首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   127143篇
  免费   9190篇
  国内免费   19764篇
化学   104203篇
晶体学   2708篇
力学   2956篇
综合类   1168篇
数学   15202篇
物理学   29860篇
  2024年   265篇
  2023年   1511篇
  2022年   3376篇
  2021年   3308篇
  2020年   3723篇
  2019年   3485篇
  2018年   2943篇
  2017年   4115篇
  2016年   4283篇
  2015年   3607篇
  2014年   4941篇
  2013年   10015篇
  2012年   8435篇
  2011年   7517篇
  2010年   6445篇
  2009年   8428篇
  2008年   8447篇
  2007年   8676篇
  2006年   7911篇
  2005年   6785篇
  2004年   6322篇
  2003年   5276篇
  2002年   6206篇
  2001年   3911篇
  2000年   3627篇
  1999年   3271篇
  1998年   2828篇
  1997年   2270篇
  1996年   1949篇
  1995年   1852篇
  1994年   1654篇
  1993年   1363篇
  1992年   1262篇
  1991年   890篇
  1990年   709篇
  1989年   675篇
  1988年   521篇
  1987年   391篇
  1986年   344篇
  1985年   321篇
  1984年   312篇
  1983年   166篇
  1982年   256篇
  1981年   242篇
  1980年   240篇
  1979年   236篇
  1978年   208篇
  1977年   159篇
  1976年   130篇
  1973年   89篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
151.
Let M be an arithmetic hyperbolic manifold and be a codimension 1 geodesic cycle. In this paper, we study the asymptotic growth of the -norm of the lifts of F in the congruence tower above M. We obtain an explicit value for the growth rate of this norm. In particular, we provide a new proof of a celebrated result of Millson [Mi] on the homology of the arithmetic hyperbolic manifolds. The method is quite general and gives a new way of getting non zero homology classes in certain locally symmetric spaces. Received: 20 April 2001; in final form: 26 September 2001 / Published online: 28 February 2002  相似文献   
152.
New biodegradable/biocompatible ABC block copolymers, poly(ethylene oxide)‐b‐poly(glycidol)‐b‐poly(L ,L ‐lactide) (PEO‐PGly‐PLLA), were synthesized. First, PEO‐b‐poly(1‐ethoxyethylglycidol)‐b‐PLLA was synthesized by a successive anionic ring‐opening copolymerization of ethylene oxide, 1‐ethoxyethylglycidyl ether, and L ,L ‐lactide initiated with potassium 2‐methoxyethanolate. In the second step, the 1‐ethoxyethyl blocking groups of 1‐ethoxyethylglycidyl ether were removed at weakly acidic conditions leaving other blocks intact. The resulting copolymers were composed of hydrophilic and hydrophobic segments joined by short polyglycidol blocks with one hydroxyl group in each monomeric unit. These hydroxyl groups may be used for further copolymer transformations. The PEO‐PGly‐PLLA copolymers with a molecular weight of PLLA blocks below 5000 were water‐soluble. Above the critical micellar concentration (ranging from 0.05 to1.0 g/L, depending on the composition of copolymer), copolymers formed macromolecular micelles with a hydrophobic PLLA core and hydrophilic PEO shell. The diameters of the micelles were about 25 nm. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 3750–3760, 2003  相似文献   
153.
We describe the pulse forming of pulsed CO2 laser using multi-pulse superposition technique. Various pulse shapes, high duty cycle pulse forming network (PFN) are constructed by time sequence. This study shows a technology that makes it possible to make various long pulse shapes by activating SCRs of three PFN modules consecutively at a desirable delay time with the aid of a PIC one-chip microprocessor. The power supply for this experiment consists of three PFN modules. Each PFN module uses a capacitor, a pulse forming inductor, a SCR, a high voltage pulse transformer, and a bridge rectifier on each transformer secondary. The PFN modules operate at low voltage by driving the primary of HV pulse transformer. The secondary of the transformer has a full-wave rectifier, which passes the pulse energy to the load in a continuous sequence.We investigated various long pulse shapes as different trigger time intervals of SCRs among three PFN modules. As a result, we could obtain laser beam with various pulse shapes and durations from about 250 to 1000 μs.  相似文献   
154.
贝克曼Allegra^TM 21R型超高速离心机开机后,操作面板上出现错误代码“28”,离心机不旋转。离心机的电机采用无刷感应驱动,由电机驱动电源模块BSMl0GD60DN2驱动离心机的电机。故障是由于电源模块BSMl0GD60DN2损坏引起的。采用东芝三相桥式IGBT电源模块MG25Q6ES42代替BSMl0GD60DN2,并更换已烧毁的栅极电阻后。开机试验,仪器恢复正常。  相似文献   
155.
[Na(18-C-6)]2[Cu(i-mnt)2]的合成与结构分析   总被引:2,自引:2,他引:0  
研究了18-冠-6与Na2[Cu(i-mnt)2][i-mnt=异丁二腈烯二硫醇阴离子,S2CC(CN)2-2]的反应,得到的配合物[Na(18-C-6)]2[Cu(i-mnt)2](1)通过元素分析、红外光谱、X射线单晶衍射进行了结构分析.配合物为单斜晶系,空间群P2(1)/c.晶体学结构数据a=1.2819(11),b=1.1793(10),c=1.4928(13)nm,β=99.121(16)°,V=2.228(3)nm3,Z=2,Dcaled.=1.369g/cm3,F(000)=958,R1=0.0521,wR2=0.1003.1中的[Cu(i-mnt)2]基团通过配体i-mnt的氮原子与两个[Na(18-C-6)]基团中的钠原子成键,形成稳定的中性配合物.  相似文献   
156.
相变光盘介电薄膜ZnS-SiO2 的微结构和光学特性   总被引:2,自引:2,他引:0  
刘波  阮昊  干福熹 《光子学报》2003,32(7):834-836
采用射频磁控溅射法制备了ZnS-SiO2 介电薄膜,利用透射电镜和椭偏仪研究了溅射条件对ZnS-SiO2薄膜微结构和折射率n的影响.研究表明,ZnS-SiO2薄膜中存在微小晶粒,大小为2~10 nm的ZnS颗粒分布在SiO2基体中,当溅射功率和溅射气压变化时,ZnS-SiO2薄膜的微结构和折射率n发生显著变化,微结构的变化是导致折射率n变化的主要原因,通过优化溅射条件可以制备适用于相变光盘的高质量ZnS-SiO2介电薄膜.  相似文献   
157.
改进型磁绝缘线振荡器的设计和数值模拟   总被引:6,自引:6,他引:0       下载免费PDF全文
 综合两种现有磁绝缘线振荡器的优点,对器件进行改进,将双渐变结构、轭流片和阻抗渐变三种增大功率的机制综合考虑,利用二维半全电磁PIC程序进行数值模拟,设计了一种新的改进型磁绝缘线振荡器,当外加电压为550kV,电流为35kA左右时,在L波段获得了6GW的峰值输出功率。  相似文献   
158.
一种不等带宽光学梳状滤波器   总被引:10,自引:4,他引:6  
提出了一种新型—Michelson—三面镜FabryPerot型50GHz不等带宽光学梳状滤波器设计方案,分析和模拟表明:该器件将一路信道间隔为50GHz的输入信号分离成信道间隔为100GHz的奇偶两路输出信号,其中在3dB处,奇数信道带宽大于30GHz用于10Gb/s传输,偶数信道带宽大于60GHz用于40Gb/s传输对于将来的40Gb/s系统,该器件具有优势.  相似文献   
159.
    
3-[4-(Azidocarbonyl)]phenylsydnone (2) obtained from 3-(4-hydrazinocarbonyl) phenylsydnone (1) on Curtius rearrangement with alcohols, water and amines afforded the corresponding carbamates (3a-h), 4,4′-(sydnone-3-yl) diphenyl urea (4) and 4-(heterocyclyl)phenyl ureas (5a-l). Compounds (5a-l) on one-pot ring conversion yielded the 1,3,4-oxadiazolin-2-one derivatives (6a-l), which on reaction with N2H4 gave the 4-amino-1,2,4-triazolin-3-ones (7a-l). All these compounds exhibited moderate antimicrobial activity against the few microbes tested. The carbamates have been found to be more toxic against fourth instar larvae ofAedes aegypti, in particular, then-butyl derivative (3e).  相似文献   
160.
1 INTRODUCTION The study of heterocyclic molecules with aroma- tic rings and their absorptions on metals is of con- siderable importance from both theoretical and te- chnological points of view. These molecules are in- teresting because of their applications as corrosion inhibitors and flotation collectors, and their abilities to form self-assembly layers[1]. 2-Mercaptobenzo- thiazole (C7H5NS2, in the following MBT) is an important heterocyclic molecule, which can be used as corrosion …  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号