Sonochemical construction of hierarchical strontium doped lanthanum trisulfide electrocatalyst: An efficient electrode for highly sensitive detection of ecological pollutant in food and water

Herbicides are used constantly in agriculture to enhance productivity across the globe. This herbicide monitoring requires utmost importance since its high dose leads to ecological imbalance and a negative impact on the environment. Moreover, a quantification of toxic herbicide is one of the important problems in the food analysis. In this work, deals with the development of a simple, and facile one-pot sonochemical synthesis of strontium doped La₂S₃ (Sr@La₂S₃). Morphological and structural characterization confirms the doping of Sr@La₂S₃ to generate a hierarchical layered structure. The electrochemical performance of modified with rotating disk electrode (RDE) using Sr@La₂S₃ composite is high, compared to La₂S₃ and bare electrodes towards the quantitative detection of mesotrione (MTO) in phosphate buffer. Sr@La₂S₃/RDE showed good sensitivity for MTO detection and it exhibit a range of 0.01–307.01 μM and limit of detection of 2.4 nM. Besides, the selectivity of fabricated electrode is high as it can electrochemically reduce MTO particularly, even in the presence of other chemicals, biological molecules and inorganic ions. The repeatability of MTO detection is high even after 30 days with a lower RSD values. Hence, simple fabrication of Sr@La₂S₃/RDE could be a novel electrode for the sensitive, selective, and reproducible determination of herbicides in real-time applications.     

Efficient thiocyanation of phenols and anilines in the CeBr3 / H2O2 system

An efficient electrophilic thiocyanation of phenols and anilines in the CeBr₃ / H₂O₂ system has been developed. The system CeBr₃ / H₂O₂ generates reactive brominating species which would react with NH₄SCN to deliver the active SCN cations in situ. The Br^- anion can be further oxidized to Br⁺, thereby furnishing the catalytic cycle.