全文获取类型
收费全文 | 11814篇 |
免费 | 1021篇 |
国内免费 | 424篇 |
专业分类
化学 | 12540篇 |
晶体学 | 44篇 |
力学 | 125篇 |
综合类 | 8篇 |
数学 | 19篇 |
物理学 | 523篇 |
出版年
2024年 | 32篇 |
2023年 | 70篇 |
2022年 | 165篇 |
2021年 | 192篇 |
2020年 | 397篇 |
2019年 | 338篇 |
2018年 | 295篇 |
2017年 | 469篇 |
2016年 | 681篇 |
2015年 | 570篇 |
2014年 | 598篇 |
2013年 | 974篇 |
2012年 | 767篇 |
2011年 | 730篇 |
2010年 | 689篇 |
2009年 | 764篇 |
2008年 | 751篇 |
2007年 | 743篇 |
2006年 | 637篇 |
2005年 | 577篇 |
2004年 | 613篇 |
2003年 | 449篇 |
2002年 | 330篇 |
2001年 | 184篇 |
2000年 | 117篇 |
1999年 | 140篇 |
1998年 | 124篇 |
1997年 | 132篇 |
1996年 | 113篇 |
1995年 | 99篇 |
1994年 | 104篇 |
1993年 | 105篇 |
1992年 | 108篇 |
1991年 | 46篇 |
1990年 | 24篇 |
1989年 | 23篇 |
1988年 | 20篇 |
1987年 | 15篇 |
1986年 | 16篇 |
1985年 | 10篇 |
1984年 | 12篇 |
1983年 | 5篇 |
1982年 | 11篇 |
1981年 | 7篇 |
1979年 | 4篇 |
1978年 | 1篇 |
1977年 | 2篇 |
1975年 | 2篇 |
1974年 | 2篇 |
1972年 | 1篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
111.
Richard A. Cairncross Jeffrey G. Becker Shri Ramaswamy Ryan O'Connor 《Applied biochemistry and biotechnology》1996,131(1-3):774-785
Management of moisture penetration and hydrolytic degradation of polylactide (PLA) is extremely important during the manufacturing,
shipping, storage, and end-use of PLA products. Moisture transport, crystallization, and degradation, in PLA have been measured
through a variety of experimental techniques including size-exclusion chromatography, differential scanning calorimetry, and
X-ray diffraction. Quartz crystal microbalance and dynamic vapor sorption experiments have also been used to measure moisture
sorption isotherms in PLA films with varying crystallinity. A surprising result is that, within the accuracy of the experiments,
crystalline and amorphous PLA films exhibit identical sorption isotherms. 相似文献
112.
We investigate the statistical and dimensional properties of uniform star polymers attached by the branching vertex of degreef in a wedge geometry in three dimensions and described by the wedge angles and. We show that the growth constant is equal to
f
, where is the self-avoiding walk limit. Thef and (, ) dependences of the corresponding critical exponent
f
(, ) are studied using Monte Carlo techniques. In the casef=1, our results are compared with existing predictions obtained from series expansion and renormalization group methods. We have also estimated the amplitudes for the mean square radius of gyration and the mean square end-to-end branch length. Our results for the ratio of the mean square radius of gyration of anf-star to that of a linear polymer of the same degree of polymerization attached in a similar wedge, and the analogous ratio for the mean square end-to-end branch length, are consistent with these ratios being lattice-independent quantities. 相似文献
113.
Yi-Cheng Zhang 《Journal of statistical physics》1989,57(5-6):1123-1128
A replica trick is used to map the problem of directed polymers into a quantum mechanics problem ofn-body bound states. This bound-state problem is then treated using a self-consistent method of Hartree-Fock. Ford=2, the exact result of the DP exponents is reproduced; and for complex DP, the ground-state energyE
n n2 is found, confirming previous numerical results. 相似文献
114.
Rong‐Min Wang Nai‐Pu He Yu‐Feng He Yun‐Tao Xie Yun‐Pu Wang Eishun Tsuchida 《先进技术聚合物》2005,16(8):638-641
Water‐soluble low molecular weight chitosan of nanometer level and its copper complexes were prepared, and characterized by IR spectra, elemental analysis and gel permeation chromatography (GPC). The modes and mechanism of these copper complexes interaction with DNA were studied by a fluorescent probe method and electrophoresis analysis. It is suggested that there are electrostatic and intercalation modes of copper complexes interacting with DNA. At first, the cationic complex electrostaticly binds to the negatively charged phosphate backbone of DNA, and then a portion of the complex intercalates between the base pairs on the DNA duplex strand. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
115.
介绍了核磁共振(NMR)波谱,尤其是核磁共振二维谱(2D NMR)在最近几年内的进展。内容包括怎样用NMR测定高聚物的序列分布、共聚物结构、聚合物的混溶性、聚合物液晶的取向度、分子量、短链度和长链支化度、凝聚态高聚物的多相结构等。 相似文献
116.
Chun H Dybtsev DN Kim H Kim K 《Chemistry (Weinheim an der Bergstrasse, Germany)》2005,11(12):3521-3529
A systematic modulation of organic ligands connecting dinuclear paddle-wheel motifs leads to a series of isomorphous metal-organic porous materials that have a three-dimensional connectivity and interconnected pores. Aromatic dicarboxylates such as 1,4-benzenedicarboxylate (1,4-bdc), tetramethylterephthalate (tmbdc), 1,4-naphthalenedicarboxylate (1,4-ndc), tetrafluoroterephthalate (tfbdc), or 2,6-naphthalenedicarboxylate (2,6-ndc) are linear linkers that form two-dimensional layers, and diamine ligands, 4-diazabicyclo[2.2.2]octane (dabco) or 4,4'-dipyridyl (bpy), coordinate at both sides of Zn(2) paddle-wheel units to bridge the layers vertically. The resulting open frameworks [Zn(2)(1,4-bdc)(2)(dabco)] (1), [Zn(2)(1,4-bdc)(tmbdc)(dabco)] (2), [Zn(2)(tmbdc)(2)(dabco)] (3), [Zn(2)(1,4-ndc)(2)(dabco)] (4), [Zn(2)(tfbdc)(2)(dabco)] (5), and [Zn(2)(tmbdc)(2)(bpy)] (8) possess varying size of pores and free apertures originating from the side groups of the 1,4-bdc derivatives. [Zn(2)(1,4-bdc)(2)(bpy)] (6) and [Zn(2)(2,6-ndc)(2)(bpy)] (7) have two- and threefold interpenetrating structures, respectively. The non-interpenetrating frameworks (1-5 and 8) possess surface areas in the range of 1450-2090 m(2)g(-1) and hydrogen sorption capacities of 1.7-2.1 wt % at 78 K and 1 atm. A detailed analysis of the sorption data in conjunction with structural similarities and differences concludes that porous materials with straight channels and large openings do not perform better than those with wavy channels and small openings in terms of hydrogen storage through physisorption. 相似文献
117.
118.
Macroporous poly(methyl methacrylate) produced by phase separation during polymerisation in solution
A. Serrano Aroca M. Monleón Pradas J. L. Gómez Ribelles 《Colloid and polymer science》2007,285(7):753-760
Polymethyl methacrylate (PMMA) sponges were obtained by polymerization in a solution with monomer/ethanol ratios up to 20:80.
The material obtained after the elimination of the solvent present a homogeneous distribution of dispersed pores up to a monomer/ethanol
ratio lower than 40:60. For higher ethanol contents in the reacting mixture, the morphology of the sponge corresponds to a
network of PMMA microparticles, leaving large empty spaces leading to highly porous structure. The monomer/ethanol ratio during
polymerization has a large influence on the porosity, thermal, and mechanical properties of the material and, for large solvent
contents, on the size of the polymer microparticles. 相似文献
119.
120.