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Zheng‐Jian Wu Feng Su Weidong Lin Jinshuai Song Ting‐Bin Wen Hui‐Jun Zhang Hai‐Chao Xu 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(47):16926-16930
Transition metal catalyzed C?H phosphorylation remains an unsolved challenge. Reported methods are generally limited in scope and require stoichiometric silver salts as oxidants. Reported here is an electrochemically driven RhIII‐catalyzed aryl C?H phosphorylation reaction that proceeds through H2 evolution, obviating the need for stoichiometric metal oxidants. The method is compatible with a variety of aryl C?H and P?H coupling partners and particularly useful for synthesizing triarylphosphine oxides from diarylphosphine oxides, which are often difficult coupling partners for transition metal catalyzed C?H phosphorylation reactions. Experimental results suggest that the mechanism responsible for the C?P bond formation involves an oxidation‐induced reductive elimination process. 相似文献