含耐高温涂覆层长周期光纤光栅的温度特性研究

利用逐点写入法在耐高温光纤中用红外飞秒激光直接写入了长周期光纤光栅,研究了光栅的高温温度特性,并做了理论分析.通过对含耐高温涂覆层的长周期光纤光栅进行20℃～300℃的温度传感实验,结果表明:在高温段光栅的谐振波长漂移量与温度之间仍能保持大的灵敏度(0.060 5 nm/℃)和好的线性度,且光纤耐高温涂覆层不受破坏,光...     

温室气体遥感探测仪器发展现状

阐述了温室气体遥感探测技术的发展历程。详细介绍了几种国外先进的高光谱分辨率温室气体遥感探测仪器的设计理念、工作方式、谱段设置和主要技术指标。综述了温室气体探测技术从综合性探测仪器到专用温室气体探测仪器的发展过程,指出了温室气体探测仪器未来发展方向,包括高光谱分辨率、高空间分辨率,宽覆盖范围,短覆盖周期以及高信噪比等。     

微波后向散射数据改进农作物光谱分类精度研究

利用实验区环境星多光谱数据与Envisat ASAR VV极化数据进行融合.讨论了VV极化微波后向散射数据用于改善多光谱遥感数据农作物分类的精度,并比较了不同分类方法的分类精度.结果表明,两种数据之间的融合充分利用了环境星数据的光谱信息和VV极化数据对于地物结构敏感的特征,不但增强了不同地物之间的光谱差异,而且提高了作...     

遥感影像分类方法研究进展

遥感影像分类是遥感信息提取的重要手段,是目前遥感技术中的热点研究内容.分类方法是遥感影像分类的重要内容,有效地选择合适的分类方法是提高分类精度的关键.随着遥感技术的发展,传统的非参数分类方法已经难以满足分类精度需求,基于智能算法的非参数分类方法得到了迅速发展,并在遥感影像分类中发挥着重要作用.近年来,组合分类器由于能够...     

多角度偏振遥感相机DPC在轨偏振定标

为了做好卫星数据应用的技术储备,多角度偏振遥感相机DPC航空预研版已经研制成功并完成了航空飞行实验. DPC相机用于获取地气系统反射的偏振、多角度的太阳辐射信息,其地气物理参数反演依赖于定标的精度. 偏振相机的辐射定标包括强度和偏振两个方面. 本文研究偏振遥感相机的偏振参数的在轨定标原理与方法. 基于偏振遥感相机的设计原理,以相机的偏振辐射模型为基础,探索偏振定标的原理和方法. 使用DPC航空遥感实验数据,初步实现了在轨偏振定标并对定标结果进行了分析. 为将来我国自主星载偏振遥感数据处理和在轨偏振定标提供 关键词： 偏振定标 遥感 在轨定标 DPC     

Fluorescent nanoparticles for chemical and biological sensing

Fluorescent nanoparticles (NPs), including quantum dots (QDs), dye-doped NPs, and rare earth-based NPs, etc., have been a major focus of research and development during the past decade. The impetus behind such endeavors can be attributed to their unique chemical and optical properties, such as bright fluorescence, high photostability, large Stocks shift and flexible processability. The introduction of fluorescent NPs into analytical chemistry has opened up new venues for fluorescent analysis. In this review...     

Humidity Sensing Properties of Flower‐Like VO2(B) and VO2(M) Nanostructures

VO₂(B) nanoflowers were synthesized via hydrothermal method, and VO₂(M) nanoflowers were obtained through heat‐transformation. Two sensors based on VO₂(B) and VO₂(M) nanoflowers were fabricated and their humidity characteristics were studied. It was found that these sensors exhibited fast response and recovery, perfect reproducibility and good stability. The VO₂(M) type sensor is more sensitive at high RH and can be used for high humidity detection. On the contrary, the VO₂(B) type sensor has a higher sensitivity at low RH, and can be used for low humidity detection, which is difficult for humidity sensors based on many other semiconductor oxides.     

Discourse on the utilization of polyaniline coatings for surface plasmon resonance sensing of ammonia vapor

Surface plasmon resonance spectroscopy is sensitive to near-surface (<300 nm) chemical and physical events that result in refractive index changes. The non-specific nature of the stimulus implies that chemical selectivity in SPR sensing configurations entirely relies upon the chemical recognition scheme employed. Biosensing applications commonly use surface layers composed of antibodies or enzymes for biomolecular recognition. Monitoring of volatile compounds with SPR spectroscopy, however, has not been widely discussed due to the difficulty in selectively responding to small molecules (<100 Da) in addition to the limited refractive index changes resulting from the interaction between the plasmon wave and volatile compounds.Different strategies explored thus far for sensing of small molecules have relied on optical and electrical changes of the recognition layer upon exposure to the analyte, yielding an indirect measurement. Examples of coatings used for gas-phase sensing with SPR include conducting metal oxides, polymers and organometallic dyes. Electrically conducting polymers, like polyaniline and polypyrrole, display dramatic conductivity changes in the presence of certain compounds. This property has resulted in their routine incorporation into different sensing schemes. However, application of electrically conducting polymers to SPR gas-phase sensing has been limited to a few examples, despite encouraging results.The emeraldine salt form of polyaniline (PAni) demonstrates a decreased electrical conductivity correlated to NH₃ concentration. In this contribution, PAni doped with camphorsulfonic acid (PAni-CSA) was applied to gas-phase sensing of NH₃ by way of SPR spectroscopy. Spectroscopic ellipsometry was used to determine the optical constants (n and k) for emeraldine salt and emeraldine base forms of PAni, confirming the wavelength-dependent response observed via SPR. The analytical performance of the coatings show that a limit of detection of 32 ppm NH₃ based on precision of the mass-flow controllers used and an estimated method limit of detection of ∼0.2 ppm based on three standard deviations of the blank. This is directly comparable to other, more established sensing architectures.     

Rhodamine-based chemosensing monolayers on glass as a facile fluorescent “turn-on” sensing film for selective detection of Pb

Rhodamine-based chemosensors 1 and 2 were synthesized and self-assembled onto glass surfaces for the selective fluorescent sensing of Pb²⁺. The immobilized chemosensors showed fluorescent responses that were turned-on with Pb²⁺ in CH₃CN, selectively over various metal ions. The Pb²⁺-selective fluorescent switch of the immobilized chemosensors was also reversible, allowing for repeated use for Pb²⁺ detection.     

Helical binuclear Co complexes of pyriporphyrin analogue for sensing homochiral carboxylic acids

A hybrid macrocycle composed of two bipyridines and two dipyrrins gave biscobalt complexes of figure eight macrocycle conformation with κ²-carboxylate ligands and water ligands at the axial sites. The axial acetate ligands of the biscobalt complex are readily exchanged with carboxylates of α-hydroxyl acids and α-amino acids. The chiral center of the axial carboxylate ligands controls the helical handedness of the macrocycle as evidenced by a typical CD couplet at 550 nm. The substitution labile nature of the biscobalt complex plays a key role for helical chirality induction on the macrocycle upon co-ordination of chiral carboxylate anions.