DC conductivity and magnetic properties of piezoelectric–piezomagnetic composite system

A series of composites (1−x) (Ni_0.8Zn_0.2Fe₂O₄)+x (BaTiO₃), where x=0%, 20%, 40%, 60%, 80% and 100% BT content, have been prepared by the standard ceramic technique, then sintered at 1200 °C for 8 h. X-ray diffraction analysis shows that the prepared composites consist of two phases, ferrimagnetic and ferroelectric. DC electrical resistivity, thermoelectric power, charge carriers concentration and charge carrier mobility have been studied at different temperatures. It was found that the DC electrical conductivity increases with increasing BT content. The values of the thermoelectric power were positive and negative for the composites indicating that there are two conduction mechanisms, hopping and band conduction, respectively. Using the values of DC electrical conductivity and thermoelectric power, the values of charge carrier mobility and the charge carrier concentration were calculated. Magnetic measurements (hysteresis loop and magnetic permeability) show that the magnetization decreases by increasing BT content. M–H loop of pure Ni_0.6 Zn_0.4 Fe₂O₄ composite indicates that it is paramagnetic at room temperature and that the magnetization is diluted by increasing the BT content in the composite system. The value of magnetoelectric coefficient for the composites decreases by increasing BT content for all the compositions except for 40% BT content, which may be due to the low resistivity of magnetic phase compared with the BT phase that causes a leakage of induced charges on the piezoelectric phase. Since both ferroelectric and magnetic phases preserve their basic properties in the bulk composite, the present BT–NZF composite are potential candidates for applications as pollution sensors and electromagnetic waves.     

On propagation of anti-plane shear waves in piezoelectric plates with surface effect

Based on the surface piezoelectricity model, the anti-plane or horizontally polarized shear (SH) waves propagating in an infinite piezoelectric plate of nano-thickness are investigated to show the surface effect on wave characteristics. The influence on the overall properties of piezoelectric structures resulting from the surface effect is treated as a spring force exerting on the boundary of the bulk. The frequency equations of anti-symmetric and symmetric waves are presented analytically for the electrically short-circuited case. Numerical results show that the wave properties are size-dependent, and the surface effect becomes very pronounced at a high frequency.     

Optimization of un-tethered, low voltage, 20-100kHz flexural transducers for biomedical ultrasonics applications

This paper describes optimization of un-tethered, low voltage, 20-100 kHz flexural transducers for biomedical ultrasonics applications. The goal of this work was to design a fully wearable, low weight (<100 g), battery operated, piezoelectric ultrasound applicator providing maximum output pressure amplitude at the minimum excitation voltage.Such implementation of ultrasound applicators that can operate at the excitation voltages on the order of only 10-25 V is needed in view of the emerging evidence that spatial-peak temporal-peak ultrasound intensity (I_SPTP) on the order of 100 mW/cm² delivered at frequencies below 100 kHz can have beneficial therapeutic effects. The beneficial therapeutic applications include wound management of chronic ulcers and non-invasive transdermal delivery of insulin and liposome encapsulated drugs.The early prototypes of the 20 and 100 kHz applicators were optimized using the maximum electrical power transfer theorem, which required a punctilious analysis of the complex impedance of the piezoelectric disks mounted in appropriately shaped metal housings.In the implementation tested, the optimized ultrasound transducer applicators were driven by portable, customized electronics, which controlled the excitation voltage amplitude and facilitated operation in continuous wave (CW) or pulsed mode with adjustable (10-90%) duty cycle. The driver unit was powered by remotely located rechargeable lithium (Li) polymer batteries. This was done to further minimize the weight of the applicator unit making it wearable. With DC voltage of approximately 15 V the prototypes were capable of delivering pressure amplitudes of about 55 kPa or 100 mW/cm² (I_SPTP). This level of acoustic output was chosen as it is considered safe and side effects free, even at prolonged exposure.     

基于匹配光纤光栅法布里-珀罗干涉仪的应变解调方法

提出并实验验证了一种基于匹配光纤光栅法布里-珀罗干涉仪的应变传感器解调方法,该方法综合了光纤法布里-珀罗干涉技术和匹配光纤光栅滤波法的优点.通过半导体制冷片和压电陶瓷组成的闭环负反馈控制系统,精确调节匹配光栅法布里-珀罗干涉仪的温度和应变,有效解决了光栅法布里-珀罗干涉仪的失配问题,从而保证系统静态工作点处于最佳匹配位置,同时能够避免探头因环境温度波动导致的测量误差.实验结果表明,该系统能够响应50～800Hz的输入信号,应变最小分辨力至少为0.4nε/Hz1/2,解调灵敏度高,且不受环境温度波动的影响,因而在动态应变或振动测量中具有较高的实用性.     

Relationship between phase structure and electrical properties of (K0.5Na0.5)NbO3-LiTaO3 lead-free ceramics

Lead-free piezoelectric ceramics of (1−x)K_0.5Na_0.5NbO₃-xLiTaO₃ (KNN-LT) system have been investigated in this work. X-ray diffraction, Raman spectra measurements, DSC (Differential Scanning Calorimetric), and dielectric constant versus temperature provide direct evidence that the phase transition temperature between tetragonal and orthorhombic shift to lower temperature with the increasing of LT content. The KNN-0.05LT ceramics exhibit the highest high-field d₃₃ up to 220 pm/V. At the same time, we also investigated the relationship between phase structure and electric properties, showing that the orthorhombic phase presents better piezoelectric temperature stabilities than the tetragonal phase. The result may provide a new way for KNN-based lead-free ceramics.     

Large piezoresponse of lead-free Bi0.5(Na0.85K0.15)0.5TiO3 thin film

0.85Bi_0.5Na_0.5TiO₃-0.15Bi_0.5K_0.5TiO₃ (BNKT15) lead-free thin films were prepared on Pt(111)/TiO₂/SiO₂/Si(100) substrates by the chemical solution deposition method. BNKT15 are MPB composition in the Bi_0.5Na_0.5TiO₃-Bi_0.5K_0.5TiO₃ (BNT-BKT) system. The maximum piezoelectric coefficient (d_33,f) value of BNKT15 thin film is approximately 75 pm/V, which is comparable to that of polycrystalline PZT thin films. These results suggest that BNKT15 thin film can be used as an alternative for PZT films in piezoelectric micro-electromechanical systems.     

Analysis of a permeable interface crack in elastic dielectric/piezoelectric bimaterials

A permeable interface crack between elastic dielectric material and piezoelectric material is studied based on the extended Stroh’s formalism. Motivated by strong engineering demands to design new composite materials, the authors perform numerical analysis of interface crack tip singularities and the crack tip energy release rates for 35 types of dissimilar bimaterials, respectively, which are constructed by five kinds of elastic dielectric materials: Epoxy, Polymer, Al₂O₃, SiC, and Si₃N₄ and seven kinds of practical piezoelectric ceramics: PZT-4, BaTiO₃, PZT-5H, PZT-6B, PZT-7A, P-7, and PZT-PIC 151, respectively. The elastic dielectric material with much smaller permittivity than commercial piezoelectric ceramics is treated as a special transversely isotropic piezoelectric material with extremely small piezoelectricity. The present investigation shows that the structure of the singular field near the permeable interface crack tip consists of three singularities: and , which is quite different from that in the impermeable interface crack. It can be concluded that different far field loading cases have significant influence on the near-tip fracture behaviors of the permeable interface crack. Based on the present theoretical treatment and numerical analysis, the electric field induced crack growth is well explained, which provides a better understanding of the failure mechanism induced from interface crack growth in elastic dielectric/piezoelectric bimaterials. The project supported by the National Natural Science Foundation of China (10572110), Doctor Foundation of the Chinese Education Ministry and Doctorate Foundation of Xi’an Jiaotong University. The English text was polished by Yunming Chen.     

Mechanochemical Synthesis of Aryl Fluorides by Using Ball Milling and a Piezoelectric Material as the Redox Catalyst

Aryl fluorides are important structural motifs in many pharmaceuticals. Although the Balz–Schiemann reaction provides an entry to aryl fluorides from aryldiazonium tetrafluoroborates, it suffers from drawbacks such as long reaction time, high temperature, toxic solvent, toxic gas release, and low functional group tolerance. Here, we describe a general method for the synthesis of aryl fluorides from aryldiazonium tetrafluoroborates using a piezoelectric material as redox catalyst under ball milling conditions in the presence of Selectfluor. This approach effectively addresses the aforementioned limitations. Furthermore, the piezoelectric material can be recycled multiple times. Mechanistic investigations indicate that this fluorination reaction may proceed via a radical pathway, and Selectfluor plays a dual role as both a source of fluorine and a terminal reductant.     

Piezoelectrically Mediated Reactions: From Catalytic Reactions to Organic Transformations

Recently, piezocatalysis has attracted considerable attention as a new type of renewable mechanical energy conversion technology, which relies on the strain induced polarization of the piezoelectric material. This new technology has been extensively applied in the applications of water splitting, water remediation, gas purification and tumor therapy. Despite the rapid development in the piezocatalysis, the utilization of piezoelectric materials for synthetic purpose is still under exploration. Piezoelectric means to promote organic reactions expand the scope of piezoelectrically mediated reactions and show successes in both organic and polymer synthesis. Herein, we provide a comprehensive review on recent progress of piezoelectrically mediated reactions, catalytic mechanisms and applications in the last few years. The limitations and future directions of this area are also discussed. We believe this review will provide new insights into the underlying mechanism of piezoelectric mediated electron transfer process and guide the design of new chemistry.      

Mechanoredox Catalysis Enables a Sustainable and Versatile Reversible Addition-Fragmentation Chain Transfer Polymerization Process

The sustainable synthesis of macromolecules with control over sequence and molar mass remains a challenge in polymer chemistry. By coupling mechanochemistry and electron-transfer processes (i.e., mechanoredox catalysis), an energy-conscious controlled radical polymerization methodology is realized. This work explores an efficient mechanoredox reversible addition-fragmentation chain transfer (RAFT) polymerization process using mechanical stimuli by implementing piezoelectric barium titanate and a diaryliodonium initiator with minimal solvent usage. This mechanoredox RAFT process demonstrates exquisite control over poly(meth)acrylate dispersity and chain length while also showcasing an alternative to the solution-state synthesis of semifluorinated polymers that typically utilize exotic solvents and/or reagents. This chemistry will find utility in the sustainable development of materials across the energy, biomedical, and engineering communities.