese medicines. In the present study, headspace solid-phase microextraction (HS-SPME) with gas chromatography-mass spectrometry (GC-MS) was used for the analysis of the volatile constituents present in their roots. Eighty-seven compounds in Angelica pubescens and thirty-six compounds in Angelica sinensis were identified by GC-MS. Their relative contents were calculated by the peak area ratio. HS-SPME was compared to steam distillation (SD) by analyzing the volatile constituents of Angelica sinensis root. A good agreement between results obtained with both techniques was found. As a conclusion, HS-SPME is a powerful tool for determining the volatile constituents present in the TCMs. 相似文献