全文获取类型
收费全文 | 12306篇 |
免费 | 1655篇 |
国内免费 | 1756篇 |
专业分类
化学 | 11590篇 |
晶体学 | 88篇 |
力学 | 89篇 |
综合类 | 97篇 |
数学 | 16篇 |
物理学 | 3837篇 |
出版年
2024年 | 38篇 |
2023年 | 133篇 |
2022年 | 466篇 |
2021年 | 486篇 |
2020年 | 516篇 |
2019年 | 563篇 |
2018年 | 416篇 |
2017年 | 496篇 |
2016年 | 624篇 |
2015年 | 622篇 |
2014年 | 667篇 |
2013年 | 1093篇 |
2012年 | 879篇 |
2011年 | 736篇 |
2010年 | 709篇 |
2009年 | 774篇 |
2008年 | 769篇 |
2007年 | 827篇 |
2006年 | 775篇 |
2005年 | 650篇 |
2004年 | 587篇 |
2003年 | 469篇 |
2002年 | 366篇 |
2001年 | 234篇 |
2000年 | 291篇 |
1999年 | 205篇 |
1998年 | 197篇 |
1997年 | 196篇 |
1996年 | 152篇 |
1995年 | 159篇 |
1994年 | 118篇 |
1993年 | 117篇 |
1992年 | 94篇 |
1991年 | 78篇 |
1990年 | 47篇 |
1989年 | 34篇 |
1988年 | 39篇 |
1987年 | 31篇 |
1986年 | 12篇 |
1985年 | 12篇 |
1984年 | 6篇 |
1983年 | 5篇 |
1982年 | 8篇 |
1981年 | 5篇 |
1980年 | 4篇 |
1979年 | 5篇 |
1978年 | 2篇 |
1977年 | 2篇 |
1973年 | 1篇 |
1971年 | 1篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
71.
Alignment of photon-induced L3 vacancies is studied in rare earth and highZ elements at energies of experimental interest, near thresholds to 60 keV, under nonrelativistic dipole approximation. Numerical
calculations of the matrix element are undertaken to produce theoretical data for comparison with the experimental findings.
The A2 values being s>0.1 at photoelectron energies <20 keV are certainly higher than 5–8% uncertainties quoted in experimental
results. Present findings are from a very basic model, hydrogen-like and can further be treated as reference to observe the
impact of screening, relativistic, multipole and retardation corrections to the model 相似文献
72.
73.
Yoshio Umezawa 《化学:亚洲杂志》2006,1(3):304-312
Lately, scientists have explored approaches to developing fluorescent and/or bioluminescent indicators to pinpoint cellular processes in single living cells. These analytical methods have become a key technology for visualizing and detecting what was otherwise unseen in live cells. The target signaling included second messengers, protein phosphorylations, protein–protein interactions, and protein localizations. 相似文献
74.
J. P. S. Farinha J. M. G. Martinho H. Xu M. A. Winnik R. P. Quirk 《Journal of Polymer Science.Polymer Physics》1994,32(9):1635-1642
Cyclization of a polystyrene chain (Mn = 10,600; Mw/Mn = 1.09) both ends labeled with 4-(1-pyrenyl)butanoamide groups was studied in cyclohexane between 25 and 95°C. The amide groups (peptide bonds) at both ends can form an intrachain hydrogen bond between the amide hydrogen at one chain end and the carbonyl oxygen at the other. The presence of two sets of conformers, random coils, and chains cyclized through hydrogen bonding, complicates the data analysis. The pyrene excimer kinetics of this polymer is well described by a model composed of two monomers (hydrogen bonded and nonbonded chains) and one excimer, in equilibrium. The cyclization rate constant for hydrogen-bonded chains is larger than the one for nonhydrogen-bonded chains. The pyrene excimer binding energy (ca. 1.6 kcal/mol) is lower than the published value for nonhydrogen-bonded chains (~ 9 kcal/mol), suggesting that intrachain hydrogen bonding hinders the stabilization of the excimer. © 1994 John Wiley & Sons, Inc. 相似文献
75.
Ildikó Mohammed-Ziegler Ferenc Billes 《Journal of inclusion phenomena and macrocyclic chemistry》2007,58(1-2):19-42
This review summarizes different applications of optical spectroscopic methods in calixarene chemistry including UV/Vis spectrometry,
vibrational spectroscopic techniques (FTIR and Raman spectroscopy), luminescence spectroscopy (including fluorescence and
phosphorescence), ellipsometry and various optical microscopic methods. Moreover, the results of theoretical studies (AM1,
PM3, DFT, ab initio, etc.) are summarized based on selected papers in the field of conformational studies, thermodynamics and complexation features.
About 300 references are processed systematically from the results reported mainly in the recent years with emphasis on the
potential of practical application of these molecules. 相似文献
76.
芳环羟基化HPLC分离荧光法检测Cu(Ⅱ)-H2O2体系中产生的·OH 总被引:4,自引:3,他引:1
采用L-苯丙氨酸为探针,使用液相色谱分离荧光检测(FLD)和荧光分光光度分析(FS)两种方法平行检测Cu(Ⅱ)-H2O2 体系中产生的·OH.试验采用的激发波长277 nm,发射波长306 nm.体系在反应前后的荧光变化,可反映·OH产生量.对FLD与FS所得数据进行了比较分析,结果显示两种方法具有较高一致性.FS使用混合体系检测,易对荧光的产生造成干扰,而FLD法没有干扰. 相似文献
77.
秦运文 《核聚变与等离子体物理》2003,23(2):84-88
托卡马克磁探针阵列通常是围绕等离子体均匀布置的完整环形系统。由于受到布置空间的限制,HL-2A装置的磁探针只能组成带空白区域的间断阵列。在分析了HL-lM极向磁场振荡——Mirnov振荡模式的基础上,探索了HL-2A磁探针阵列诊断应注意的问题。 相似文献
78.
79.
Theoretical models for Monte Carlo simulation of radiative processes, i.e. bremsstrahlung and characteristic x-ray emission, are presented. Possible strategies for simulating electron transport are briefly described. For mechanisms involving energy loss and angular deflections, difficulties for strict implementation of accurate numerical differential cross sections still remain due to the strong correlations between these variables. Practical solutions for the case of inelastic collisions and bremsstrahlung emission are described. Comparisons of simulation results with experimental data for several problems of interest in electron probe microanalysis are presented. 相似文献
80.
DING Xuantong YANG Qingwei YAN Long wen LIU Yi HUANG Yuan LIU Zetian HONG Wenyu SHI Peilan 《核工业西南物理研究院年报(英文版)》2004,(1):1-4
The main mission the HL-2A tokamak is of the experiments on to explore the divertor physics and to investigate the plasma confinement, transport and instabilities with high power auxiliary heating and advanced fuelling, it is necessary to develop more new diagnostics and increase the spatial and temporal resolutions of the measurements for exist system. Up to now, about 30 diagnostic systems have been moved from HL-1M to HL-2A tokamak. Other 10 diagnostic systems are being designed and installed on the device. In developed in last 2 years, will be presented. 相似文献