全文获取类型
收费全文 | 18695篇 |
免费 | 2232篇 |
国内免费 | 1767篇 |
专业分类
化学 | 12733篇 |
晶体学 | 517篇 |
力学 | 1746篇 |
综合类 | 121篇 |
数学 | 632篇 |
物理学 | 6945篇 |
出版年
2024年 | 51篇 |
2023年 | 297篇 |
2022年 | 452篇 |
2021年 | 566篇 |
2020年 | 901篇 |
2019年 | 581篇 |
2018年 | 504篇 |
2017年 | 676篇 |
2016年 | 964篇 |
2015年 | 912篇 |
2014年 | 1038篇 |
2013年 | 1451篇 |
2012年 | 945篇 |
2011年 | 1160篇 |
2010年 | 1014篇 |
2009年 | 1130篇 |
2008年 | 1229篇 |
2007年 | 1257篇 |
2006年 | 1061篇 |
2005年 | 899篇 |
2004年 | 855篇 |
2003年 | 817篇 |
2002年 | 599篇 |
2001年 | 493篇 |
2000年 | 428篇 |
1999年 | 348篇 |
1998年 | 317篇 |
1997年 | 266篇 |
1996年 | 242篇 |
1995年 | 187篇 |
1994年 | 191篇 |
1993年 | 152篇 |
1992年 | 130篇 |
1991年 | 90篇 |
1990年 | 87篇 |
1989年 | 71篇 |
1988年 | 56篇 |
1987年 | 52篇 |
1986年 | 47篇 |
1985年 | 31篇 |
1984年 | 36篇 |
1983年 | 22篇 |
1982年 | 30篇 |
1981年 | 17篇 |
1980年 | 8篇 |
1979年 | 10篇 |
1977年 | 3篇 |
1973年 | 2篇 |
1971年 | 6篇 |
1970年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
91.
92.
Effects of Nb2O5 on thermal stability and optical properties of Er3+-doped tellurite glasses
下载免费PDF全文
![点击此处可从《中国物理》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Er3+-doped tellurite glasses with molar compositions of
xNb2O5-(14.7-x)Na2O--10ZnO--5K2O--10GeO2--
60TeO2--0.3Er2O3
(x=0, 3, 5, 7 and 9) have been investigated for developing 1.5~μm
fibre and planar amplifiers. The effects of Nb2O5 on the thermal stability
and optical properties of Er3+-doped tellurite glasses have been discussed.
It is noted that the incorporation of Nb2O5 (x=5) increases the thermal
stability of tellurite glasses significantly. Er3+-doped niobium tellurite
glasses exhibit a large stimulated emission cross-section (7.2\times 10-21-
10.7×10-21~cm2 and the gain bandwidth, FWHM×\sigmae^{\rm peak} (274\times 10-28 - 480×10-28~cm3), which are
significantly higher than that of silicate and phosphate glasses. In addition, the
intensity of upconversion luminescence of the Er3+-doped niobium tellurite
glasses decreases rapidly with increasing Nb2O5 content. As a result,
Er3+-doped niobium tellurite glasses might be a potential candidate for
developing laser or optical amplifier devices. 相似文献
93.
基于机器视觉的离散傅里叶变换目标识别方法 总被引:1,自引:0,他引:1
提出了一种基于机器视觉与离散傅里叶变换的目标特征识别方法。利用计算机图像技术采集和处理图像信号;利用离散的傅里叶变换对图像数据提取特征,能够更好的辨别数据细节,从而可通过图像的比对来实现目标的识别。该方法在对实际的静止图像进行处理与计算后,能够很好的对图像的细节变化进行识别。 相似文献
94.
用射频磁控溅射结合传统退火的方法制备LiCo0.8M0.2O2 (M=Ni,Zr)阴极薄膜.X射线衍射、拉曼光谱、扫描电子显微镜等手段表征了不同掺杂的LiCo0.8M0.2O2薄膜.结果显示,700℃退火的LiCo0.8M0.2O2薄膜具有类似α-NaFeO2的层状结构.通过对不同掺杂锂钴氧阴极的全固态薄膜锂电池Li/LiPON/LiCo0.8M0.2O2的电化学性能研究表明,电化学活性元素Ni的掺杂使全固态电池具有更大的放电容量(56μAh/cm2μm),而非电化学活性元素Zr的掺杂使全固态电池具有更好的循环稳定性. 相似文献
95.
Z.X. Cheng S.J. ZhangF. Song H.C. GuoJ.R. Han H.C. Chen 《Journal of Physics and Chemistry of Solids》2002,63(11):2011-2017
Erbium and ytterbium codoped double tungstates NaY(WO4)2 crystals were prepared by using Czochralski (CZ) pulling method. The absorption spectra in the region 290-2000 nm have been recorded at room temperature. The Judd-Ofelt theory was applied to the measured values of absorption line strengths to evaluate the spontaneous emission probabilities and stimulated emission cross sections of Er3+ ions in NaY(WO4)2 crystals. Intensive green and red lights were measured when the sample were pumped by a 974 nm laser diode (LD), especially, the intensities of green upconversion luminescence are very strong. The mechanism of energy transfer from Yb3+ to Er3+ ions was analyzed. Energy transfer and nonradiative relaxation played an important role in the upconversion process. Photoexcited luminescence experiments are also fulfilled to help analyzing the transit processes of the energy levels. 相似文献
96.
Cluster ions have been recognized as a superb primary species in time of flight secondary ion mass spectroscopy (ToF-SIMS) compared with monatomic primary ions, as they significantly enhance the secondary ion yields from bulk samples. Self-assembled monolayers provide an important system for studying the fundamental mechanism involved in the yield enhancement.We used a gold cluster ion source to analyze a new type of self-assembled monolayer: a fluorocarbon-grafted polyethylene terephthalate. In addition to the structure details, which helped to understand the grafting mechanism, ToF-SIMS analysis revealed that fluorocarbon secondary ion yield enhancements by cluster ions were due to the enhanced sputter efficiency. A larger information depth may also be expected from the enhancement. Both mathematical definitions of damage cross-section and disappearance cross-section were revisited under a new context. Another cross-section parameter, sputter cross-section, was introduced to differentiate the beam induced sputter process from damage process. 相似文献
97.
两种蓝色有机电致发光材料 总被引:4,自引:1,他引:3
重点研究以两种蓝色OEL材料蒽类衍生物JBEM和联苯乙烯衍生物DPVBi分别作基质,以perylene作掺杂剂的器件的电致发光性能,特别研究了它稳定性,在这度和效率方面,两种器件并没有很大差别,然而在稳定性方面却有很大差别,蒽类衍生物JBEM的器件在100cd/m^2初始亮度下,半亮度寿命可达1035h,而DPVBi的器件在同样条件下,半亮度寿命为255h。通过分析两种器件的能级图,认为稳定性的差别可能源于两种蓝光材料本身的热稳定性不同,JBEM优于DPVBi,是一种很有前途的蓝色发光材料。 相似文献
98.
Ana L. Montero Luis A. Montero Ricardo Martínez S. Spange 《Journal of Molecular Structure》2006,770(1-3):99-106
A quantum chemical model (Abinitio HF-MO and DFT-B3LYP) of polyfurfuryl alcohol crosslinking is shown. Two pathways were considered: (a) a Diels–Alder (D–A) reaction between a dihydrofuran moiety and a furan ring; (b) the addition reaction of electrophilic specimens on conjugated double bonds. The ability for the formation of D–A adducts (dienes and dienophiles) was investigated by the frontier molecular orbital (FMO) theory. Energy gaps between the FMO's of diene and dienophile structures suggest that the occurrence of the D–A reaction is possible. The results suggest that the carbons of the exo double bonds attached to dihydrofuran rings are the sites most likely to be attacked by electrophilic species, while the C3 and C4 atoms display the opposite tendency due to their low HOMO electron densities. Results of a thermochemical approach to these reactions at the MP2 level was in agreement with reactivity modelled by MO predictions. 相似文献
99.
为实现书籍扫描图像的畸变自动校正,提出用多项式来描述各像素的理论灰度g(zi)与页面上对应点到扫描仪工作平面距离zi二者之间的关系。为确立该多项式,在畸变参数已知条件下扫描一幅图像,根据已知畸变参数求出zi,即可按最小二乘法原理由各像素灰度的实际值求出多项式的各个系数。实验证明,采用4阶多项式已能满足一般要求,并求出了各系数。对任意扫描图像,自动计算畸变参数的方法为:首先利用扫描图像上页边空白处各像素的灰度,对畸变参数进行估计,并求出zi的估计值;然后代入所确立的多项式,可求得g(zi);通过调整各畸变参数的估计值,直到g(zi)与gi最为接近,即得最佳畸变参数。用于图像校正实验,获得了较好的校正效果,最大误差由不校正时的41%下降到了6.9%。这使得无需用户测量并输入有关畸变参数即可进行自动校正。 相似文献
100.
C. Devaux J.P. Chapel E. Beyou Ph. Chaumont 《The European physical journal. E, Soft matter》2002,7(4):345-352
Thin layers of polystyrene were grown from surface-grafted nitroxide initiators via controlled “living” free radical polymerization.
The “reactive” Langmuir-Blodgett deposition method allowed an effective control of the initiator layer density leading to
PS brushes with different and high grafting density and stretching. The influence of the grafting density on the layer structure
was studied. Comparison with theoretical predictions for monodispersed brushes in bad solvent was discussed. The thickness
was found to vary linearly with molecular weight and the density dependence was shown using wetting measurements. Special
features of controlled radical nitroxide polymerization from a surface were discussed. A direct comparison of the molecular
weight and polydispersity between surface and bulk polymers was made by de-grafting the brushes into a toluene/HF solution.
Finally, some evidence of a “surface Fischer” effect was shown from re-initiated layers.
Received 20 December 2001 相似文献