Picosecond stimulated Raman scattering of BaWO4 crystal

In single-pass configuration, a picosecond pulse laser was used to investigate the stimulated Raman scattering in different BaWO₄ crystals. Using the thresholds for the first Stokes line along the a- and c-axis, the Raman gain coefficients of the BaWO₄ crystals were calculated along their respective direction. The higher Stokes (fourth) and anti-Stokes (third) lines were observed. Compared with other well-known Raman crystals, such as KGd(WO₄)₂ and Ba(NO₃)₂, BaWO₄ has favorable properties for scattering the pump radiation with picosecond pulse duration. The Raman gain coefficients of BaWO₄ are different, but do not vary for different transmission directions, which means that this Raman material can be selected more freely.     

Exact Stationary States of a Two-Dimensional Transport Model

Previous calculations of transport coefficients of particle systems in two or more dimensions have used computer simulations or various approximations, like those implicit in the Boltzmann equation or in the standard probability theory of diffusion. Here an exactly solved model of crystal growth in three dimensions is transformed into a 2D model of steady particle transport. Then the exact, many-body stationary distribution and exact transport coefficients can be found as well as correlation functions. The model is highly asymmetric. In the transverse direction, particles are strongly attracted, so that long transverse rows of particles tend to form at low temperature. Kinks in these rows are rare, so the transverse positions of kinks effectively move continuously on a large distance scale.     

Anisotropic diffusion in a nematic liquid crystal- An electric field PFG NMR approach

The access to self-diffusion coefficients in anisotropic systems such as thermotropic liquid crystals by means of PFG NMR is complicated by strong dipolar interactions. Additionally, problems arise due to the immediate orientation of low-molar-mass nematic liquid crystals in an external field. The director orientation can be changed by the application of an additional electric field. This can be exploited in order to reduce the dipolar interaction to such an extent that the NMR linewidths change from a solid-state to a liquid-like situation enabling PFG NMR experiments.     

X射线荧光分析中谢尔曼方程逆问题的求解（理论影响系数法 …

本文首先在理论分析基础上,建立多元素样品的重量分数Ｃｉ、Ｘ射线荧光相对强度Ｒｉ与基体效应因子Ｆｉ的代数关系。然后,按照此关系导出两种求解谢尔曼方程逆问题的方法,即理论影响系数法和基本参数法。并用这两种方法分析了６个耐热钢标样,主量、常量元素的平均相对分析误差〈０．５％,对低含量轻元素Ｓｉ、Ｐ、Ｓ的分析也取得良好的结果。     

电磁波在左右手介质界面折射与反射特性的研究

研究了电磁波在左右手介质界面折射与反射的特性,给出了折射系数和反射系数,从另外一个方面探讨了最小作用量原理在左手材料中的适用性;从电动力学和最小作用量原理证明了Snell定律,验证了Snell定律在左手材料中的适用性,并且得到Fresnell公式在左右手材料中的一致性.     

High-temperature electrical properties of magnesiowustite Mg1 − xFexO and spinel Fe3 − x − yMgxCryO4 ceramics

Phase relationships, thermal expansion and electrical properties of Mg_1 − xFe_xO (x = 0.1-0.45) cubic solid solutions and Fe_{3 − x − y}Mg_xCr_yO_4 ± δ (x = 0.7-0.95; y = 0 or 0.5) spinels were studied at 300-1770 K in the oxygen partial pressure range from 10 Pa to 21 kPa. Increasing iron content enlarges the spinel phase stability domain at reduced oxygen pressures and elevated temperatures. The total conductivity of the spinel ceramics is predominantly n-type electronic and is essentially p(O₂)-independent within the stability domain. The computer simulations using molecular dynamics technique confirmed that overall level of ion diffusion remains low even at high temperatures close to the melting point. Temperature dependencies of the total conductivity in air exhibit a complex behavior associated with changing the dominant defect-chemistry mechanism from prevailing formation of the interstitial cations above 1370-1470 K to the generation of cation vacancies at lower temperatures, and with kinetically frozen cation redistribution in spinel lattice below 700-800 K. The average thermal expansion coefficients of the spinel ceramics calculated from dilatometric data in air vary in the range (9.6-10.0) × 10^− 6 K^− 1 at 300-500 K and (13.2-16.1) × 10^− 6 K^− 1 at 1050-1370 K. Mg_1 − xFe_xO solid solutions undergo partial decomposition on heating under oxidizing and mildly reducing conditions, resulting in the segregation of spinel phase and conductivity decrease.     

Isobaric expansion coefficient and isothermal compressibility for a finite-size ideal Fermi gas system

Due to quantum size effects (QSEs), the isobaric thermal expansion coefficient and isothermal compressibility well defined for macroscopic systems are invalid for finite-size systems. The two parameters are redefined and calculated for a finite-size ideal Fermi gas confined in a rectangular container. It is found that the isobaric thermal expansion coefficient and isothermal compressibility are generally anisotropic, i.e., they are generally different in different directions. Moreover, it is found the thermal expansion coefficient may be negative in some directions under the condition that the pressures in all directions are kept constant.     

表面等离极化激元对电荷输运影响的自洽场理论研究Ⅱ——MIM体系分子轨道场的计算与分析

采用自洽场方法计算MIM体系在电场作用下分子场系数、态密度和局域电子态密度的变化.结果表明，分子场系数分布呈现弦函数形式；随电场增大，能带向深能量延伸并且能级峰间分离的更明显，以及构成电流通道的3d_m群原子轨道交叠态的重叠量增大，提高 了电荷输运的能力.该分析为探讨SPP对电荷输运影响的建立奠定了基础. 关键词： 分子轨道场系数 电流通道 态密度 局域电子态密度     

红外光学材料折射率温度系数测量装置

本文介绍一台红外光学材料折射率温度系数测量装置。该装置是由温控系统、精密测角系统、光学系统和电器控制系统等组成的一台高精度全自动化测量系统，采用改进的自准直法测量折射率温度系数值。该装置达到的主要技术指标：工作波长为2～12μm，温度范围为-50～150℃，测量不确定度为3%，可满足各种红外光学材料折射率温度系数测量的要求。利用该装置对红外材料锗折射率温度系数值进行了测量，并对测量数据进行了报道。     

杨氏模量用电学量转换测量的设计

本文在传统的力学量测定的实验基础上,利用电学量参数变化测定杨氏模量,达到研究应力与应变的规律。