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31.
Okan Dereli 《European Polymer Journal》2006,42(2):368-374
The synthesis of polypentenamer by an electrochemically generated metathesis polymerization catalyst from methylene chloride solution of WCl6 was investigated. The active species formed by electroreduction of this salt under controlled potential of +900 mV at a platinum cathode with an aluminum anode were found to catalyze the ring-opening metathesis polymerization (ROMP) of cyclopentene, monocyclic olefin of relatively low strain, in high yield (89%) and at short period (32 min) under mild conditions. The effect of reaction parameters, e.g., olefin/catalyst ratio, reaction time, electrolysis time, catalyst aging, on the polymerization yield have been studied. The resulting polymer has been characterized by 1H and 13C NMR, IR and gel permeation chromatography (GPC) techniques. Analysis of the polypentenamer microstructure by means of 13C NMR spectroscopy indicates that the polymer contains a mainly trans stereoconfiguration of the double bonds (σc = 0.31) and a slightly blocky distribution (rtrc > 1) of cis and trans double bond dyads (rtrc = 1.44). However, this electrochemical system is reluctant to facilitate the competing vinyl type addition polymerization reactions. 相似文献
32.
The bulk polymerization of benzonitrile catalyzed by Co(Ⅱ), Co(Ⅲ) and Fe(Ⅲ) acetylacetonate was studied. The results of kinetics study show that the rate of polymerization was proportional to first power of the concentration of catalyst and second power of the concentration of monomer. 相似文献
33.
Xiong Wen Ye Yu Ping Zhang Ling Bo Qu Li Qun Fan Bo Li 《中国化学快报》2007,18(11):1399-1402
Microwave irradiation was firstly attempted for the preparation of organic-based monoliths of poly(styrene-divinylbenzene- methacrylic acid), which single step in situ polymerization was carried out during 15 min. The colunm permeability, electrophoretic and chromatographac behaviors were comparatively evaluated using pressure-assisted CEC, GEC and low pressure-driven separation modes. The largest theoretical plates for the preparing column could be close to 18,0000 plates/m for thiourea in the mode of p-CEC. It provided a viable alternative to traditional initiation means for the perparation of monolithic capillary columns. 相似文献
34.
35.
本文是含咔唑化合物及其聚合物系列研究的一部分,以对-溴苯酚为原料,经过乙烯基醚化,再同咔唑反应、合成了新的单体,N-(p-乙烯氧基苯基)咔唑(NEOPC),经过元素分析、NMR和IR等对NEOPC进行分析鉴定,研究了它的聚合行为。 相似文献
36.
37.
Yunjie Luo Yingming Yao Jinglei Chen Yong Zhang 《Journal of organometallic chemistry》2003,679(1):125-129
Reactions of [N(C6H3i-Pr2-2,6)(SiMe3)]2LnCl(THF) (Ln=Nd, Yb) with two equivalents of MeLi in a mixture solution of toluene and Et2O gave [N(C6H3i-Pr2-2,6)(SiMe3)]2LnCH3(μ-CH3)Li(THF)3·PhCH3 (Ln=Nd (1), Yb (2)) in good isolated yields as crystalline solids. The single-crystal structural analysis of 2 revealed that the coordination geometry of ytterbium ion is best described as a distorted pseudo-tetrahedron. Both 1 and 2 are active for the polymerization of methyl methacrylate to give syndiotactic-rich and high molecular weight polymers (Mn>104) with relatively narrow molecular weight distributions (Mw/Mn<2). 相似文献
38.
碳五馏分中微量阻聚剂二乙基羟胺的气相色谱测定法 总被引:2,自引:0,他引:2
提出采用HP-l毛细管色谱柱测定碳五馏分中微量阻聚剂二乙基羟胺组分的气相色谱方法。在本文提出的条件下,二乙基羟胺与其他组分分离良好,检出限低于20mg/kg,相对标准偏差为3.86%,结果准确可靠,方法满足控制分析的要求。 相似文献
39.
用直接酯化法合成了聚对苯二甲酸乙二酯(PET)。对缩聚反应温度、真空度及稳定剂等合条件对产物结晶速率的影响进行了研究。以ΔTc=Tc-Tg和ΔTco=Tco-Tg表征样品的结晶速率。结果表明,真空度一定,反应温度高则样品结晶速率慢;温度一定,真空度高样品结晶速率也慢。这两个因素的影响均是不可忽视的。 相似文献
40.
G. G. Wang J. M. Wang W. Q. Mao H. B. Shao J. Q. Zhang C. N. Cao 《Journal of Solid State Electrochemistry》2005,9(7):524-530
LiMn2O4 powder for lithium-ion batteries was prepared by a precipitation method, and the effects of calcination temperature on the physical properties and electrochemical performance of the samples were investigated by various methods. The results of X-ray diffraction (XRD) showed that the lattice parameter (a) and the unit cell volume (v) decrease with the increasing calcination temperature, and the LiMn2O4 sample calcined at 750°C has smaller particle size and higher crystallinity than other samples. The results of the electrochemical experiments showed that the sample calcined at 750°C has larger peak currents, higher initial capacity, and better cycling capability, because of its lower charge-transfer resistance and larger diffusion coefficient of Li+ ions than those of other samples. 相似文献