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81.
Recently, ferroelectric materials have attracted considerable research attention. In particular, two dimensional (2D) ferroelectric materials have been considered as most crucial for next-generation circuit designs because of their application as novel electric memory devices. However, a 2D ferroelectric material is very rare. The ferroelectric materials with the form ABP2X6 (A = Ag, Cu; B = Bi, In; X = S, Se) are of interest because of their ferroelectric property maintained in their ultrathin structures. Within the ABP2X6 monolayer, the P―P bonds form the pillars that hold the top and bottom X planes, while the off-center A―B atoms between the X layers induce a spontaneous ferroelectric polarization. If the two off-center A―B sites are equally aligned, this would lead to the appearance of the paraelectric state. Such intriguing structures must impart novel mechanical properties to the materials. Until now, there has been no report on the mechanical properties of monolayer ABP2X6. Based on first-principles calculations, we studied the structural, electronic, mechanical as well as the electromechanical coupling properties of monolayer ABP2X6 (A = Ag, Cu; B = Bi, In; X = S, Se). We found that they are all semiconductors with wide bandgaps of 2.73, 2.17, 3.00, and 2.31 eV for CuInP2Se6, CuBiP2Se6, AgBiP2S6, and AgBiP2Se6, respectively, which are calculated based on the Heyd-Scuseria-Ernzerhof (HSE) exchange correlation functional model. The conduction band minimum is mainly from p orbitals of X and B atoms, whereas the valence band maximum is due to the hybridization of the p orbital of X atoms and the d orbital of A atoms. Moreover, there are three short and three long A/B―X bonds due to the A―B off-center displacement. Together with the d-p orbital hybridization, the main reason for the distorted ferroelectric structure in ABP2X6 monolayers is the Jahn-Teller effect. ABP2X6 monolayers are predicted to be a new class of auxetic materials with an out-of-plane negative Poisson's ratio, i.e., the values of the negative Poisson's ratio are in the order AgBiP2S6 (−0.805) < AgBiP2Se6 (−0.778) < CuBiP2Se6 (−0.670) < CuInP2S6 (−0.060). This is mainly due to the tensile strain applied in the x/y direction enlarging the angle between P―P bonds and top layer X atoms, thereby enhancing the bucking height of monolayer ABP2X6. Moreover, external strain has a significant impact on the A―B off-center displacement, rendering an out-of-plane piezoelectric polarization. The values of e13 for CuInP2S6, CuBiP2Se6, AgBiP2S6 , AgBiP2Se6 monolayers are calculated to be −3.95 × 10−12, −5.68 × 10−12, −3.94 × 10−12, −2.71 × 10−12 C∙m−1, respectively, which are comparable to the only experimentally confirmed 2D out-of-plane piezoelectric Janus system (piezoelectric coefficient = −3.8 × 10−12 C∙m−1). This unusual auxetic behavior, ferroelectric polarization, and the electromechanical coupling in monolayer ABP2X6 could potentially lead to enormous technologically important applications in nanoelectronics, nanomechanics, and piezoelectrics. 相似文献
82.
This paper presented development work of an in situ method for damage detection in thin-wall structures using embedded two-dimensional ultrasonic phased arrays. Piezoelectric wafer active sensors were used to generate and receive guided Lamb waves propagating in the plate-like structure. The development of a generic beamforming algorithm that does not require parallel ray assumption through using full wave propagation paths is described. A virtual beam steering method and device, the embedded ultrasonic structural radar, was implemented as a signal post-processing procedure. Several two-dimensional configurations were investigated and compared with beamforming simulation. Finally, rectangular shape arrays were developed for verifying the generic formulas and omnidirectionality. The rectangular arrays yield good directionality within the 360° full range and are able to detect damage anywhere in the entire plate. 相似文献
83.
Piezoelectric materials have received much attention due to their great potential in environmental remediation by utilizing vibrational energy. In this paper, a novel piezoelectric catalyst, CoOx nanoparticles anchored BiFeO3 nanodisk composite, was intentionally synthesized via a photodeposition method and applied in piezocatalytic degradation of rhodamine B (RhB) under ultrasonic vibration. The as-synthesized CoOx/BiFeO3 composite presents high piezocatalytic efficiency and stability. The RhB degradation rate is determined to be 1.29 h−1, which is 2.38 folds higher than that of pure BiFeO3. Via optimizing the reaction conditions, the piezocatalytic degradation rate of the CoOx/BiFeO3 can be further increased to 3.20 h−1. A thorough characterization was implemented to investigate the structure, piezoelectric property, and charge separation efficiency of the CoOx/BiFeO3 to reveal the nature behind the high piezocatalytic activity. It is found that the CoOx nanoparticles are tightly adhered and uniformly dispersed on the surface of the BiFeO3 nanodisks. Strong interaction between CoOx and BiFeO3 triggers the formation of a heterojunction structure, which further induces the migration of the piezoinduced holes on the BiFeO3 to CoOx nanoparticles. The recombination of electron-hole pairs is retarded, thereby increasing the piezocatalytic performance greatly. This work may offer a new paradigm for the design of high-efficiency piezoelectric catalysts. 相似文献
84.
Nanogenerators, as the typical conversion of mechanical energy to electrical energy devices, have great potential in the application of providing sustainable energy sources for powering miniature devices. In this work, cellulose acetate/cellulose nanocrystal(CA/CNC) composite nanofiber membranes were prepared by electrospinning method and then utilized to manufacture a flexible pressure-driven nanogenerator. The addition of CNC not only increased the content of piezoelectric cellulose I crystallization but also strengthened the mechanical deformation of the nanofiber membranes, which could greatly enhance the piezoelectric performance of CA/CNC composite membranes. The CA/CNC composite nanofiber membrane with 20%(mass fraction) of CNC(CA/CNC-20%) showed optimal piezoelectric conversion performance with the output voltage of 1.2 V under the force of 5 N(frequency of 2 Hz). Furthermore, the output voltage of the CA/CNC-20% nanogenerator device exhibited a linear relationship with applied impact force, indicating the great potential in pressure sensors. 相似文献
85.
86.
This work concerns the control of sound transmission through double laminated panels with viscoelastic core using semi-passive piezoelectric shunt technique. More specifically, the system consists of two laminated walls, each one composed of three layers and called sandwich panel with an air cavity in between. The external sandwich panel has a surface-mounted piezoelectric patches. The piezoelectric elements, connected with resonant shunt circuits, are used for the vibration damping of some specific resonance frequencies of the coupled system. Firstly, a finite element formulation of the fully coupled visco-electro-mechanical-acoustic system is presented. This formulation takes into account the frequency dependence of the viscoelastic material. A modal reduction approach is then proposed to solve the problem at a lower cost. In the proposed technique, the coupled system is solved by projecting the mechanical displacement unknown on a truncated basis composed by the first real short-circuit structural normal modes and the pressure unknown on a truncated basis composed by the first acoustic modes with rigid boundaries conditions. The few initial electrical unknowns are kept in the reduced system. A static correction is also introduced in order to take into account the effect of higher modes. Various results are presented in order to validate and illustrate the efficiency of the proposed finite element reduced order formulation. 相似文献
87.
Flexible and lead-free piezoelectric nanocomposites were synthesized with BaTiO3 nanowires (filler) and poly(vinylidene fluoride) (PVDF) (matrix), and the piezoelectric performances of the composites were systematically studied by varying the aspect ratio (AR) and volume fraction of the nanowire and poling time. BaTiO3 nanowires with AR of 18 were synthesized and incorporated into PVDF to improve the piezoelectric performance of the composites. It was found that high AR significantly increased the dielectric constant up to 64, which is over 800% improvement compared to those from the composites containing spheroid shape BaTiO3 nanoparticles. In addition, the dielectric constant and piezoelectric coefficient were also enhanced by increasing the concentration of BaTiO3 nanowires. The piezoelectric coefficient with 50-vol% BaTiO3 nanowires embedded in PVDF displayed 61 pC/N, which is much higher than nanocomposites with spheroid shape BaTiO3 nanoparticles as well as comparable to, if not better, other nanoparticle-filled polymer composites. Our results suggest that it is possible to fabricate nanocomposites with proper mechanical and piezoelectric properties by utilizing proper AR fillers. 相似文献
88.
The frequency response characteristics for twenty-two organic vapours by piezoelectric thickness-shear-mode (TSM) acoustic wave sensors coated with four supramolecule compounds—calixarenes have been investigated. Among them, 2,8,14,20-tetraethyl-4,6,10,12,16,18,22,24-octahydroxylcalix[4]arene (I) was the most efficient actively adsorptive material for host-guest recognizing alkyl ketone molecules such as 2-butanone and acetone. The supramolecule recognition mechanism has been discussed, that is based on the formation of C-H?π bond interaction between the methyl group of ketone molecule and the phenyl ring of the calixarene compound. The linear range of the TSM sensor upon exposure to 2-butanone vapour was 0-940.5 ppm with a detection limit of 2.67 ppm when the coating mass of the compound I was selected as 19 μg. The kinetics behaviours in the adsorption and desorption processes have been examined with polynomial curve fitting procedure. Furthermore, the proposed TSM sensor possessed good selectivity, reversibility, reproducibility and high stability. Compared with gas chromatography (GC) method, the proposed sensor can be used for on-line determination of 2-butanone vapour in air with a recovery of 94.8-106.5%, which was in consistent with those obtained by GC method. 相似文献
89.
Q.-H. Qin 《Archive of Applied Mechanics (Ingenieur Archiv)》1999,69(2):133-144
Summary For a two-dimensional piezoelectric plate subjected to mechanical and electric load, a Green function satisfying traction
free and exact electric boundary conditions along a hole is developed using Lekhnitskii's formalism and the technique of conformal
mapping. The critical points for the mapping function used is investigated numerically, and the study indicates that the transformation
of a polygonal hole in a piezoelectric plate into a unit circle is nonsingle-valued. A simple approach is presented to treat
such a situation. Based on the Green function developed in this paper, a system of singular integral equations for the unknown
dislocation defined on crack faces is presented to study the interaction between cracks and holes. Numerical results are presented
to elucidate the effects of crack orientation on stress and electric displacement (SED) intensity factors and to illustrate
the application of the proposed formulation.
Received 4 June 1998, accepted for publication 15 July 1988 相似文献
90.