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91.
A. Hamou C Devallencourt F. Burel J. M. Saiter M. Belbachir 《Journal of Thermal Analysis and Calorimetry》1998,52(3):697-703
The thermal stability of p-cresol novolac resin was studied by means of DSC, X-ray diffraction, thermogravimetry and SEC investigations.
After 30 thermal cycles in which the same sample was heated, cooled and heated again, without attainment of the temperature
of degradation at any time in the experiment, important structural modifications are observed. At the end of the experiments,
the resin, which is initially highly crystalline, exhibits all the characteristics of a semi-crystalline material.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
92.
Barral L. Cano J. López J. López-Bueno I. Nogueira P. Ramírez C. Abad M. J. 《Journal of Thermal Analysis and Calorimetry》1999,55(1):37-45
A study of an epoxy-cycloaliphatic amine system has been realized using a thermogravimetric technique (TG). Isothermal and
non-isothermal (dynamic) methods were employed to determine the kinetic data of this system.
Five methods were used for determining the activation energies of this system in the dynamic heating experiments. In two of
them (Flynn-Wall-Ozawa, and Kissinger) it is not necessary to have a prior knowledge of the reaction mechanism of the degradation
behaviour for this system. In the other ones (Coats and Redfern, Horowitz and Metzger, and Van Krevelen et al.) it is necessary
to know this reaction mechanism, besides Criado et al. method was used for determining it.
The results have shown that good agreement between the activation energies obtained from all methods can be achieved if it
is assumed that the degradation behaviour of this system is of sigmoidal-rate type.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
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A core-shell structure was found in AM SURE™ resin, in which most amino groups were located at the skin layer. The AM SURE™ resin revealed better synthetic efficiency, compared to the noncore-shell type resin in the synthesis of the fragment 65-74 of acyl carrier protein, the fragment 27-35 of HIV (human immunodeficiency virus) fusion inhibitor (T-20) and the Jung-Redemann 10-mer. 相似文献
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98.
Cure kinetics of a cobalt catalysed dicyanate ester monomer in air and argon atmospheres from DSC data 总被引:1,自引:0,他引:1
A kinetic analysis of the cyclotrimerisation reaction of a dicyanate ester monomer catalysed by cobalt(II) acetylacetonate and nonylphenol in air and argon atmospheres has been carried out by differential scanning calorimetry (DSC). Dynamic and isothermal DSC scans as well as the glass transition temperature are the experimental data obtained. From isothermal scans a higher cyanate conversion in air than in argon was obtained. The cyanate conversions are satisfactorily described with a second-order kinetic equation in the kinetically controlled region, and by m-order (m<1) equation after vitrification is reached. Activation energies determined by different procedures agree among them, showing slightly higher values in argon than in air. 相似文献
99.
用改性PVA树脂,从水中富集痕量合成非离子型表面活性剂(SNS),进一步用SNS与钡盐和磷钼酸定量地形成难溶缔合物沉淀,使SNS与共存物分离浓缩。用Mo-邻苯二酚紫-溴化十二烷基吡啶(DPB)显色反应(表面摩尔吸光系数εmax值为3.1×10^5L.mol^-1.cm^_1)体系分光光度测定与SNS定量缔合的Mo,从而间接测定水中痕量SNS。方法用于江,湖水中痕量SNS的测定,获得较好结果。 相似文献
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