光纤拉曼放大器中增益的偏振相关特性研究

提出了一种改进的、可用于计算偏振相关拉曼增益的光纤拉曼放大器的非线性耦合波方程。建立了单模双折射光纤拉曼增益的数学模型,分析了线偏振抽运光以与光纤快轴成45°激励的单模双折射光纤拉曼放大器模型与实际具有随机双折射的光纤拉曼放大器的拉曼增益偏振相关特性的等价性。基于上述模型,提出了一个可定量表征单模光纤偏振模色散统计特性的拉曼增益偏振相关因子,用以替代常规的光纤拉曼放大器非线性耦合波方程中的偏振相关因子。计算结果与已报道文献的实验数据非常吻合。同时对抽运增益在同向和反向抽运方式下截然不同的增益偏振相关特性给出了合理的解释。     

TracePro在“光的偏振实验”中的应用

为提高光的偏振实验教学效果和教学质量,在教学中引入专业的光学设计软件--TracePro,利用该软件仿真了光的双折射过程和现象,以及偏振片的原理;建立光的偏振实验系统实体模型,完成光的偏振态判断实验;仿真光通过波片后的偏振态转换现象;验证马吕斯定律,并仿真了多层介质膜对光的分离和旋光现象.结果表明该方法可以提高教学效率,激发学生探索科学的主观能动性,仿真结论与理论推导和实际实验结果一致.     

Faraday镜预转角对FMOCT输出光偏振态的影响

通过计算机仿真,运用琼斯矩阵理论分析了Faraday镜预转角对法拉第镜式光学电流互感器输出光偏振态的影响.实验测量了Faraday镜实际预转角的大小,测量了外磁场的改变对Faraday镜预转角的影响.外磁场的存在和变化使Faraday镜预转角偏离初始值,并使系统输出光由理想状态下的线偏振光退化成椭圆偏振光,并引起法拉第镜式光学电流互感器工作灵敏度和稳定性的下降.提出了用电磁屏蔽解决外界磁场影响的方法.     

异质结型光催化膜的活性及其机理研究

采用浸渍提拉法制得TiO₂,ZnO,Fe₂O₃,ZnO/TiO₂,TiO₂/ZnO,Fe₂O₃/TiO₂和TiO₂/Fe₂O₃石英玻璃基底负载膜.光催化降解亚甲基蓝实验表明,TiO₂和ZnO具有良好的光催化活性,Fe₂O₃活性较差.但形成异质结后,TiO₂和Fe₂O₃的光催化降解能力发生明显的变化.用254nm紫外光光照后,TiO₂,ZnO和Fe₂O₃等3种氧化物膜与水的接触角均有不同程度的降低,TiO₂表现出超亲水性,ZnO/TiO₂和Fe₂O₃/TiO₂膜与水的接触角小于对应的单纯ZnO和Fe₂O₃膜与水的接触角,其中Fe₂O₃/TiO₂表面出现超亲水性.瞬态光电导谱的少数载流子寿命的测定表明,异质结势垒电场能有效地增强光生电子-空穴对的分离效率.根据能带理论建立的两组异质结能带模型可合理地解释实验结果.     

用于监控过氧化氮的近红外荧光探针的光物理性质及PET机理

含有机硒的七甲川菁染料是基于光诱导电子转移(PET)的近红外(IR)荧光探针, 能在生理条件下高灵敏、高选择性地监控过氧化氮. 本文应用含时密度泛函理论(TD-DFT)计算方法研究其光物理性质和PET机理.结果表明, 在激发态, 荧光母体发生最高占有分子轨道(HOMO)到最低非占有分子轨道(LUMO)的电子跃迁, 识别基团上的HOMO轨道能级提高到荧光母体的单电子占据的HOMO轨道能级之上, 并向其转移一个电子, 使激发态电子回落过程受阻而导致荧光部分淬灭. 硒被氧化后, 识别基团上的HOMO轨道能级降低, PET过程被阻断, 荧光发射恢复. 研究进一步证明, PET效应来自于识别基团上苯胺N原子的p电子, 它的电子转移能力受到其对位苯硒基的氧化-还原状态的影响, 产生了荧光信号的“开-关”作用.     

二氧化碳在铜表面的吸附研究及其光致分解

使用X光电子能谱(XPS)及高分辨电子能量损失谱(HREELS)研究了二氧化碳在铜表面的吸附及其光化学反应.通过实验条件控制将物理吸附及化学吸附的二氧化碳吸附物种分别分离在规整铜表面及无序铜表面上,并使用193 nm激光对其照射研究其相应的光化学反应.结果表明只有化学吸附的二氧化碳物种在光诱导下发生了解理反应,而物理吸附的二氧化碳未发生反应.     

Synthesis and optical properties of metal-centered dimeric fullerene macromolecules

Dimeric fullerene macromolecules were prepared via the complexation of two fullerenylated 2,2′:6′,2″-terpyridine ligands with Fe(II) and Co(II) ions. The solubility of these macromolecules in some organic solvents allowed both their structural characterization and a study of their optical properties. The electronic absorption and emission of the macromolecules in solution were evaluated; and the results indicated no meaningful ground-state and excited singlet state intramolecular charge transfer interactions. However, the laser flash photolysis results could be explained in terms of the electron transfer quenching of the excited triplet methanofullerene moiety by the center metal–ligand complex in the macromolecules. The optical limiting properties of the macromolecules in solution were also investigated in comparison with those of the ligands for an evaluation of the complexation effects.     

An Exceptional Peroxide Birefringent Material Resulting from d–π Interactions

Birefringent materials, which can modulate the polarization of light, are almost exclusively limited to oxides. Peroxides have long been overlooked as birefringent materials, because they are usually not stable in air. Now, the first peroxide birefringent material Rb₂VO(O₂)₂F is reported, the single crystals of which keep transparency after being exposed in the air for two weeks. Interestingly, Rb₂VO(O₂)₂F does not feature an optimal anisotropic structure, but its birefringence (Δn=0.189 at 546 nm) exceeds those of the majority of oxides. According to the first‐principles calculations, this exceptional birefringence should be attributed to the strong electronic interactions between localized π orbital of O₂^2? anions and V⁵⁺ 3d orbitals, which may be also favorable to the stability in the air for Rb₂VO(O₂)₂F. These findings distinguish peroxides as a brand‐new class of birefringent materials that may possess birefringence superior to the traditional oxides.     

New fabrication approach to develop a high birefringence photo-crosslinked film based on a sulfur-containing liquid crystalline molecule with large temperature dependence of birefringence

ABSTRACT

We present a new fabrication approach to achieve a high birefringence film by means of photopolymerization based on an alkylthio-containing rod-like liquid crystalline molecule exhibiting large temperature dependence of birefringence. We designed a new reactive mesogen having alkylthio linkages (BPM–S). It was found that BPM–S had a larger increment of birefringence with decreasing temperature, relative to commercially available alkoxy analog LC242. This result could be thought to be due to enhanced intermolecular attractive interaction for an alkylthio mesogen implied by the proximity of laterally neighboring molecules and cybotactic nematic tendency based on wide-angle X-ray measurement. The uniaxially-aligned photo-polymerized film for BPM–S showed higher birefringence than that for LC 242.     

一种新的双偶氮染料掺杂聚合物薄膜的光致双折射及偏振全息的研究

作为一种有可能作为永久信息存储的材料,合成出一种新的双偶氮材料(BA1)。当样品被波长为532nm的光激发时,几乎大部分BA1分子从反-反态转化到顺-顺态,产生了光致双折射。因此,研究了BA1分子掺杂的PMMA薄膜的光致双折射和透过信号与入射光强度的关系。实验结果表明:透过信号强度随着泵浦光的增强而增强。通过偏振态互相平行(SS)和垂直(SP)的两束偏振光用来研究偏振全息存储,结果表明SP光栅形成的衍射信号要比SS光栅的衍射信号强很多。