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221.
Engineering nanostructures in metallic materials such as nanograins and nanotwins can promote plastic performance significantly. Nano/ultrafine-grained metals embedded in coarse grains called bimodal metals and nanotwinned polycrystalline metals have been proved to possess extensively improved yield strength whilst keeping good ductility. This paper will present an experimental study on nanostructured stainless steel prepared by surface mechanical attrition treatment (SMAT) with surface impacts of lower strain rate (10 s?1–103 s?1) and higher strain rate (104 s?1–105 s?1). Microstructure transition has been observed from the original γ-austenite coarse grains to α′-martensite nanograins with bimodal grain size distribution for lower strain rates to nanotwins in the ultrafine/coarse grained austenite phase for higher strain rates. Meanwhile, we will further address the mechanism-based plastic models to describe the yield strength, strain hardening and ductility in nanostructured metals with bimodal grain size distribution and nanotwinned polycrystalline metals. The proposed theoretical models can comprehensively describe the plastic deformation in these two kinds of nanostructured metals and excellent agreement is achieved between the numerical and experimental results. These models can be utilized to optimize the strength and ductility in nanostructured metals by controlling the size and distribution of nanostructures. 相似文献
222.
Andrés Vásquez Quintero Danick Briand Nico F. de Rooij 《Journal of Polymer Science.Polymer Physics》2013,51(8):668-679
This study presents the mechanical characterization of the dry film photoresist PerMX and its adhesion properties when laminated onto Kapton® E (PI) and Melinex® ST506 (PET). Additionally, the processing temperature, the adhesion strength, and the neutral plane position are investigated and optimized. A relatively low-temperature (85 °C) process is developed to protect the integrity of the polymers with low glass transition temperature and reduce the thermal mismatch stress. Reduction in processing temperature led to a decrement in the adhesion strength. To counteract this unwanted effect, surface treatments (oxygen plasma) are performed on the polymer surface before lamination. Using the latter techniques, adhesion of PerMX to PET (hard bake: 1 h at 85 °C) is increased from 0.07 to 0.26 N mm−1 (variation of 270%). Finally, the mechanical robustness is investigated and increased by tuning the position of the neutral plane, after 50,000 bending cycles and a radius of curvature of 2.5 mm. © 2013 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys, 2013 相似文献
223.
The glass transition temperature (Tg), density, refractive index, Raman scattering spectra, and X-ray photoelectron spectra (XPS) for xZnO-yBi2O3-zB2O3 glasses (x=10-65, y=10-50, z=25-60 mol%) are measured to clarify the bonding and structure features of the glasses with large amounts of ZnO. The average electronic polarizability of oxide ions (αO2−) and optical basicity (Λ) of the glasses estimated using Lorentz-Lorenz equation increase with increasing ZnO or Bi2O3 content, giving the values of αO2−=1.963 Å3 and Λ=0.819 for 60ZnO-10Bi2O3-30B2O3 glass. The formation of BOBi and BOZn bridging bonds in the glass structure is suggested from Raman and XPS spectra. The average single bond strength (BMO) proposed by Dimitrov and Komatsu is applied to the glasses and is calculated using single bond strengths of 150.6 kJ/mol for ZnO bonds in ZnO4 groups, 102.5 kJ/mol for BiO bonds in BiO6 groups, 498 kJ/mol for BO bonds in BO3 groups, and 373 kJ/mol for BO bonds in BO4 groups. Good correlations are observed between Tg and BMO, Λ and BMO, and Tg and Λ, proposing that the average single bond strength is a good parameter for understanding thermal and optical properties of ZnOBi2O3B2O3 glasses. 相似文献
224.
The effect of different storage temperatures on the physical properties of pectin solutions and gels
Gordon A. Morris Jonathan Castile Gary G. Adams Stephen E. Harding 《Polymer Degradation and Stability》2010,95(12):2670-2673
The stability (in terms of viscosity and gel strength) of pectin solutions and gels potentially plays an important role in their behaviour and functional properties in a wide range of applications and therefore any changes over time must be understood. The gel strength of pectin gels and intrinsic viscosity of pectin solutions at different temperatures (4 °C, 25 °C and 40 °C) have been investigated using a “rolling ball” viscometer and a texture analyser respectively. Both the intrinsic viscosity ([η]) and gel strength decrease with increased storage time, although this more pronounced at elevated temperatures. The changes in intrinsic viscosity with storage time and temperature were used to determine the depolymerisation constant (k). Pectin storage conditions and particularly temperature have an influence on depolymerisation, particularly elevated storage temperatures, but whether or not this will be detrimental to its intended application will depend on the functional significance of the changes that occur. In this case based on the previous diffusion studies on a model drug (paracetamol) we conclude that the decreases in viscosity and gel strength within the range observed have no detrimental effect on the drug release properties. 相似文献
225.
226.
Allyl alcohol (AA), acrylonitrile (AN), methyl methacrylate (MMA), monomers and monomer mixtures AA+AN, AA+MMA were used to conserve and consolidate Beech and Spruce. After impregnation, copolymerisation and polymerisation were accomplished by gamma irradiation. The fine structure of wood+polymer(copolymer) composites was investigated by Scanning Electron Microscopy (SEM). It was observed that copolymer obtained from AA+MMA monomer mixture showed the optimum compatibility. The compressional strength and Brinell Hardness Numbers determined for untreated and treated wood samples indicated that the mechanical strength of wood+copolymer composites was increased. It was found that the mechanical strength of the wood samples containing the AA+MMA copolymer was higher than the others. In the presence of P(AA/MMA), at highest conversion, the compressive strength perpendicular to the fibres in Beech and Spruce increased approximately 100 times. The water uptake capacity of wood+copolymer composites was observed to decrease by more than 50% relative to the original samples, and biodegradation did not take place. 相似文献
227.
Hexiang Yan Guohua Tian Kang Sun Yong Zhang Yinxi Zhang 《Journal of Polymer Science.Polymer Physics》2005,43(5):573-584
The effects of filler loading and a new silane coupling agent 3‐octanoylthio‐1‐ propyltriethoxysilane (NXT silane) on the polymer‐filler interaction and mechanical properties of silica‐filled and carbon black‐filled natural rubber (NR) compounds were studied. Silica (high dispersion silica7000GR, VN2, and VN3) and carbon black (N330) were used as the fillers, and the loading range was from 0 to 50 phr. The loading of NXT silane was from 0 to 6 phr. Experimental results show that the maximum and minimum torques of silica and carbon black‐filled NR increase with increasing filler loading. With increasing filler loading, the scorch time and optimum cure time decrease for carbon black‐filled NR, but increase for silica‐filled NR. The minimum torque, scorch time, and optimum cure time decrease because of the presence of NXT silane. For the carbon black and silica‐filled NR, the tensile strength and elongation at break have maximum values, but the hardness, M300, M100, and tear strength keep increasing with filler loading. The mechanical properties of silica‐filled NR were improved in the presence of NXT silane. With increasing filler loading, the storage modulus of filled NR increases, but the loss factor decreases. Carbon black shows the strongest polymer‐filler interaction, followed by VN3, 7000GR, and VN2. © 2005 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 43: 573–584, 2005 相似文献
228.
This paper presents a priority rule-based heuristic for the multi-mode resource-constrained project scheduling problem with the splitting of activities around unavailable resources allowed. All resources considered are renewable and each resource unit may not be available at all times due to resource vacations, which are known in advance. A new concept called moving resource strength is developed to help identify project situations where activity splitting is likely to be beneficial during scheduling. The moving resource strength concept is implemented in priority rule-based heuristics to control activity splitting when scheduling. Multiple comparisons of the performance of combination of activity–mode priority rules used in the heuristics are provided. Computational experiments demonstrate the effectiveness of the heuristic in reducing project makespan, and minimizing activity splitting. 相似文献
229.
In the paper, the bending stiffness and strength of multilayer structural elements in relation to the mechanical properties of layers and their number layout and sizes are investigated and the corresponding correlations are established. It is found that the most rational structure of a multilayer element in bending is a symmetric three-layer structure formed from two materials with the thickness of the core less than the half-thickness of the element. The values of normal stresses in the layers of a multilayer beam in bending depends on its bending stiffness and the position of layers relative to the neutral axis. The influence of the number of layers on the stiffness of the structural element and on the magnitude of normal stresses is insignificant. 相似文献
230.
S. N. Gridchin G. G. Gorboletova D. F. Pyreu 《Journal of Thermal Analysis and Calorimetry》2007,90(2):607-609
Reaction enthalpy changes were measured with the use of calorimetric method for the protonation and neutralization of glycyl-β-alanine
at 298.15 K and ionic strengths 0.5, 1.0, 1.5 mol L−1 (KNO3), and the corresponding standard thermodynamic parameters were evaluated. The results obtained were compared with the literature
data on related compounds. 相似文献