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51.
Nanoscale SiO2-TiO2 composite thin films with the thickness of about 100 nm were prepared by sol-gel method at room temperature in air. The chemical states of the elements on the surface and near the surface were measured by XPS. The results showed that the Ti on/near the surface of the thin films existed not only as TiO2 but also as Ti2O3. Part of the TiO2 was changed to Ti2O3 after UV irradiation. The crystalline structure of the TiO2 in the SiO2-TiO2 thin films was anatase with the crystallite size of 14–20 nm. It was found that the thin film prepared at room temperature in air has good superhydrophilic property and has strong adherence to the substrate.  相似文献   
52.
A detailed investigation of addition–fragmentation chain transfer (AFCT) in the free‐radical polymerization of methyl methacrylate (MMA) in the presence of methyl α‐(bromomethyl)acrylate (MBMA) was carried out to elucidate mechanistic details with efficient macromonomer synthesis as an underlying goal. Advanced modeling techniques were used in connection with the experimental work. Curve fitting of simulated and experimental molecular weight distributions with respect to the rate coefficient for addition of propagating radicals to MBMA (kadd) over 60–120 °C resulted in Eadd = 21.7 kJ mol?1 and Aadd = 2.18 × 106 M?1 s?1 and a very weak temperature dependence of the chain‐transfer constant (EaddEp). The rate coefficient for fragmentation of adduct radicals at 60 °C was estimated as kf ≈ 39 s?1 on the basis of experimental data of the MMA conversion and the concentration of 2‐carbomethoxy‐2‐propenyl end groups. The approach developed is generic and can be applied to any AFCT system in which copolymerization does not occur and in which the resulting unsaturated end groups do not undergo further reactions. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 2640–2650, 2004  相似文献   
53.
程愿应  王又青  胡进  李家熔 《物理学报》2004,53(8):2576-2582
根据有限元法单元划分的思想,提出了一种新颖的模拟光腔模式及光束传输的特征向量法. 该方法的关键之处在于基于衍射积分理论构造了一种新的光束传输矩阵,通过求解特征矩阵方程可一次性得到谐振腔的一系列特征向量,每一列特征向量即代表了腔镜上光场的一个确定模式的振幅及相位分布. 并可采用该方法模拟光场传输到腔内或腔外任意地方的场分布. 该方法将传统方法中大量的迭代过程转化成为本征积分方程特征向量的求解过程,并与初值取值无关,且可一次性求得多个模式分布,从而可方便地分析谐振腔的模式鉴别能力. 特征向量法对圆形镜共焦 关键词: 谐振腔 特征向量法 模式分布  相似文献   
54.
郭汝海  时红艳  孙秀冬 《物理学报》2004,53(10):3487-3492
自组装量子点材料作为一种新型的光电材料无论在理论和实际应用都成为当今物理学界的研 究热点.由GaAs包围的InAs小岛,由于较大的晶格失配(≈-0.067),应变效应在量子点 的 形成过程中起主导作用.大部分计算量子点结构应变分布的方法都是基于数值解法,需要大 量的计算工作.给出用格林函数法推导各种常见形状量子点应变分布的解析表达式详细过程,讨论了弹性各向异性和形状各向异性对量子点应变分布的影响程度.结果表明对于不 同形状量子点结构中主要部分的应变分布都是相似的,流体静压变部分的特征值随量子点形状的变化不 关键词: 自组装量子点 格林函数 应变分布  相似文献   
55.
强流离子束离子径向密度分布的模拟研究   总被引:7,自引:0,他引:7       下载免费PDF全文
白龙  翁甲强  方锦清  罗晓曙 《物理学报》2004,53(12):4126-4130
对初始分布为K-V分布的离子束进行模拟研究.除观察到存在束晕现象外,还发现离子束在通 道内运行过程中,离子沿径向密度分布发生了变化. 通过延迟反馈控制,不仅可以消除束晕 ,而且只要控制参数适当,也可以使束中心部分呈均匀分布状态. 关键词: 强流离子束 束晕 填充因子 离子密度分布  相似文献   
56.
We consider a single server queue with disasters where the arrivals of customers and disasters are correlated. When a disaster occurs, it removes all the customers in the system and there requires repair time for the system to be operated normally. The stationary queue length distribution at the embedded points and at an arbitrary time are presented.  相似文献   
57.
The form of the probability density derived from the evolution in time of a previously truncated frequency distribution of animal Liveweights is of interest in animal husbandry. Truncated frequency distributions arise when the heavier animals are sold for slaughter and the lighter animals retained. The demands of modern quality assurance schemes require that, given information on animal growth, the farmer is able to estimate the number of animals that would meet the specifications at some time in the future after truncation. Assuming that animal growth can be described by a linear stochastic differential equation, we derive an explicit expression for the probability density of animal Liveweights at any time after the truncation of an initial Gaussian density. It is shown that this probability density converges rapidly to a Gaussian density, so that after about 20 days of typical growth rates for lambs, the resulting density is practically indistinguishable from Gaussian.  相似文献   
58.
The distributions of limit cycles of cubic vector fields (P2, Q3) are considered in this paper, where P2 and Q3 are polynomials of x and y of order two and three, respectively. It is possibly seven different distributions of limit cycles given in [1]. We now prove that in which three kinds of distributions are impossible and other four kinds all can be realized by concrete vector fields of (P2,Q3). Some related results are also given.  相似文献   
59.
Space time-index plots for probing dynamical nonstationarity   总被引:3,自引:0,他引:3  
We propose a simple method to efficiently probe dynamical nonstationarity in observed time series. In a space time-index plot, the density distributions as a function of normalized time-index are V-shaped due to nonstationarity. We show that this method is workable for short data sets and typical examples are illustrated.  相似文献   
60.
Asymptotic chi-squared test statistics for testing the equality of moment vectors are developed. The test statistics proposed are generalized Wald test statistics that specialize for different settings by inserting an appropriate asymptotic variance matrix of sample moments. Scaled test statistics are also considered for dealing with nonstandard conditions. The specialization will be carried out for testing the equality of multinomial populations, and the equality of variance and correlation matrices for both normal and nonnormal data. When testing the equality of correlation matrices, a scaled version of the normal theory chi-squared statistic is proven to be an asymptotically exact chi-squared statistic in the case of elliptical data.  相似文献   
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