塞曼石墨炉原子吸收法测定水产品中的铬

研究了石墨炉原子吸收法测定的方法 ,对多种方法比较研究得出 ,样品经过干法灰化 ,以硝酸溶解未消解完全的样品 ,用硝酸镁作基体改进剂 ,利用塞曼扣背景技术 ,热解平台石墨管进行测定 ,线性范围为2 .5— 5 0 μg·L-1,回收率为 90 %— 10 3% ,相对标准偏差为 6 .8%。     

NEW AND CONVENIENT SYNTHESIS OF (R) AND (S) OF 2-METHYL-3-OXA-5-(TERT-BUTYLDIPHENYLSILYLOXYL) METHYLPENTANOATE AND 2-METHYL-3-OXA-5- (TERT-BUTYLDIMETHYLSILYLOXYL)METHYLPENTANOATE

Abstract

(R) and (S) of 2-Methy1-3-oxa-5-(tert-butyldiphenylsilyloxyl)methy1pentanoate (4a. 6a) and (R) and (S) of 2-methy1-3-oxa-5-(tert-butyldimethylsilyloxyl)methylpentanoate (4b, 6b) were synthesized by the reaction of the preparative compounds (2a, 2b) with (R) and (S) methy1lactate (3, 4) in the presence of a silver (1) oxide catalyst (Method B). The title compounds are useful for the synthesis of different natural products such as epothilones.     

Reactions of Trifluoromethylsulfenyl Chloride with 1,5-Cyclooctadiene

The reaction of 1,5-cyclooctadiene with F 3 CSCl at m 80;C has been examined and found to furnish both di- and tetrasubstituted adducts. Their mass spectra show the presence of the intact cyclooctyl ring. However, photolyis of a solution of 1,5-cyclooctadiene and F 3 CSCl in dry pentane yields addition, isomerization and dimerization as well as free radical products. The rationalization of the formation of the above products along with their mass spectral characterization is described in this communication.     

Palladium‐Catalzyed Atroposelective 16‐Membered Macrocyclization: Total Synthesis of Isoplagiochin D†

Isoplagiochin D is a ring‐strained macrocyclic bisbibenzylis, which showed stable axial chirality in one biaryl structure, and semistable axial chirality in the other biaryl moiety. We reported here an unprecedented example for the catalytically asymmetric synthesis of ring‐strained atropisomers via Pd‐catalyzed macrocyclization between benzyl halides and carbenes. This newly developed Pd‐catalyzed asymmetric macrocyclization protocol enabled us a quick synthesis of isoplagiochin D in a highly enantioselective manner.     

List coloring of Cartesian products of graphs

A well-established generalization of graph coloring is the concept of list coloring. In this setting, each vertex v of a graph G is assigned a list L(v) of k colors and the goal is to find a proper coloring c of G with c(v)∈L(v). The smallest integer k for which such a coloring c exists for every choice of lists is called the list chromatic number of G and denoted by χ_l(G).We study list colorings of Cartesian products of graphs. We show that unlike in the case of ordinary colorings, the list chromatic number of the product of two graphs G and H is not bounded by the maximum of χ_l(G) and χ_l(H). On the other hand, we prove that χ_l(G×H)?min{χ_l(G)+col(H),col(G)+χ_l(H)}-1 and construct examples of graphs G and H for which our bound is tight.     

火焰原子吸收光谱法测定铜镍矿浮选产品中铜、镍、镁

研究了用火焰原子吸收光谱法在同一溶液体系中直接快速测定金川铜镍矿浮选产品中铜、镍、镁含量新的新方法。考察了产品中高含量的SiO2对测定镁的干扰情况，并提出了排除这项干扰简便方法，根据各元素的标准溶液系列的测定数据，推算出了铜、镍、镁3元素的线性回归方程及线性相关系数，特征浓度铜为0．40mg.L^-1/1%，镍为0．48mg.L^-1／1％，Mg为0．018mg.L^-1／1％；线性浓度范围铜，镍均为0－10mg.L^-1，镁为0．2－1．2mg.L^-1。相对标准偏差铜为2．5％(n=6)，镍为2．3％（n＝6），镁为2．8％（n=6），加标回收率铜为96．5％－102．5％，镍为98．8％－103．5％，镁为98．2％－102．5％，这种方法操作简便，快速，实用，具有较好的精密度和准确度，实际产品分析结果与外检单位及金川公司测定的结果吻合。     

白金制品的X射线荧光检验

应用含量归一原理，解决样品形状和大小不确定的问题，可用Ｘ射线荧光法直接测定白金制品成色。     

Dehn Twists and Products of Mapping Classes of Riemann Surfaces with One Puncture

Let S be a Riemann surface that contains one puncture x. Let ℐ be the collection of simple closed geodesics on S, and let ℱ denote the set of mapping classes on S isotopic to the identity on S ∪ {x}. Denote by t _c the positive Dehn twist about a curve c ∈ ℐ. In this paper, the author studies the products of forms (t _b ^−m ∘ t _a ⁿ ) ∘ f ^k , where a, b ∈ ℐ and f ∈ ℱ. It is easy to see that if a = b or a, b are boundary components of an x-punctured cylinder on S, then one may find an element f ∈ ℱ such that the sequence (t _b ^−m ∘ t _n ^a ) ∘ f ^k contains infinitely many powers of Dehn twists. The author shows that the converse statement remains true, that is, if the sequence (t _b ^−m ∘ t _a ⁿ ) ∘ f ^k contains infinitely many powers of Dehn twists, then a, b must be the boundary components of an x-punctured cylinder on S and f is a power of the spin map t _b ⁻¹ ∘ t _a .     

随机变量部分和乘积的广义弱不变原理

考虑独立但不同分布的正随机变量序列,建立了关于部分和乘积的弱不变原理的一个普遍性结果,推广和改进了由Matula和Stepien在2009年以及Rempala和Wesolowski在2002年获得的弱不变原理.     

Impact of various stresses on the streaming electrification of transformer oil

In this contribution the influence of various stresses and their combined impact on the electrostatic charging tendency of oil is studied. Various physicochemical properties were measured according to ASTM Standards to detect changes in oil quality. A free radical reagent, 2.2 diphenyl-1-picrylhydrazyl (DPPH), was added to oil before and after the application of stresses to determine free radical concentration. The results obtained show that the application of stresses contributes to an increase in the electrification current. These results also demonstrate that electrification current is affected by the quantity of the free radicals.